Avaliação de adsorventes sólidos para determinação de pesticidas organoclorados e bifenilos policlorados na atmosfera marinha

A sampling system was developed to be used in coastal areas and on board of océanographie vessels for the determination of chlorinated pesticides and polychlorinated biphenyls (PCB) in the atmosphere. The basis of the system is the pre-concentration step on solid adsorbents. Florisil, XAD-2 resin and polyurethane foam (PUF) were tested. The sampling efficiency presented variations between 16-118% (florisil), 41131% (XAD-2) and 66-122% (PUF) depending on the organochlorine compound.Um sistema de amostragem foi desenvolvido para ser usado em áreas costeiras e a bordo de embarcações oceanográficas para a determinação de pesticidas organoclorados e bifenilos policlorados (PCBs) na atmosfera. Este sistema baseia-se na pré-concentração em adsorventes sólidos. Foram usados Florosil, Resina XAD-2 e espuma de poliuretano (EPU). A eficiência de amostragens para estes adsorventes foi de 16-118% (florosil), 41-131% (XAD-2) e 66-112 (EPU), para os compostos organoclorados analisados

Seabird colonies as relevant sources of pollutants in Antarctic ecosystems: Part 2 - Persistent Organic Pollutants

International audienceDespite typically not being taken into account (usually in favour of the "Global Distillation" process), the input of Persistent Organic Pollutants (POPs) via biological activity can be indeed relevant at the local scale in terrestrial Polar environments when seabird colonies are considered. The fact that seabirds bioaccumulate and biomagnify those POPs, gather in large numbers and excrete on land during their reproductive season can act locally as relevant secondary source of the same contaminants. The first part of this study indicated that these colonies act as so for several essential and non-essential trace elements and this second part tests the same hypothesis concerning POPs using the very same samples. Lichens (n=55), mosses (n=58) and soil (n=37) were collected in 13 locations within the South Shetlands Archipelago during the austral summers of 2013-14 and 2014-15. They were divided in colony (within the colony itself for soil and bordering it for vegetation) and control (at least 150m away from any colony interference), analysed for POPs: organochlorine pesticides, polychlorinated byphenyls (PCBs) and polybrominated diphenyl ethers (PBDEs); and stable isotopes (C and N). Results showed that colonies act clearly as a secondary source for PCBs and likely for HCB. As in the first part, probable local sources other than the colonies themselves are hypothesised due to high concentrations found in control sites. Again, soil seemed the most adequate matrix for the intended purposes especially because of some particularities in the absorption of animal derived organic matter by vegetation, pointed out by stable isotope analyses

Seabird colonies as relevant sources of pollutants in Antarctic ecosystems: Part 1 - Trace elements

International audienceGlobal distillation is classically pointed as the biggest responsible for contaminant inputs in Polar ecosystems. Mercury (Hg) and other trace elements (TEs) also present natural sources, whereas the biologically mediated input is typically ignored. However, bioaccumulation and biomagnification combined with the fact that seabirds gather in large numbers into large colonies and excrete on land might represent an important local TEs input. A previous work suggested these colonies as sources of not only nutrients, but also organic contaminants. To evaluate a similar hypothesis for TEs, samples of lichen (n = 55), mosses (n = 58) and soil (n = 37) were collected in 13 locations within the South Shetlands Archipelago during the austral summers of 2013-14 and 2014-15. They were divided in: "colony" (within the colony itself for soil and bordering it for vegetation) and "control" (at least 50m away from colony interference), analysed for TEs (As, Cd, Co, Cr, Cu, Fe, Hg, Mn, Ni, Pb, Se, V, and Zn) and stable isotopes (C and N). In most cases, soil seems the best matrix to assess colonies as TEs sources, as it presented more differences between control/colony sites than vegetation. Colonies are clearly local sources of organic matter, Cd, Hg and likely of As, Se and Zn. Conversely, Co, Cr, Ni and Pb come presumably from other sources, natural or anthropogenic. In general, isotopes were more useful for interpreting vegetation data due to fractionation of absorbed animal-derived organic matter. Other local Hg sources could be inferred from high levels in control sites, location and wind patterns

International regulatory responses to global challenges in marine pollution and climate change

Marine pollution, also referred to as \u27pollution of the marine environment\u27, may occur as a result of different activities. Examples are land-based activities, vessel-related activitiese, dumping at sea, atmospheric and offshore hydrocarbon exploration, seabed mining, and so on. As discussed in Chapter 4, these types of marine pollution are often transboundary in nature and are harmful to human health and marine ecosystem. Similarly, climate change is a global issue involving the interests of all States. The Fifth Assessment Report of the Intergovernmental Panel on Climate Change (IPCC), finalized and published in 2014, has further confirmed the existence of global warming when compared with the previous IPCC reports. It indicates that climate change has negatively affected natural and human systems on all continents and across the oceans, and asserts that 280substantial and sustained reduction of greenhouse gas (GHG) emissions would contribute to the tackling of climate change. 1 International issues need international responses. Both the marine pollution and climate change are issues with international dimensions, and thus require the global regulation by the international community