A review on the corrosion behaviour of nanocoatings on metallic substrates

Growth in nanocoatings technology is moving towards implementing nanocoatings in many sectors of the industry due to their excellent abilities. Nanocoatings offer numerous advantages, including surface hardness, adhesive strength, long-term and/or high-temperature corrosion resistance, the enhancement of tribological properties, etc. In addition, nanocoatings can be applied in thinner and smoother thickness, which allows flexibility in equipment design, improved efficiency, lower fuel economy, lower carbon footprints, and lower maintenance and operating costs. Nanocoatings are utilised efficiently to reduce the effect of a corrosive environment. A nanocoating is a coating that either has constituents in the nanoscale, or is composed of layers that are less than 100 nm. The fine sizes of nanomaterials and the high density of their ground boundaries enable good adhesion and an excellent physical coverage of the coated surface. Yet, such fine properties might form active sites for corrosion attack. This paper reviews the corrosion behaviour of metallic, ceramic, and nanocomposite coatings on the surface of metallic substrates. It summarises the factors affecting the corrosion of these substrates, as well as the conditions where such coatings provided required protection. 2018 by the authors.Acknowledgments: This work was supported by Hamad Bin Khalifa University, College of Science and Engineering, Sustainable Development Division, Doha, Qatar. The publication of this article was funded by the Qatar National Library.Scopu

Effect of Carboxylic Functional Group Functionalized on Carbon Nanotubes Surface on the Removal of Lead from Water

The adsorption mechanism of the removal of lead from water by using carboxylic functional group (COOH) functionalized on the surface of carbon nanotubes was investigated. Four independent variables including pH, CNTs dosage, contact time, and agitation speed were carried out to determine the influence of these parameters on the adsorption capacity of the lead from water. The morphology of the synthesized multiwall carbon nanotubes (MWCNTs) was characterized by using field emission scanning electron microscopy (FESEM) and transmission electron microscopy (TEM) in order to measure the diameter and the length of the CNTs. The diameters of the carbon nanotubes were varied from 20 to 40 nm with average diameter at 24 nm and 10 micrometer in length. Results of the study showed that 100% of lead was removed by using COOH-MCNTs at pH 7, 150 rpm, and 2 hours. These high removal efficiencies were likely attributed to the strong affinity of lead to the physical and chemical properties of the CNTs. The adsorption isotherms plots were well fitted with experimental data

Preparation and characterization of polyamidoxime chelating resin from rubberwood fibre-g-polyacrylonitrile

Grafted rubberwood fibre was converted to polyamidoxime ion-exchange resin in order to remove heavy metal ions from aqueous solution. The cation-exchange resin existed predominantly in the syn-hydroxyamino form. The water uptake by the resin was ca. 31 g/g dry resin while its hydrogen ion capacity was 3.6 mmol/g. The adsorption capacity of the resin towards different metal ions from wastewater was determined at different pH values within the range 1–6. The prepared chelating ion-exchanger exhibited the highest adsorption capacity towards Cu2+ ions (3.83 mmol/g), followed by Cd2+,Fe3+, Pb2+, Ni2+ and Co3+ ions, respectively. The results showed that the adsorption capacity depended on the solution pH. Polyamidoxime ion-exchange resin was also used to separate Co3+ and Ni2+ ions from Cu2+ ions using a column technique. On passing Cu2+/Ni2+ and Cu2+/Co3+ ion mixtures through the resin at pH 3, Cu2+ ions were adsorbed by the resin but no sorption of Ni2+ or Co3+ ions was detected. Approximately 98% of the Cu2+ ions could be desorbed from the resin. FT-IR spectroscopy was used to confirm the conversion of polyacrylonitrile-g-rubberwood fibre to polyamidoxime

Engineering the Surface and Mechanical Properties of Water Desalination Membranes Using Ultralong Carbon Nanotubes

In this work, novel polysulphone (PS) porous membranes for water desalination, incorporated with commercial and produced carbon nanotubes (CNT), were fabricated and analyzed. It was demonstrated that changing the main characteristics of CNT (e.g., loading in the dope solutions, aspect ratio, and functionality) significantly affected the membrane properties and performance including porosity, water flux, and mechanical and surface properties. The water flux of the fabricated membranes increased considerably (up to 20 times) along with the increase in CNT loading. Conversely, yield stress and Young’s modulus of the membranes dropped with the increase in the CNT loading mainly due to porosity increase. It was shown that the elongation at fracture for PS/0.25 wt. % CNT membrane was much higher than for pristine PS membrane due to enhanced compatibility of commercial CNTs with PS matrix. More pronounced effect on membrane’s mechanical properties was observed due to compatibility of CNTs with PS matrix when compared to other factors (i.e., changes in the CNT aspect ratio). The water contact angle for PS membranes incorporated with commercial CNT sharply decreased from 73° to 53° (membrane hydrophilization) for membranes with 0.1 and 1.0 wt. % of CNTs, while for the same loading of produced CNTs the water contact angles for the membrane samples increased from 66° to 72°. The obtained results show that complex interplay of various factors such as: loading of CNT in the dope solutions, aspect ratio, and functionality of CNT. These features can be used to engineer membranes with desired properties and performance

Micro-Nano Scale Surface Coating for Nucleate Boiling Heat Transfer: A Critical Review

Nucleate boiling is a phase change heat transfer process with a wide range of applications i.e., steam power plants, thermal desalination, heat pipes, domestic heating and cooling, refrigeration and air-conditioning, electronic cooling, cooling of turbo-machinery, waste heat recovery and much more. Due to its quite broad range of applications, any improvement in this area leads to significant economic, environmental and energy efficiency outcomes. This paper presents a comprehensive review and critical analysis on the recent developments in the area of micro-nano scale coating technologies, materials, and their applications for modification of surface geometry and chemistry, which play an important role in the enhancement of nucleate boiling heat transfer. In many industrial applications boiling is a surface phenomenon, which depends upon its variables such as surface area, thermal conductivity, wettability, porosity, and roughness. Compared to subtractive methods, the surface coating is more versatile in material selection, simple, quick, robust in implementation and is quite functional to apply to already installed systems. The present status of these techniques for boiling heat transfer enhancement, along with their future challenges, enhancement potentials, limitations, and their possible industrial implementation are also discussed in this paper

Corrosion Behaviour of 316L Stainless Steel in CNTs–Water Nanofluid: Effect of Temperature

The inhibition behavior of carbon nanotubes (CNTs) and Gum Arabic (GA) on the corrosion of 316L stainless steel in CNTs–water nanofluid under the effect of different temperatures was investigated by electrochemical methods and surface analysis techniques. Thereby, 316L stainless steel samples were exposed to CNTs–water nanofluid under temperatures of 22, 40, 60 and 80 °C. Two concentrations of the CNTs (0.1 and 1.0 wt.% CNTs) were homogenously dispersed in deionized water using the surfactant GA and tested using three corrosion tests conducted in series: open circuit test, polarization resistance test, and potentiodynamic scans. These tests were also conducted on the same steel but in solutions of GA-deionized water only. Tests revealed that corrosion increases with temperature and concentration of the CNTs–water nanofluids, having the highest corrosion rate of 32.66 milli-mpy (milli-mil per year) for the 1.0 wt.% CNT nanofluid at 80 °C. In addition, SEM observations showed pits formation around areas of accumulated CNTs that added extra roughness to the steel sample. The activation energy analysis and optical surface observations have revealed that CNTs can desorb at higher temperatures, which makes the surface more vulnerable to corrosion attack

Corrosion Evaluation of 316L Stainless Steel in CNT-Water Nanofluid: Effect of CNTs Loading

Polarization resistance and potentiodynamic scan testing were performed on 316L stainless steel (SS) at room temperature in carbon nanotube (CNT)-water nanofluid. Different CNT loadings of 0.05, 0.1, 0.3 and 0.5 wt% were suspended in deionized water using gum arabic (GA) surfactant. Corrosion potential, Tafel constants, corrosion rates and pitting potential values indicated better corrosion performance in the presence of CNTs with respect to samples tested in GA-water solutions. According to Gibbs free energy of adsorption, CNTs were physically adsorbed into the surface of the metal, and this adsorption followed Langmuir adsorption isotherm type II. Samples tested in CNT nanofluid revealed a corrosion performance comparable to that of tap water and better than that for GA-water solutions. Among all samples tested in CNT nanofluids, the lowest corrosion rate was attained with 0.1 wt% CNT nanofluid, while the highest value was obtained with 0.5 wt% CNT nanofluid. At higher CNT concentrations, accumulated CNTs might form active anodic sites and increase the corrosion rate. SEM images for samples of higher CNT loadings were observed to have higher pit densities and diameters

Effect of PEG functionalized carbon nanotubes on the enhancement of thermal and physical properties of nanofluids

In this study, pristine carbon nanotubes and polyethylene glycol functionalized carbon nanotubes (CNT-PEG) have been used to enhance the heat capacity, viscosity, thermal conductivity, heat transfer rate and pressure drop of nanofluids. Multi-walled carbon nanotubes (MWCNT) were functionalized with polyethylene glycol (PEG) using a Fischer esterification method to improve their dispersion in aqueous media. Three concentrations of 0.01 wt%, 0.05 wt% and 0.1 wt% of pristine and functionalized CNTs in the nanofluids have been used. The heat-transfer rate and pressure drop of these nanofluids have been measured in a shell and tube heat exchanger. Differential Scanning Calorimetry (DSC) was used to study the specific heat capacity of the nanofluids. The specific heat capacity of pristine and functionalized CNTs mixed with water was found to be significantly higher than of the pure water by 10% and 45% respectively. The results of the heat transfer of the nanofluids increased suddenly with the increasing the concentrations of both pristine and functionalized CNTs. It can be concluded that the functionalizing CNT with Polyethylene glycol enhanced the dispersion of the CNTs and increased their heat capacities. The viscosity of the nanofluids was found to be dependent on the concentration of CNTs in solution. The pressure drop of the nanofluid compared with that of pure water was almost unchanged resulting in no extra pumping energy penalty.The authors would like to acknowledge the support provided by King Abdulaziz City for Science and Technology (KACST) through Science & Technology Unit at King Fahd University of petroleum & Minerals (KFUPM) for funding this work through project No: 09-NAN758-04 titled “Experimental Investigation of Heat Transfer Characterization for CNT-Nanofluid in Heat Exchangers” as part of the National Science Technology and Innovation Plan (NSTIP)