Novel approaches to determine residual stresses by ultramicroindentation techniques: application to sand blasted austenitic stainless steel

This research addresses the determination of residual stresses in sandblasted austenitic steel by ultramicroindentation techniques using a sharp indenter, whose sensitivity to residual stress effects is said to be inferior to that for spherical ones. We propose the introduction of an angular correction in the model of Wang et al. that relates variations in the maximum load to the presence of residual stresses. Likewise, the contribution to hardness of grain size refinement and work hardening, developed as a consequence of the severe plastic deformation during blasting, is determined to avoid overestimation of the residual stresses. Measurements were performed on polished cross sections along a length of several microns, thus obtaining a profile of the residual stresses. Results show a good agreement with those obtained by synchrotron radiation on the same specimens, which validates the method and demonstrates that microindentation using sharp indenters may be sensitive to the residual stress effect.Peer Reviewe

Interplay between the magnetic anisotropy contributions of Cobalt nanowires

We report on the magnetic properties and the crystallographic structure of the cobalt nanowire arrays as a function of their nanoscale dimensions. X-ray diffraction measurements show the appearance of an in-plane HCP-Co phase for nanowires with 50 nm diameter, suggesting a partial reorientation of the magnetocrystalline anisotropy axis along the membrane plane with increasing pore diameter. No significant changes in the magnetic behavior of the nanowire system are observed with decreasing temperature, indicating that the effective magnetoelastic anisotropy does not play a dominant role in the remagnetization processes of individual nanowires. An enhancement of the total magnetic anisotropy is found at room temperature with a decreasing nanowire diameter-to-length ratio (d/L), a result that is quantitatively analyzed on the basis of a simplified shape anisotropy model.Comment: 8 pages, 4 figure

Dependence of exchange anisotropy and coercivity on the Fe–oxide structure in oxygen-passivated Fe nanoparticles

Ultrafine Fe particles have been prepared by the inert gas condensation method and subsequently oxygen passivated. The as-obtained particles consist in an Fe core surrounded by an amorphous Fe-oxide surface layer. The antiferromagnetic character of the Fe-oxide surface induces an exchange anisotropy in the ferromagnetic Fe core when the system is field cooled. Samples have been heat treated in vacuum at different temperatures. Structural changes of the Fe–O layer have been monitored by x-ray diffraction and transmission electron microscopy. Magnetic properties as coercivity, hysteresis loop shift, and evolution of magnetization with temperature have been analyzed for different oxide crystallization stages. A decrease of the exchange anisotropy strength is reported as the structural disorder of the surface oxide layer is decreased with thermal treatment

Dependence of exchange anisotropy and coercivity on the Fe–oxide structure in oxygen-passivated Fe nanoparticles

Ultrafine Fe particles have been prepared by the inert gas condensation method and subsequently oxygen passivated. The as-obtained particles consist in an Fe core surrounded by an amorphous Fe-oxide surface layer. The antiferromagnetic character of the Fe-oxide surface induces an exchange anisotropy in the ferromagnetic Fe core when the system is field cooled. Samples have been heat treated in vacuum at different temperatures. Structural changes of the Fe–O layer have been monitored by x-ray diffraction and transmission electron microscopy. Magnetic properties as coercivity, hysteresis loop shift, and evolution of magnetization with temperature have been analyzed for different oxide crystallization stages. A decrease of the exchange anisotropy strength is reported as the structural disorder of the surface oxide layer is decreased with thermal treatment

Field and temperature dependence of magnetization in FeCu-based amorphous alloys

In this paper, the production of FeCu-based FeCuZr amorphous alloys by ball milling is reported. The thermal dependence of magnetization for the [Fe_(0.5)Cu_(0.5)]_85Zr_(15) (at. %) amorphous alloy has been found to show a dramatic field dependence of the kink point of the magnetization. This kink corresponds to a temperature different from the Curie temperature, above 400 K, of the ferromagnetic phase, which, according to spin waves fitting, can be induced by applying external fields. Just above 235 K, the thermoremanence increases sharply, and this feature strongly suggests an increase of the ferromagnetic ordering under zero field heating. Neutron diffraction experiments seem to confirm the enhancement of spin alignment. The thermal expansion above the compensation temperature is proposed to be the origin of the thermoremanence enhancement through the anti-Invar effect as might be explained within the framework of recent ab initio calculations [M. van Schilfgaarde et al., Nature (London) 400, 46 (1999)]

Evidence of spin disorder at the surface–core interface of oxygen passivated Fe nanoparticles

Hysteresis, thermal dependence of magnetization, and coercivity of oxide coated ultrafine Fe particles prepared by inert gas condensation and oxygen passivation have been studied in the 5–300 K range. The results are found to be consistent with a spin-glasslike state of the oxide layer inducing, through exchange interaction with the ferromagnetic core, a shift of the field cooled hysteresis loops at temperatures below the freezing at approximately 50 K.Dirección General de Investigación y Desarrollo. Gobierno de España-CICYT MAT95- 1042-C02-02Dirección General de Investigación y Desarrollo. Gobierno de España-PB96-0863-C02-02.Comisión Europea-ERBFMBI-CT95-0534

Structural and magnetic characterization of oleic acid and oleylamine-capped gold nanoparticles

In this work the study of oleic acid and oleylamine-capped gold nanoparticles is presented. The structural characterization of the sample shows 6.7 nm gold nanoparticles with a narrow size distribution. The experimental optical absorption spectrum has a maximum at 2.35 eV. The calculated optical absorption spectrum is shifted and narrower than the experimental one, indicating that the oleic acid and oleylamine do not merely passivate the metallic nanoparticles but modify its electronic structure. These gold nanoparticles show in addition a kind of magnetic order similar to other organic passivated gold nanoparticles as thiol-capped gold nanoparticles. Although the magnetic interactions seem to be weaker than in thiol-capped ones, the magnetic behavior looks similar to that, i.e., an invariant temperature dependence of the magnetization from 5 to 300 K and a noticeable coercive field. We analyze the influence of the organic layer bonding the nanoparticles on the magnetic behavior. © 2006 American Institute of Physics.Financial support from the Spanish MCyT under Project No. MAT2002–04246-c05–05 and CAM under Project No. S-0505/MAT/0194 are acknowledged.Peer Reviewe

Thermoremanence anomaly in Fe-Zr(B,Cu) Invar metallic glasses: Volume expansion induced ferromagnetism

We report the existence of a thermally induced sharp increase of thermoremanence around the Curie temperature of Invar-like Fe-Zr(B,Cu) soft magnetic glasses. Neutron-diffraction measurements indicate that a true enhancement of the average local magnetic moment, rather than only a change in the domain structure, occurs. Such enhancement has been tentatively attributed to the increasing volume expansion that takes place beyond the Curie temperature and reinforces ferromagnetism in some low-density clusters

Dependence of exchange anisotropy and coercivity on the Fe–oxide structure in oxygen-passivated Fe nanoparticles

3 pages, 5 figures.Ultrafine Fe particles have been prepared by the inert gas condensation method and subsequently oxygen passivated. The as-obtained particles consist in an Fe core surrounded by an amorphous Fe-oxide surface layer. The antiferromagnetic character of the Fe-oxide surface induces an exchange anisotropy in the ferromagnetic Fe core when the system is field cooled. Samples have been heat treated in vacuum at different temperatures. Structural changes of the Fe–O layer have been monitored by x-ray diffraction and transmission electron microscopy. Magnetic properties as coercivity, hysteresis loop shift, and evolution of magnetization with temperature have been analyzed for different oxide crystallization stages. A decrease of the exchange anisotropy strength is reported as the structural disorder of the surface oxide layer is decreased with thermal treatment.Peer reviewe

Structural and magnetic characterization of oleic acid and oleylamine-capped gold nanoparticles

In this work the study of oleic acid and oleylamine-capped gold nanoparticles is presented. The structural characterization of the sample shows 6.7 nm gold nanoparticles with a narrow size distribution. The experimental optical absorption spectrum has a maximum at 2.35 eV. The calculated optical absorption spectrum is shifted and narrower than the experimental one, indicating that the oleic acid and oleylamine do not merely passivate the metallic nanoparticles but modify its electronic structure. These gold nanoparticles show in addition a kind of magnetic order similar to other organic passivated gold nanoparticles as thiol-capped gold nanoparticles. Although the magnetic interactions seem to be weaker than in thiol-capped ones, the magnetic behavior looks similar to that, i.e., an invariant temperature dependence of the magnetization from 5 to 300 K and a noticeable coercive field. We analyze the influence of the organic layer bonding the nanoparticles on the magnetic behavior