Stability of Breakwater Armor Units against Tsunami Attacks

The design of breakwater armour units against tsunami attacks has received little attention in the past because of the comparative low frequency of these events and the rarity of structures designed specifically to withstand them. However, field surveys of recent events, such as the 2011 Great Eastern Japan Earthquake Tsunami and the 2004 Indian Ocean Tsunami, have shown flaws in the design of protection structures. During these extreme events, many breakwaters suffered partial or catastrophic damage. Although it is to be expected that most normal structures fail due to such high order events, practicing engineers need to possess tools to design certain important breakwaters that should not fail even during level 2 events. Research into the design of critical structures that only partially fail (i.e., “resilient” or “tenacious” structures) during a very extreme level 2 tsunami event should be prioritized in the future, and in this sense the present paper proposes a formula that allows the estimation of armour unit damage depending on the tsunami wave height

Exploiting non-covalent π interactions for catalyst design

Molecular recognition, binding and catalysis are often mediated by non-covalent interactions involving aromatic functional groups. Although the relative complexity of these so-called π interactions has made them challenging to study, theory and modelling have now reached the stage at which we can explain their physical origins and obtain reliable insight into their effects on molecular binding and chemical transformations. This offers opportunities for the rational manipulation of these complex non-covalent interactions and their direct incorporation into the design of small-molecule catalysts and enzymes