Finite element analysis of the ECT test on mode III interlaminar fracture of carbon-epoxy composite laminates

In this work a parametric study of the Edge Crack Torsion (ECT) specimen was performed in order to maximize the mode III component (GIII) of the strain energy release rate for carbon-epoxy laminates. A three-dimensional finite element analysis of the ECT test was conducted considering a [90/0/(+45/-45)2/(-45/+45)2/0/90]S lay-up. The main objective was to define an adequate geometry to obtain an almost pure mode III at crack front. The geometrical parameters studied were specimen dimensions, distance between pins and size of the initial crack. The numerical results demonstrated that the ratio between the specimen length and the initial crack length had a significant effect on the strain energy release rate distributions. In almost all of the tested configurations, a mode II component occurred near the edges but it did not interfere significantly with the dominant mode III state.FCT - POCTI/EME/45573/200

A new data reduction scheme to obtain the mode II fracture properties of Pinus Pinaster wood

In this work a numerical study of the End Notched Flexure (ENF) specimen was performed in order to obtain the mode II critical strain energy released rate (GIIc) of a Pinus pinaster wood in the RL crack propagation system. The analysis included interface finite elements and a progressive damage model based on indirect use of Fracture Mechanics. The difficulties in monitoring the crack length during an experimental ENF test and the inconvenience of performing separate tests in order to obtain the elastic properties are well known. To avoid these problems, a new data reduction scheme based on the equivalent crack concept was proposed and validated. This new data reduction scheme, the Compliance-Based Beam Method (CBBM), does not require crack measurements during ENF tests and additional tests to obtain elastic properties.FCT - POCTI/EME/45573/200

Characterization of polyphenoloxidase (PPO) extracted from "Jonagored" apple

Polyphenoloxidase (PPO) was extracted from apple (cv. Jonagored) with addition of 2% PVP and 0.25% Triton X100 to the extraction buffer containing phenolic adsorbents. Experiments were performed to evaluate the affinity and specificity towards several substrates. ‘Jonagored’ apple PPO was found to have higher specificity (lower Km) towards L-dopa, 4-methylcatechol and (+) catechin than other phenols tested, but the highest activity level was obtained with p-cresol. The ratio Vmax/Km indicates that p-cresol followed by L-dopa and 4-methylcatechol are the best substrates for ‘Jonagored’ apple PPO. The enzyme activity showed two pH optima, at 5.0 and 7.5, at room temperature, with the main peak at pH 7.5 and the secondary one at pH 5.0 when catechol was the substrate

Shelf life of minimally processed apple (cv. Jonagored) determined by colour changes

Physical, chemical and sensory changes of cut apple (cv. Jonagored) stored in the dark at 4 °C were evaluated. Colour was found to be the critical parameter for this product. Apple cubes underwent severe surface browning primarily during the initial days of storage. The shelf-life of cut apple was therefore very limited, to three days maximum. Sensory analyses and objective quality evaluations of cut apple were considered highly correlated in terms of colour and flavour, especially with respect to fructose and sucrose, showing that the selected sensory attributes were good indicators of overall fruit quality