Vertical Resolved Dust Mass Concentration and Backscatter Coefficient Retrieval of Asian Dust Plume Using Quartz Raman Channel in Lidar Measurements

In this work, we present a method for estimating vertical resolved mass concentration of dust immersed in Asian dust plume using Raman scattering of quartz (silicon dioxide, silica). During the Asian dust period of March 15, 16, and 21 in 2010, Raman lidar measurements detected the presence of quartz, and successfully showed the vertical profiles of the quartz backscatter coefficient. Since the Raman backscatter coefficient was connected with the Raman backscatter differential cross section and the number density of quartz molecules, the mass concentration of quartz in the atmosphere can be estimated from the quartz backscatter coefficient. The weight percentage from 40 to 70 % for quartz in the Asian dust was estimated from references. The vertical resolved mass concentration of dust was estimated by quartz mass concentration and weight percentage. We also present a retrieval method to obtain dust backscatter coefficient from the mixed Asian dust and pollutant layer. OPAC (Optical Properties of Aerosol and Clouds) simulations were conducted to calculate dust backscatter coefficient. The retrieved dust mass concentration was used as an input parameter for the OPAC calculations. These approaches in the study will be useful for characterizing the quartz dominated in the atmospheric aerosols and estimating vertical resolved mass concentration of dust. It will be especially applicable for optically distinguishing the dust and non-dust aerosols in studies on the mixing state of Asian dust plume. Additionally, the presented method combined with satellite observations is enable qualitative and quantitative monitoring for Asian dust

Application of the method of decomposition of lidar signal-to-noise ratio to the assessment of laser instruments for gaseous pollution detection

A general methodology for rating both performance and potential of lidar systems used for detection of atmospheric trace constituents including pollutants and gas leaks is developed. By individually examining and decomposing the contribution of both lidar system parameters and atmospheric operating conditions on signal-to-noise-ratio, a generalized figure of merit, V, for lidar quality is introduced and evolved. Computer simulations based on V and atmospheric parameters are carried out to determine achievable lidar performance. A simple design procedure is outlined for determination of lidar instrumentation parameters to ensure the best monitoring efficiency for a given set of initial parameters/requirements, including operation range, minimum detectable gas concentration, and so on.Postprint (published version

X-Ray Study of Pressure-Collapsed Fullerite

X-ray-diffraction studies are described for a new phase of carbon called collapsed fullerite (CF) that was produced by application of high pressure to fullerite (C$_{60}$). At $\sim$20 GPa there is an irreversible transition to a phase that has neither the (111) Bragg peak of diamond nor any of the Bragg peaks associated with the fcc phase of C$_{60}$. The spectrum of CF is flat and featureless in the range of study.Engineering and Applied Science

Coherent Doppler Lidar for Wind Sensing

An eye-safe all-fiber Coherent Doppler Lidar for wind sensing system has been developed and tested at the Remote Sensing Laboratory of the City College of New York, New York, NY. The system, which operates at a 20 kHz pulse repetition rate and acquires lidar return signals at 400 MSample/s, accumulates signals that are as much as 20 dB lower than the receiver noise power by using embedded programming techniques. Two FPGA embedded programming algorithms are designed and compared. In the first algorithm, power spectra of return signals are calculated and accumulated for different range gates. Line of sight wind speed estimates can then be calculated after transferring the range gated accumulated power spectra to a host computer. In the second FPGA algorithm, a digital IQ demodulator and down sampler allow an autocorrelation matrix representing a pre-selected number of lags to be accumulated. Precision in the velocity measurements is estimated to be on the order of 0.08 m/s and the precision in the measured horizontal wind direction is estimated to be to be about 2°

Observed sea breeze life cycle in and around NYC: Impacts on UHI and ozone patterns

This observational study investigates New York City (NYC) impacts on summer sea breeze fronts (SBFs) during a 2018 LISTOS Campaign day with a regional heat wave and O3 episode. A morning urban heat island peaked at 8.3 °C and then induced convergences into the City, trapping its NO2 emissions. SBFs came ashore at 0700 EST from the Atlantic along southern Long Island (LI), and from the LI Sound along northern LI and southern Connecticut; 2-h later another formed over New Jersey. The Ocean front was retarded over NYC at noon, while all fronts merged by 1400 EST and continued inland for four more hours. High O3 first appeared at 0900 EST downwind of NYC. By 1100 EST, a new surface peak formed north of the City in the Hudson River Valley (HRV). The maxima merged, peaking at 143 ppb at 1300 EST behind the SBF and near the maximum temperatures of 39 °C. Trajectories ending at the northern LI site with a PBL O3 peak first passed NYC, arrived before the episode, and then recirculated back in its SB flow. Trajectories ending in the HRV showed pollutant transport over NYC twice, before advection northward into the narrow Valley by the ocean SBF

Simulation of Cloud-aerosol Lidar with Orthogonal Polarization (CALIOP) attenuated backscatter profiles using the Global Model of Aerosol Processes (GLOMAP)

To permit the calculation of the radiative effects of atmospheric aerosols, we have linked our aerosol-chemical transport model (CTMGLOMAP) to a new radiation module (UKCARADAER). In order to help assess and improve the accuracy of the radiation code, in particular the height dependence of the predicted scattering, we have developed a module that simulates attenuated backscatter (ABS) profiles that would be measured by the satellite-borne Cloud-Aerosol Lidar with Orthogonal Polarization (CALIOP) if it were to sample an atmosphere with the same aerosol loading as predicted by the CTM. Initial results of our comparisons of the predicted ABS profiles with actual CALIOP data are encouraging but some differences are noted, particularly in marine boundary layers where the scattering is currently under-predicted and in dust layers where it is often over-predicted. The sources of these differences are being investigated

A quantum fluid of metallic hydrogen suggested by first-principles calculations

It is generally assumed that solid hydrogen will transform into a metallic alkali-like crystal at sufficiently high pressure. However, some theoretical models have also suggested that compressed hydrogen may form an unusual two-component (protons and electrons) metallic fluid at low temperature, or possibly even a zero-temperature liquid ground state. The existence of these new states of matter is conditional on the presence of a maximum in the melting temperature versus pressure curve (the 'melt line'). Previous measurements of the hydrogen melt line up to pressures of 44 GPa have led to controversial conclusions regarding the existence of this maximum. Here we report ab initio calculations that establish the melt line up to 200 GPa. We predict that subtle changes in the intermolecular interactions lead to a decline of the melt line above 90 GPa. The implication is that as solid molecular hydrogen is compressed, it transforms into a low-temperature quantum fluid before becoming a monatomic crystal. The emerging low-temperature phase diagram of hydrogen and its isotopes bears analogies with the familiar phases of 3He and 4He, the only known zero-temperature liquids, but the long-range Coulombic interactions and the large component mass ratio present in hydrogen would ensure dramatically different propertiesComment: See related paper: cond-mat/041040

Vertical Profiles of Aerosol Optical and Microphysical Properties During a Rare Case of Long-range Transport of Mixed Biomass Burning-polluted Dust Aerosols from the Russian Federation-kazakhstan to Athens, Greece

Multi-wavelength aerosol Raman lidar measurements with elastic depolarization at 532 nm were combined with sun photometry during the HYGRA-CD campaign over Athens, Greece, on May-June 2014. We retrieved the aerosol optical [3 aerosol backscatter profiles (baer) at 355-532-1064 nm, 2 aerosol extinction (aaer) profiles at 355-532 nm and the aerosol linear depolarization ratio (δ) at 532 nm] and microphysical properties [effective radius (reff), complex refractive index (m), single scattering albedo (ω)]. We present a case study of a long distance transport (~3.500-4.000 km) of biomass burning particles mixed with dust from the Russian Federation-Kazakhstan regions arriving over Athens on 21-23 May 2014 (1.7-3.5 km height). On 23 May, between 2-2.75 km we measured mean lidar ratios (LR) of 35 sr (355 nm) and 42 sr (532 nm), while the mean Ångström exponent (AE) aerosol backscatter-related values (355nm/532nm and 532nm/1064nm) were 2.05 and 1.22, respectively; the mean value of δ at 532 nm was measured to be 9%. For that day the retrieved mean aerosol microphysical properties at 2-2.75 km height were: reff=0.26 μm (fine mode), reff=2.15 μm (coarse mode), m=1.36+0.00024i, ω=0.999 (355 nm, fine mode), ω=0.992(355 nm, coarse mode), ω=0.997 (532 nm, fine mode), and ω=0.980 (532 nm, coarse mode)

Reversible Pressure-Induced Amorphization in Solid C70 : Raman and Photoluminescence Study

We have studied single crystals of $C_{70}$ by Raman scattering and photoluminescence in the pressure range from 0 to 31.1 GPa. The Raman spectrum at 31.1 GPa shows only a broad band similar to that of the amorphous carbon without any trace of the Raman lines of $C_{70}$. After releasing the pressure from 31.1 GPa, the Raman and the photoluminescence spectra of the recovered sample are that of the starting $C_{70}$ crystal. These results indicate that the $C_{70}$ molecules are stable upto 31.1 GPa and the amorphous carbon high pressure phase is reversible, in sharp contrast to the results on solid $C_{60}$. A qualitative explaination is suggested in terms of inter- versus intra-molecular interactions.Comment: To appear in Phys. Rev. Lett., 12 pages, RevTeX (preprint format), 3 figures available upon reques

Third order dielectric susceptibility in a model quantum paraelectric

In the context of perovskite quantum paraelectrics, we study the effects of a quadrupolar interaction $J_q$, in addition to the standard dipolar one $J_d$. We concentrate here on the nonlinear dielectric response $\chi_{P}^{(3)}$, as the main response function sensitive to quadrupolar (in our case antiquadrupolar) interactions. We employ a 3D quantum four-state lattice model and mean-field theory. The results show that inclusion of quadrupolar coupling of moderate strength ($J_q \sim {{1}\over{4}} J_d$) is clearly accompanied by a double change of sign of $\chi_{P}^{(3)}$ from negative to positive, near the quantum temperature $T_Q$ where the quantum paraelectric behaviour sets in. We fit our $\chi_{P}^{(3)}$ to recent experimental data for SrTiO$_3$, where the sign change is identified close to $T_Q \sim 37 K$.Comment: 22 page