Waterborne GPR survey for estimating bottom-sediment variability: A survey on the Po River, Turin, Italy

We conducted an integrated geophysical survey on a stretch of the river Po in order to check the GPR ability to discriminate the variability of riverbed sediments through an analysis of the bottom reflection amplitudes. We conducted continuous profiles with a 200-MHzGPR system and a handheld broadband EM sensor.Aconductivity meter and a TDR provided punctual measurements of water conductivity, permittivity, and temperature. The processing and interpretation of the GEM-2 and GPR data were enhanced by reciprocal results and by integration with the punctual measurements of the EM properties of the water. We used a processing flow that improved the radargram images and preserved the amplitude ratios among the different profiles and the frequency content at the bottom reflection signal.We derived the water attenuation coefficient both from the punctual measurements using the Maxwell formulas and from the interpretation of the GPR data, finding an optimal matching between the two values. The GPR measurements provided maps of the bathymetry and of the bottom reflection amplitude. The high reflectivity of the riverbed, derived from the GPR interpretation, agreed with the results of the direct sampling campaign that followed the geophysical survey. The variability of the bottom-reflection-amplitudes map, which was not confirmed by the direct sampling, could also have been caused by scattering phenomena due to the riverbed clasts which are dimensionally comparable to the wavelength of the radar pulse

Klimaatverandering op de hoge zandgronden: effecten en adaptatie : betekenis van klimaatverandering voor het landelijk gebied in de provincie Gelderland : een uitwerking voor de gebiedsontwikkeling in Baakse Beek en Blauwe Bron

Doel van het project: kennis uitwisselen over klimaatverandering en functies in het landelijk gebied. Tussen wetenschap en de praktijk van gebiedsontwikkeling. Daarnaast: vanuit de gebiedsontwikkeling onderzoeksvragen formuleren voor vervolgonderzoek

Degradation of isazofos in the soil environment

Field and laboratory studies were conducted to investigate the degradation of the organophosphorus insecticide isazofos (0-5-chloro-l-isopropyl-1H-l,2,4-triazol-3-ylO,O-diethyl phosphorothioate) in soil. In a 6-year field study, soil pH was an important factor influencing the degradation of isazofos inasmuch as an increased rate of degradation was observed in soils with previous isazofos applications and pH of 6.9 or more. A laboratory study of [14Clisazofos confirmed the rapid degradation of this insecticide in high pH soils. No increased degradation rate, however, was observed in sterilized high-pH soils. The availability of isazofos to microorganisms, based on sorption of isazofos to soil, seems to be an important factor influencing the degradation of isazofos in soil. Sorption coefficients were negatively correlated with isazofos degradation rate

Time Interval Between Cover Crop Termination and Planting Influences Corn Seedling Disease, Plant Growth, and Yield

Experiments were established in a controlled-growth chamber and in the field to evaluate the effect of the length of time intervals between winter rye cover crop termination and corn planting on corn seedling disease, corn growth, and grain yield in 2014 and 2015. Rye termination dates ranged from 25 days before planting (DBP) to 2 days after planting (DAP) corn in the field and from 21 DBP to 1 DAP in controlled studies. Results were similar in both environments. In general, shorter intervals increased seedling disease and reduced corn emergence, shoot growth, and grain yield of corn following winter rye compared with corn planted 10 or more days after rye termination or without rye. Incidence of Pythium spp. increased with shorter intervals (less than 8 DBP); incidence of Fusarium spp. was not consistent between runs and experiments. In 2014, in the 1-DAP treatment, number of ears and grain yield were reduced (P = 0.05 and 0.02, respectively). In 2015, all termination intervals reduced plant population, number of ears, and yield (P = 0.01), with the 2-DBP treatment causing the biggest decrease. A 10- to 14-day interval between rye termination and corn planting should be followed to improve corn yield following a rye cover crop

Electrical stimulation for enhanced denitrification in woodchip bioreactors: Opportunities and challenges

Woodchip bioreactors are being implemented for the removal of nitrates in groundwater and tile water drainage. However, low nitrate removals in denitrifying woodchip bioreactors have been observed for short hydraulic retention time (HRT) and low water temperature (°C). One potential approach to improve woodchip bioreactor performance is to provide an alternative and readily available electron source to the denitrifying microorganisms through electrical stimulation. Previous work has demonstrated the capability of bio-electrochemical reactors (BER) to remove a variety of water contaminants, including nitrate, in the presence of a soluble carbon source. The objective of this study was to evaluate the denitrification efficiency of electrically augmented woodchip bioreactors and conduct a simple techno-economic analysis (TEA) to understand the possibilities and limitations for full-scale BER implementation for treatment of agricultural drainage. Up-flow column woodchip bioreactors were studied included two controls (non-energized, and without electrodes), two electrically enhanced bioreactors, each using a single 316 stainless steel anode coupled with graphite cathodes, and two electrically enhanced bioreactors, each with graphite for both anode and cathodes. Both pairs of electrically enhanced bioreactors demonstrated higher denitrification efficiencies than controls when 500 mA of current was applied. While this technology appeared promising, the techno-economic analysis showed that the normalized N removal cost ($/kg N) for BERs was 2–10 times higher than the base cost with no electrical stimulation. With our current reactor design, opportunities to make this technology cost effective require denitrification efficiency of 85% at 100 mA. This work informs the process and design of electrically stimulated woodchip bioreactors with optimized performance to achieve lower capital and maintenance costs, and thus lower N removal cost

Occurrence of Atrazine and Degradates as Contaminants of Subsurface Drainage and Shallow Groundwater

Atrazine is a commonly used herbicide in corn (Zea mays L.) growing areas of the USA. Because of its heavy usage, moderate persistence, and mobility in soil, monitoring of atrazine movement under field conditions is essential to assess its potential to contaminate groundwater. Concentrations of atrazine, deisopropylatrazine (DIA), and deethylatrazine (DEA) were measured in subsurface drainage and shallow groundwater beneath continuous, no-till corn. Water samples were collected from the subsurface drain (tile) outlets and suction lysimeters in the growing seasons of 1990 and 1991, and analyzed for atrazine and two principle degradates using solid-phase extraction and HPLC. In 1990, atrazine concentration ranged from 1.3 to 5.1 µg L−1 in tile-drain water and from 0.5 to 20.5 µg L−1 in lysimeter water. In general, concentrations of parent and degradates in solution were atrazine \u3e DEA \u3e DIA. Lesser levels of atrazine were measured in 1991 from Plots 2 and 4; however, greater concentrations of atrazine (6.0–8.4 µg L−1) were measured from Plot 5. Throughout the two growing seasons, atrazine concentration in Plot 5 tile-drain water was greater than that of Plots 2 and 4, suggesting a preferential movement of atrazine. Concentrations of DIA and DEA ranged from 0.1 to 2.2 and 0.9 to 3.2 µg L−1, respectively, indicating that the degradation products by themselves or in combination with parent atrazine can exceed the maximum contaminant level (mcl) of 3 µg L−1 even though atrazine by itself may be \u3c3 µg L−1. The deethylatrazineto-atrazine ratio (DAR) is an indicator of residence time in soil during transport of atrazine to groundwater. In Plots 2 and 4, DAR values for tile-drain water ranged from 0.43 to 2.70 and 0.50 to 2.66, respectively. By comparison, a DAR of 0.38 to 0.60 was observed in Plot 5, suggesting less residence time in the soil

Brands in the Labor Market: How Vertical and Horizontal Brand Differentiation Impact Pay and Profits Through Employee-Brand Matching

The primary focus of brand equity research has been on how brand knowledge creates value for firms through customer behavior in product markets. Using archival data and five experiments, this article tests a framework that outlines the unique role brands play in the labor market. The framework distinguishes between vertical and horizontal differentiation and shows that vertical brand differentiation is associated with lower pay, whereas horizontal brand differentiation is associated with higher pay. Employees are also vertically and horizontally differentiated and firms high in horizontal brand differentiation pay more for employees who match their brands differentiating characteristics (i.e., brand-relevant complementarities). Results show that these brand-pay relationships have important downstream effects on employee behavior and, consequently, on firm profits. Specifically, leveraging vertical brand differentiation to lower pay represents a false economy because profits are attenuated by negative effects on employee productivity and retention. In contrast, when managers at firms high on horizontal brand differentiation pay more, profits increase via the same mediating employee behaviors. Six firm strategies and investments that influence firm bargaining power in the employee-brand matching process are found to moderate the brand-pay relationship and downstream effects on profits