Natural Polymers and Cosmeceuticals for a Healthy and Circular Life: The Examples of Chitin, Chitosan, and Lignin

The present review considers the design and introduction of new cosmeceuticals in the market, based on natural polymers and active molecules extracted from biomass, in a biomimetic strategy, starting with a consideration of the biochemical mechanisms, followed by natural precision biopolymer production. After introducing the contest of nanobiotechnology in relationship with its applicability for skin contact products and classifying the currently available sustainable polymers, some widely selected abundant biopolymers (chitin, chitosan, and lignin), showing specific functionalities (anti-microbial, anti-oxidant, anti-inflammatory, etc.), are described, especially considering the possibility to combine them in nanostructured tissues, powders, and coatings for producing new cosmeceuticals, but with potentialities in other sectors, such as biomedical, personal care, and packaging sectors. After observing the general increase in market wellness and beauty forecasts over the next few years, parallelisms between nano and macro scales have suggested that nanobiotechnology application expresses the necessity to follow a better way of producing, selecting, and consuming goods that will help to transform the actual linear economy in a circular economy, based on redesigning, reducing, recycling, and reusing

The outer filament of Centaurus A as seen by MUSE

We investigate signatures of a jet-interstellar medium (ISM) interaction using optical integral-field observations of the so-called outer filament near Centaurus A, expanding on previous results obtained on a more limited area. Using the Multi Unit Spectroscopic Explorer (MUSE) on the VLT during science verification, we observed a significant fraction of the brighter emitting gas across the outer filament. The ionized gas shows complex morphology with compact blobs, arc-like structures and diffuse emission. Based on the kinematics, we identified three main components. The more collimated component is oriented along the direction of the radio jet. The other two components exhibit diffuse morphology together with arc-like structures also oriented along the radio jet direction. Furthermore, the ionization level of the gas is found to decrease from the more collimated component to the more diffuse components. The morphology and velocities of the more collimated component confirm our earlier results that the outer filament and the nearby HI cloud are likely partially shaped by the lateral expansion of the jet. The arc-like structures embedded within the two remaining components are the clearest evidence of a smooth jet-ISM interaction along the jet direction. This suggests that, although poorly collimated, the radio jet is still active and has an impact on the surrounding gas. This result indicates that the effect on the ISM of even low-power radio jets should be considered when studying the influence Active Galactic Nuclei can have on their host galaxy.Comment: 5 pages, 3 figures, Accepted for publication by A&

The unfriendly ISM in the radio galaxy 4C12.50 (PKS 1345+12)

The radio source 4C12.50 has often been suggested to be a prime candidate for the link between ultraluminous infrared galaxies and young radio galaxies. A VLBI study of the neutral hydrogen in the nuclear regions of this object shows that most of the gas detected close to the systemic velocity is associated with an off-nuclear cloud (~50 to 100 pc from the radio core) with a column density of ~10^22 T_spin/100 K) cm^(-2) and an HI mass of a few times 10^5 to 10^6 M_sun. We consider a number of possibilities to explain the results. In particular, we discus the possibility that this cloud indicates the presence of a rich and clumpy interstellar medium in the centre, likely left over from the merger that triggered the activity and that this medium influences the growth of the radio source. The location of the cloud -- at the edge of the northern radio jet/lobe -- suggests that the radio jet might be interacting with a gas cloud. This interaction could be responsible for bending the young radio jet. The velocity profile of the gas is relatively broad (~150$ km/s) and we interpret this as kinematical evidence for interaction of the radio plasma with the cloud. We also consider the model where the cloud is part of a broader circumnuclear structure. Only a limited region of this structure would have sufficient background radio brightness and large enough column depth in neutral gas to obtain detectable HI absorption against the counterjet. The VLBI study of the neutral hydrogen in 4C12.50 suggests that HI detected near the systemic velocity (as it is often the case in radio galaxies) may not necessarily be connected with a circumnuclear disk or torus (as is very often assumed) but instead could be a tracer of the large-scale medium that surrounds the active nucleus and that may influence the growth of the young radio source.Comment: 7 pages, 2 figures. Accepted for publication in A&

Emission lines and optical continuum in low-luminosity radio galaxies

We present spectroscopic observations of a complete sub-sample of 13 low-luminosity radio galaxies selected from the 2Jy sample. The underlying continuum in these sources is carefully modelled in order to make a much-needed comparison between the emission line and continuum properties of FRIs with those of other classes of radio sources. We find that 5 galaxies in the sample show a measurable UV excess: 2 of the these sources are BL Lacs and in the remaining 3 galaxies we argue that the most likely contributor to the UV excess is a young stellar component. Excluding the BL Lacs, we therefore find that \~30% of the sample show evidence for young stars, which is similar to the results obtained for higher luminosity samples. We compare our results with far-infrared measurements in order to investigate the far-infrared-starburst link. The nature of the optical-radio correlations is investigated in light of this new available data and, in contrast to previous studies, we find that the FRI sources follow the correlations with a similar slope to that found for the FRIIs. Finally, we compare the luminosity of the emission lines in the FRI and BL Lac sources and find a significant difference in the [OIII] line luminosities of the two groups. Our results are discussed in the context of the unified schemes.Comment: 18 pages, 31 figures, MNRAS in press, (all enquiries to Clive Tadhunter ([email protected])

BeppoSAX observations of low power radio galaxies: possible detection of obscured nuclei

We present the first results of BeppoSAX observations of a small sample of low brightness FRI radio galaxies. The flux of all the targets is consistent with a thermal spectrum, as due to the presence of hot intracluster gas or galactic corona. Moreover in three sources a non thermal absorbed spectrum can be present in the MECS spectrum at energies larger than 7 keV, while for a fourth object a high energy flux has been detected in the PDS instrument at energies larger than 15 keV. This component could be related to the inner AGN surrounded by an obscuring torus.Comment: 4 pages, LateX, 3 figures (included). Uses espcrc2.sty (included). To appear in: "The Active X-ray Sky: Results from BeppoSAX and Rossi-XTE", Rome, Italy, 21-24 October, 1997, Eds.: L. Scarsi, H. Bradt, P. Giommi and F. Fior

B2 1144+35B, a giant low power radio galaxy with superluminal motion. Orientation and evidence for recurrent activity

The goal of this work is a detailed study of the nearby, low power radio galaxy B2 1144+35B. For this purpose, we performed new Very Long Baseline Array (VLBA) and Very Large Array (VLA) observations. This source has several properties (bright, nearby, large range of spatial structures, visible counterjet, etc.) that make it an excellent astrophysical laboratory for the study of the evolution of radio jets. Here we report the detection of motion in the counterjet at 0.23 $\pm$ 0.07 c, which allows us to estimate the orientation of the parsec-scale jet at 33$^\circ \pm 7^\circ$ from the line of sight, with an intrinsic velocity of (0.94$^{+0.06}_{-0.11}$)c. We also report on a brightening of the core at high frequencies which we suggest could be the result of a new component emerging from the core. High dynamic range VLBA observations at 5 GHz reveal, for the first time, extended emission connecting the core with the bright complex of emission that dominates the flux density of the parsec scale structure at frequencies below 20 GHz. The evolution of this bright complex is considered and its slow decline in flux density is interpreted as the result of an interaction with the interstellar medium of the host galaxy.Comment: 7 pages, 6 b&w figures. A&A in pres

A Deep WSRT 1.4 GHz Radio Survey of the Spitzer Space Telescope FLSv Region

The First Look Survey (FLS) is the first scientific product to emerge from the Spitzer Space Telescope. A small region of this field (the verification strip) has been imaged very deeply, permitting the detection of cosmologically distant sources. We present Westerbork Synthesis Radio Telescope (WSRT) observations of this region, encompassing a ~1 sq. deg field, centred on the verification strip (J2000 RA=17:17:00.00, DEC=59:45:00.000). The radio images reach a noise level of ~ 8.5 microJy/beam - the deepest WSRT image made to date. We summarise here the first results from the project, and present the final mosaic image, together with a list of detected sources. The effect of source confusion on the position, size and flux density of the faintest sources in the source catalogue are also addressed. The results of a serendipitous search for HI emission in the field are also presented. Using a subset of the data, we clearly detect HI emission associated with four galaxies in the central region of the FLSv. These are identified with nearby, massive galaxies.Comment: 9 pages, 6 figures (fig.3 in a separate gif file). Accepted for publication in A&A. The full paper and the related material can be downloaded from http://www.astron.nl/wsrt/WSRTsurveys/WFLS