5,274 research outputs found
Analysis and Model-Based Description of the Total Process of Periodic Deactivation and Regeneration of a VOx Catalyst for Selective Dehydrogenation of Propane
This study intends to provide insights into various aspects related to the reaction kinetics of the VOx catalyzed propane dehydrogenation including main and side reactions and, in particular, catalyst deactivation and regeneration, which can be hardly found in combination in current literature. To kinetically describe the complex reaction network, a reduced model was fitted to lab scale experiments performed in a fixed bed reactor. Additionally, thermogravimetric analysis (TGA) was applied to investigate the coking behavior of the catalyst under defined conditions considering propane and propene as precursors for coke formation. Propene was identified to be the main coke precursor, which agrees with results of experiments using a segmented fixed bed reactor (FBR). A mechanistic multilayer-monolayer coke growth model was developed to mathematically describe the catalyst coking. Samples from long-term deactivation experiments in an FBR were used for regeneration experiments with oxygen to gasify the coke deposits in a TGA. A power law approach was able to describe the regeneration behavior well. Finally, the results of periodic experiments consisting of several deactivation and regeneration cycles verified the long-term stability of the catalyst and confirmed the validity of the derived and parametrized kinetic models for deactivation and regeneration, which will allow model-based process development and optimization
Multi-Component Dosing in Membrane Reactors Including an Internal Reactant Recycling
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Process Intensification of the Propane Dehydrogenation Considering Coke Formation, Catalyst Deactivation and RegenerationâTransient Modelling and Analysis of a Heat-Integrated Membrane Reactor
A heat-integrated packed-bed membrane reactor is studied based on detailed, transient 2D models for coupling oxidative and thermal propane dehydrogenation in one apparatus. The reactor is structured in two telescoped reaction zones to figure out the potential of mass and heat integration between the exothermic oxidative propane dehydrogenation (ODH) in the shell side, including membrane-assisted oxygen dosing and the endothermic, high selective thermal propane dehydrogenation (TDH) in the inner core. The developing complex concentration, temperature and velocity fields are studied, taking into account simultaneous coke growth corresponding with a loss of catalyst activity. Furthermore, the catalyst regeneration was included in the simulation in order to perform an analysis of a periodic operating system of deactivation and regeneration periods. The coupling of the two reaction chambers in a new type of membrane reactor offers potential at oxygen shortage and significantly improves the achievable propene yield in comparison with fixed bed and well-established membrane reactors in the distributor configuration without inner mass and heat integration. The methods developed allow an overall process optimization with respect to maximum spacetime yield as a function of production and regeneration times
Multiple sequence alignment based on set covers
We introduce a new heuristic for the multiple alignment of a set of
sequences. The heuristic is based on a set cover of the residue alphabet of the
sequences, and also on the determination of a significant set of blocks
comprising subsequences of the sequences to be aligned. These blocks are
obtained with the aid of a new data structure, called a suffix-set tree, which
is constructed from the input sequences with the guidance of the
residue-alphabet set cover and generalizes the well-known suffix tree of the
sequence set. We provide performance results on selected BAliBASE amino-acid
sequences and compare them with those yielded by some prominent approaches
Nuclear alpha-clustering, superdeformation, and molecular resonances
Nuclear alpha-clustering has been the subject of intense study since the
advent of heavy-ion accelerators. Looking back for more than 40 years we are
able today to see the connection between quasimolecular resonances in heavy-ion
collisions and extremely deformed states in light nuclei. For example
superdeformed bands have been recently discovered in light N=Z nuclei such as
Ar, Ca, Cr, and Ni by -ray spectroscopy.
The search for strongly deformed shapes in N=Z nuclei is also the domain of
charged-particle spectroscopy, and our experimental group at IReS Strasbourg
has studied a number of these nuclei with the charged particle multidetector
array {\sc Icare} at the {\sc Vivitron} Tandem facility in a systematical
manner. Recently the search for -decays in Mg has been
undertaken in a range of excitation energies where previously nuclear molecular
resonances were found in C+C collisions. The breakup reaction
MgC has been investigated at E(Mg) = 130 MeV, an
energy which corresponds to the appropriate excitation energy in Mg for
which the C+C resonance could be related to the breakup
resonance. Very exclusive data were collected with the Binary Reaction
Spectrometer in coincidence with {\sc Euroball IV} installed at the {\sc
Vivitron}.Comment: 10 pages, 4 eps figures included. Invited Talk 10th Nuclear Physics
Workshop Marie and Pierre Curie, Kazimierz Dolny Poland, Sep. 24-28, 2003; To
be published in International Journal of Modern Physics
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