Coupled opto-electronic simulation of organic bulk-heterojunction solar cells: parameter extraction and sensitivity analysis

A general problem arising in computer simulations is the number of material and device parameters, which have to be determined by dedicated experiments and simulation-based parameter extraction. In this study we analyze measurements of the short-circuit current dependence on the active layer thickness and current-voltage curves in poly(3-hexylthiophene):[6,6]-phenyl-C61-butyric acid methyl ester (P3HT:PCBM) based solar cells. We have identified a set of parameter values including dissociation parameters that describe the experimental data. The overall agreement of our model with experiment is good, however a discrepancy in the thickness dependence of the current-voltage curve questions the influence of the electric field in the dissociation process. In addition transient simulations are analyzed which show that a measurement of the turn-off photocurrent can be useful for estimating charge carrier mobilities.Comment: 10 pages, 12 figures, 2 tables, Accepted for publication in Journal of Applied Physic

The FUSE survey of OVI absorption in and near the Galaxy

We present FUSE observations of OVI absorption in a sample of 100 extragalactic targets and 2 distant halo stars. We describe the details of the calibration, alignment in velocity, continuum fitting, and manner in which contaminants were removed (Galactic H2, absorption intrinsic to the background target and intergalactic Ly-beta lines). We searched for OVI absorption in the velocity range -1200 to 1200 km/s. With a few exceptions, we only find OVI between -400 and 400 km/s; the exceptions may be intergalactic OVI. We discuss the separation of the observed OVI absorption into components associated with the Galactic halo and components at high-velocity, which are probably located in the neighborhood of the Galaxy. We describe the measurements of equivalent width and column density, and we analyze the different contributions to the errors. We conclude that low-velocity Galactic OVI absorption occurs along all sightlines - the few non-detections only occur in noisy spectra. We further show that high-velocity OVI is very common, having equivalent width >65 mAA in 50% of the sightlines and >30 mAA in 70% of the high-quality sightlines. The high-velocity OVI absorption has velocities relative to the LSR of +/-(100--330) km/s; there is no correlation between velocity and absorption strength. We present 50 km/s wide OVI channel maps. These show evidence for the imprint of Galactic rotation. They also highlight two known HI high-velocity clouds (complex~C and the Magellanic Stream). The channel maps further show that OVI at velocities <-200 km/s occurs along all sightlines in the region l=20-150, b200 km/s occurs along all sightlines in the region l=180-300, b>20 (abbreviated).Comment: 85 pages, 127 figures, 13 color figures, 3 tables, AASTeX preprint format. All figures are in PNG format due to space concerns. Bound copies of manuscript and two accompanying articles are available upon request. submitted to ApJ

Highly-Ionized High-Velocity Gas in the Vicinity of the Galaxy

We report the results of an extensive FUSE study of high velocity OVI absorption along 102 complete sight lines through the Galactic halo. The high velocity OVI traces a variety of phenomena, including tidal interactions with the Magellanic Clouds, accretion of gas, outflow from the Galactic disk, warm/hot gas interactions in a highly extended Galactic corona, and intergalactic gas in the Local Group. We identify 85 high velocity OVI features at velocities of -500 < v(LSR) < +500 km/s along 59 of the 102 sight lines. Approximately 60% of the sky (and perhaps as much as 85%) is covered by high velocity H+ associated with the high velocity OVI. Some of the OVI is associated with known high velocity HI structures (e.g., the Magellanic Stream, Complexes A and C), while some OVI features have no counterpart in HI 21cm emission. The smaller dispersion in the OVI velocities in the GSR and LGSR reference frames compared to the LSR is necessary (but not conclusive) evidence that some of the clouds are extragalactic. Most of the OVI cannot be produced by photoionization, even if the gas is irradiated by extragalactic background radiation. Collisions in hot gas are the primary OVI ionization mechanism. We favor production of some of the OVI at the boundaries between warm clouds and a highly extended [R > 70 kpc], hot [T > 10^6 K], low-density [n < 10^-4 cm^-3] Galactic corona or Local Group medium. A hot Galactic corona or Local Group medium and the prevalence of high velocity OVI are consistent with predictions of galaxy formation scenarios. Distinguishing between the various phenomena producing high velocity OVI will require continuing studies of the distances, kinematics, elemental abundances, and physical states of the different types of high velocity OVI features found in this study. (abbreviated)Comment: 78 pages of text/tables + 31 figures, AASTeX preprint format. All figures are in PNG format due to astro-ph space restrictions. Bound copies of manuscript and two accompanying articles are available upon request. Submitted to ApJ

Deuterium Toward WD1634-573: Results from the Far Ultraviolet Spectroscopic Explorer (FUSE) Mission

We use Far Ultraviolet Spectrocopic Explorer (FUSE) observations to study interstellar absorption along the line of sight to the white dwarf WD1634-573 (d=37.1+/-2.6 pc). Combining our measurement of D I with a measurement of H I from Extreme Ultraviolet Explorer data, we find a D/H ratio toward WD1634-573 of D/H=(1.6+/-0.5)e-5. In contrast, multiplying our measurements of D I/O I=0.035+/-0.006 and D I/N I=0.27+/-0.05 with published mean Galactic ISM gas phase O/H and N/H ratios yields D/H(O)=(1.2+/-0.2)e-5 and D/H(N)=(2.0+/-0.4)e-5, respectively. Note that all uncertainties quoted above are 2 sigma. The inconsistency between D/H(O) and D/H(N) suggests that either the O I/H I and/or the N I/H I ratio toward WD1634-573 must be different from the previously measured average ISM O/H and N/H values. The computation of D/H(N) from D I/N I is more suspect, since the relative N and H ionization states could conceivably vary within the LISM, while the O and H ionization states will be more tightly coupled by charge exchange.Comment: 23 pages, 5 figures; AASTEX v5.0 plus EPSF extensions in mkfig.sty; accepted by ApJ Supplemen

Distribution and Kinematics of O VI in the Galactic Halo

FUSE spectra of 100 extragalactic objects are analyzed to obtain measures of O VI absorption along paths through the Milky Way thick disk/halo. Strong O VI absorption over the approximate velocity range from -100 to 100 km/s reveals a widespread but highly irregular distribution of thick disk O VI, implying the existence of substantial amounts of hot gas with T ~ 3x10^5 K in the Milky Way halo. Large irregularities in the distribution of the absorbing gas are found to be similar over angular scales extending from less than one to 180 degrees, indicating a considerable amount of small and large scale structure in the gas. The overall distribution of Galactic O VI is not well described by a symmetrical plane-parallel layer of patchy O VI absorption. The simplest departure from such a model that provides a reasonable fit to the observations is a plane-parallel patchy absorbing layer with a scale height of 2.3 kpc, and a 0.25 dex excess of O VI in the northern Galactic polar region. The O VI absorption has a Doppler parameter b = 30 to 99 km/s, with an average value of 60 km/s . Thermal broadening alone cannot explain the large observed profile widths. The average O VI absorption velocities toward high latitude objects range from -46 to 82 km/s, with a sample average of 0 km/s and a standard deviation of 21 km/s. O VI associated with the thick disk moves both toward and away from the plane with roughly equal frequency. A combination of models involving the radiative cooling of hot fountain gas, the cooling of supernova bubbles in the halo, and the turbulent mixing of warm and hot halo gases is required to explain the presence of O VI and other highly ionized atoms found in the halo. (abbreviated)Comment: 70 pages, single-spaced, PDF format. Bound copies of this manuscript and two accompanying articles are available upon request. Submitted to ApJ