172 research outputs found
What is the true charge transfer gap in parent insulating cuprates?
A large body of experimental data point towards a charge transfer instability
of parent insulating cuprates to be their unique property. We argue that the
true charge transfer gap in these compounds is as small as 0.4-0.5\,eV rather
than 1.5-2.0\,eV as usually derived from the optical gap measurements. In fact
we deal with a competition of the conventional (3d) ground state and a
charge transfer (CT) state with formation of electron-hole dimers which evolves
under doping to an unconventional bosonic system. Our conjecture does provide
an unified standpoint on the main experimental findings for parent cuprates
including linear and nonlinear optical, Raman, photoemission, photoabsorption,
and transport properties anyhow related with the CT excitations. In addition we
suggest a scenario for the evolution of the CuO planes in the CT unstable
cuprates under a nonisovalent doping.Comment: 13 pages, 5 figures, submitted to PR
Non collinear magnetism and single ion anisotropy in multiferroic perovskites
The link between the crystal distortions of the perovskite structure and the
magnetic exchange interaction, the single-ion anisotropy (SIA) and the
Dzyaloshinsky-Moriya (DM) interaction are investigated by means of
density-functional calculations. Using BiFeO and LaFeO as model
systems, we quantify the relationship between the oxygen octahedra rotations,
the ferroelectricity and the weak ferromagnetism (wFM). We recover the fact
that the wFM is due to the DM interaction induced by the oxygen octahedra
rotations. We find a simple relationship between the wFM, the oxygen rotation
amplitude and the ratio between the DM vector and the exchange parameter such
as the wFM increases with the oxygen octahedra rotation when the SIA does not
compete with the DM forces induced on the spins. Unexpectedly, we also find
that, in spite of the electronic configuration of Fe, the SIA is
very large in some structures and is surprisingly strongly sensitive to the
chemistry of the -site cation of the BO perovskite. In the ground
state phase we show that the SIA shape induced by the ferroelectricity
and the oxygen octahedra rotations are in competition such as it is possible to
tune the wFM "on" and "off" through the relative size of the two types of
distortion
Microscopic mechanisms of spin-dependent electric polarization in 3d oxides
We present a short critical overview of different microscopic models for
nonrelativistic and relativistic magnetoelectric coupling including the
so-called "spin current scenario", ab-initio calculations, and several recent
microscopic approaches to a spin-dependent electric polarization in 3d oxides.Comment: 8 pages, 3 figure
Dzyaloshinsky-Moriya antisymmetric exchange coupling in cuprates: Oxygen effects
We revisit a problem of Dzyaloshinsky-Moriya antisymmetric exchange coupling
for a single bond in cuprates specifying the local spin-orbital contributions
to Dzyaloshinsky vector focusing on the oxygen term. The Dzyaloshinsky vector
and respective weak ferromagnetic moment is shown to be a superposition of
comparable and, sometimes, competing local Cu and O contributions. The
intermediate oxygen O Knight shift is shown to be an effective tool to
inspect the effects of Dzyaloshinsky-Moriya coupling in an external magnetic
field. We predict the effect of oxygen weak antiferromagnetism in
edge-shared CuO chains due to uncompensated oxygen Dzyaloshinsky vectors.
Finally, we revisit the effects of symmetric spin anisotropy, in particular,
those directly induced by Dzyaloshinsky-Moriya coupling.Comment: 12 pages, 2 figures, submitted to JET
Nonbonding oxygen holes and spinless scenario of magnetic response in doped cuprates
Both theoretical considerations and experimental data point to a more
complicated nature of the valence hole states in doped cuprates than it is
predicted by Zhang-Rice model. Actually, we deal with a competition of
conventional hybrid Cu 3d-O 2p state and purely
oxygen nonbonding state with symmetry. The latter
reveals a non-quenched Ising-like orbital moment that gives rise to a novel
spinless purely oxygen scenario of the magnetic response in doped cuprates with
the oxygen localized orbital magnetic moments of the order of tenths of Bohr
magneton. We consider the mechanism of Cu-O 2p transferred orbital
hyperfine interactions due to the mixing of the oxygen O 2p orbitals with Cu 3p
semicore orbitals. Quantitative estimates point to a large magnitude of the
respective contributions both to local field and electric field gradient, and
their correlated character.Comment: 7 pages, 1 figur
Topological phase separation in 2D quantum lattice Bose-Hubbard system away from half-filling
We suppose that the doping of the 2D hard-core boson system away from
half-filling may result in the formation of multi-center topological
inhomogeneity (defect) such as charge order (CO) bubble domain(s) with Bose
superfluid (BS) and extra bosons both localized in domain wall(s), or a {\it
topological} CO+BS {\it phase separation}, rather than an uniform mixed CO+BS
supersolid phase. Starting from the classical model we predict the properties
of the respective quantum system. The long-wavelength behavior of the system is
believed to remind that of granular superconductors, CDW materials, Wigner
crystals, and multi-skyrmion system akin in a quantum Hall ferromagnetic state
of a 2D electron gas. To elucidate the role played by quantum effects and that
of the lattice discreteness we have addressed the simplest nanoscopic
counterpart of the bubble domain in a checkerboard CO phase of 2D hc-BH square
lattice. It is shown that the relative magnitude and symmetry of
multi-component order parameter are mainly determined by the sign of the
and transfer integrals. In general, the topologically inhomogeneous phase
of the hc-BH system away from the half-filling can exhibit the signatures both
of , and symmetry of the off-diagonal order.Comment: 12 pages, 6 figure
Topological phase separation in 2D hard-core Bose-Hubbard system away from half-filling
We suppose that the doping of the 2D hard-core boson system away from
half-filling may result in the formation of multi-center topological defect
such as charge order (CO) bubble domain(s) with Bose superfluid (BS) and extra
bosons both localized in domain wall(s), or a {\it topological} CO+BS {\it
phase separation}, rather than an uniform mixed CO+BS supersolid phase.
Starting from the classical model we predict the properties of the respective
quantum system. The long-wavelength behavior of the system is believed to
remind that of granular superconductors, CDW materials, Wigner crystals, and
multi-skyrmion system akin in a quantum Hall ferromagnetic state of a 2D
electron gas.Comment: 6 pages, 1 figur
One-Center Charge Transfer Transitions in Manganites
In frames of a rather conventional cluster approach, which combines the
crystal field and the ligand field models we have considered different charge
transfer (CT) states and O 2p-Mn 3d CT transitions in MnO octahedra.
The many-electron dipole transition matrix elements were calculated using the
Racah algebra for the cubic point group. Simple "local" approximation allowed
to calculate the relative intensity for all dipole-allowed and
CT transitions. We present a self-consistent description of
the CT bands in insulating stoichiometric LaMnO compound with the
only Mn valent state and idealized octahedral MnO centers
which allows to substantially correct the current interpretation of the optical
spectra. Our analysis shows the multi-band structure of the CT optical response
with the weak low-energy edge at 1.7 eV, associated with forbidden
transition and a series of the weak and strong
dipole-allowed high-energy transitions starting from 2.5 and 4.5 eV,
respectively, and extending up to nearly 11 eV. The most intensive features are
associated with two strong composite bands near eV and
eV, respectively, resulting from the superposition of the dipole-allowed
and CT transitions. These predictions are in good
agreement with experimental spectra. The experimental data point to a strong
overscreening of the crystal field parameter in the CT states of
MnO centers.Comment: 10 pages, 3 figure
Lattice Distortion and Magnetism of 3d- Perovskite Oxides
Several puzzling aspects of interplay of the experimental lattice distortion
and the the magnetic properties of four narrow -band perovskite oxides
(YTiO, LaTiO, YVO, and LaVO) are clarified using results of
first-principles electronic structure calculations. First, we derive parameters
of the effective Hubbard-type Hamiltonian for the isolated bands using
newly developed downfolding method for the kinetic-energy part and a hybrid
approach, based on the combination of the random-phase approximation and the
constraint local-density approximation, for the screened Coulomb interaction
part. Then, we solve the obtained Hamiltonian using a number of techniques,
including the mean-field Hartree-Fock (HF) approximation, the second-order
perturbation theory for the correlation energy, and a variational superexchange
theory. Even though the crystal-field splitting is not particularly large to
quench the orbital degrees of freedom, the crystal distortion imposes a severe
constraint on the form of the possible orbital states, which favor the
formation of the experimentally observed magnetic structures in YTiO,
YVO_, and LaVO even at the HF level. Beyond the HF approximation, the
correlations effects systematically improve the agreement with the experimental
data. Using the same type of approximations we could not reproduce the correct
magnetic ground state of LaTiO. However, we expect that the situation may
change by systematically improving the level of approximations for dealing with
the correlation effects.Comment: 30 pages, 17 figures, 8 tables, high-quality figures are available
via e-mai
Crystal Field and Dzyaloshinsky-Moriya Interaction in orbitally ordered La_{0.95}Sr_{0.05}MnO_3: An ESR Study
We present a comprehensive analysis of Dzyaloshinsky-Moriya interaction and
crystal-field parameters using the angular dependence of the paramagnetic
resonance shift and linewidth in single crystals of La_{0.95}Sr_{0.05}MnO_3
within the orthorhombic Jahn-Teller distorted phase. The Dzyaloshinsky-Moriya
interaction (~ 1K) results from the tilting of the MnO_6 octahedra against each
other. The crystal-field parameters D and E are found to be of comparable
magnitude (~ 1K) with D ~= -E. This indicates a strong mixing of the |3z^2-r^2>
and |x^2-y^2> states for the real orbital configuration.Comment: 12 pages, 6 figure
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