5 research outputs found
Influence of the bridging tetrazole containing ligands on magnetic properties of 3d metal complexes.
catena-Poly[cobalt(II)-di-μ-chlorido-κ4 Cl:Cl-μ-1,5-dimethyl-1H-tetraÂzole-κ2 N 3:N 4]: an X-ray powder investigation
The asymmetric unit of the title compound, [CoCl2(C3H6N4)]n, contains two Co atoms, both lying on inversion centres, two Cl atoms and one 1,5-dimethylÂtetraÂzole ligand. The coordination polyhedra of both Co atoms adopt flattened octaÂhedral geometry, with two N atoms from two ligands in axial positions and four Cl atoms in equatorial sites. Neighbouring Co atoms are linked together via two bridging Cl atoms and one tetraÂzole ring to form polymeric chains running along the a axis