Forces between elongated particles in a nematic colloid

Using molecular dynamics simulations we study the interactions between elongated colloidal particles (length to breath ratio ≫1) in a nematic host. The simulation results are compared to the results of a Landau–de Gennes elastic free energy. We find that depletion forces dominate for the sizes of the colloidal particles studied. The tangential component of the force, however, allows us to resolve the elastic contribution to the total interaction. We find that this contribution differs from the quadrupolar interaction predicted at large separations. The difference is due to the presence of nonlinear effects, namely, the change in the positions and structure of the defects and their annihilation at small separations

Simulating Particle Dispersions in Nematic Liquid-Crystal Solvents

A new method is presented for mesoscopic simulations of particle dispersions in nematic liquid crystal solvents. It allows efficient first-principle simulations of the dispersions involving many particles with many-body interactions mediated by the solvents. A simple demonstration is shown for the aggregation process of a two dimentional dispersion.Comment: 5 pages, 5 figure

A Smooth Interface Method for Simulating Liquid Crystal Colloid Dispersions

A new method is presented for mesoscopic simulations of particle dispersions in liquid crystal solvents. It allows efficient first-principle simulations of the dispersions involving many particles with many-body interactions mediated by the solvents. Demonstrations have been performed for the aggregation of colloid dispersions in two-dimensional nematic and smectic-C* solvents neglecting hydrodynamic effects, which will be taken into account in the near future.Comment: 13 pages, 4 figure

Effective forces in colloidal mixtures: from depletion attraction to accumulation repulsion

Computer simulations and theory are used to systematically investigate how the effective force between two big colloidal spheres in a sea of small spheres depends on the basic (big-small and small-small) interactions. The latter are modeled as hard-core pair potentials with a Yukawa tail which can be both repulsive or attractive. For a repulsive small-small interaction, the effective force follows the trends as predicted by a mapping onto an effective non-additive hard-core mixture: both a depletion attraction and an accumulation repulsion caused by small spheres adsorbing onto the big ones can be obtained depending on the sign of the big-small interaction. For repulsive big-small interactions, the effect of adding a small-small attraction also follows the trends predicted by the mapping. But a more subtle ``repulsion through attraction'' effect arises when both big-small and small-small attractions occur: upon increasing the strength of the small-small interaction, the effective potential becomes more repulsive. We have further tested several theoretical methods against our computer simulations: The superposition approximation works best for an added big-small repulsion, and breaks down for a strong big-small attraction, while density functional theory is very accurate for any big-small interaction when the small particles are pure hard-spheres. The theoretical methods perform most poorly for small-small attractions.Comment: submitted to PRE; New version includes an important quantitative correction to several of the simulations. The main conclusions remain unchanged thoug

Spring migration dates of Teal (Anas crecca) ringed in the Camargue

The policy of the European Commission prohibits hunting of migratory birds while they travel to their breeding grounds. To date, spring migration dates of ducks have mainly been determined using bird counts, but the validity of this sometimes disputed method has never been tested. We used ring-recovery data from close to 9,000 teal Anas crecca ringed in the Camargue, southern France, to determine the onset of spring migration. This method makes it possible to avoid potential biases linked to duck counts, and was used to test the validity of spring migration dates inferred from such counts. Depending on the type of analysis (intra- or inter-annual recoveries), teal appeared to start migrating from the Camargue during the first or second 10-day period of January, with no significant differences between years, and no effect of the bird’s age or sex. However, when taking potential winter dispersion into account, we suggest that a conservative estimate for the onset of spring migration is the first 10-day period of February. Migration dates inferred from ring-recovery analyses were consistent with earlier results from duck counts, and provide a firm basis for policy making related to hunting. Though ringing data should be preferred when available, our study suggests that determining migration dates from bird counts may be a reliable method for teal, and potentially for other dabbling and diving ducks as well.</p

Recensements d'anatides et foulques hivernant en Afrique du Nord et de l'Ouest. Janvier 1984, 1985 et 1986

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