Optimisation of silicone-based dielectric elastomer transducers by means of block copolymers – synthesis and compounding

Emerging artificial muscle technology has developed from metal-based robotics to softtype robotics made from soft matter. Research into artificial muscle technology based on soft matter has been conducted mainly in order to mimic soft and robust human muscle. In this regard, dielectric elastomers have been studied. Their actuation occurs when Maxwell stress exceeds elastic stress in the presence of an electrical field, resulting in contraction in thickness and planar expansion in the area. As well as an actuator, dielectric elastomers can be used as generators and sensors. As a dielectric elastomer, silicones have been used extensively in many applications, due to favourable properties such as thermal stability, non-conductivity, high gas permeability and low toxicity. However, silicones have a low dielectric constant and thereby low energy density. In order to enhance actuation performance, it is the aim of this research to develop silicone elastomers with a high dielectric constant and high electrical breakdown strength, as well as a low Young’s modulus. In this Ph.D. thesis, two methods were developed to enhance silicone properties such as the dielectric constant and electrical breakdown strength. The first method was devised to enhance the dielectric constant of silicone elastomers through the use of a polydimethylsiloxane-polyethyleneglycol (PDMS-PEG) copolymer, in order to obtain an elastomer with high electrical energy. PDMS-PEG copolymers were synthesised and blended in commercial silicone and subsequently cross-linked. The relative permittivity of cross-linked silicone with 5 wt% of PDMS-PEG copolymers increased by nearly 50%, without compromising dielectric loss and mechanical properties, compared to the commercial silicone elastomer. The second investigated method involved enhancing the electrical breakdown strength of silicone by using an aromatic voltage stabiliser. Here, polyphenylmethylsiloxane (PPMS), which contained aromatic voltage stabilisers, was bonded covalently to PDMS through a hydrosilylation reaction obtaining PDMS-PPMS copolymers. The synthesised copolymers were subsequently cross-linked with a vinyl cross-linker. The obtained cross-linked PDMS-PPMS copolymers were inherently soft and robust with increased electrical breakdown strength (21%) compared to the reference elastomer without an aromatic voltage stabiliser. The conducting polymer was developed through the use of a multi-walled carbon nanotube (MWCNT) in a PDMS-PEG matrix as a compliant electrode of dielectric elastomers. The conductive PDMS-PEG copolymer was incorporated with surface-treated MWCNT, in order to obtain highly conductive elastomer. The prepared sample with 4 parts per hundred rubber (phr) MWCNT was soft and the resulting conductivity of the cross-linked PDMS-PEG copolymer with the addition of MWCNT was high, at 10-2 S cm-1, nearly equivalent to a commonly used commercial conducting polymer. In this thesis, the elastomer and electrode system is referred to as a ‘dielectrielastome

Effects of modern instructional technology (MIT) on critical thinking skills of students in agriculture vocational courses in Nigeria

The recent development in modern instruction technology (MIT) methods and equipment warranted for studies to examine their effects on students, teachers, and the education system in general. This study examines the effects of MIT on students’ critical thinking skills in Agriculture vocational courses in Nigeria. The methods and equipment used were identified, and the effect of teachers’ usage behaviour was assessed. A survey approach was adopted, using questionnaires for data collection. The descriptive, correlations and multiple regressions were carried out using SPSS. The result of this study indicates that the most commonly used equipment is electronic whiteboard, while the least are electronic tablets and laptops. Cooperative learning is the most commonly used methods while games and online instruction are the least. There is a moderate positive correlation between MIT methods and the students’ critical thinking skill, but a very weak positive correlation between MIT equipment and students’ critical thinking skill. There is statistically significant contribution of methods to student’s critical thinking, but insignificant method usage behaviour. Therefore, it is concluded that government should incorporate the provision and effective utilisation of MIT equipment and methods in the national education policy. School managements should emphasise the use of MIT methods and review curriculum to improve teachers’ skills in MIT usage. Teachers should utilise the available MIT equipment and method along with their skills for an effective delivery of lessons. Similarly, the students should be encouraged to appreciate the available methods and the equipment, and use them effectively

Formation of a Nanorod-Assembled TiO₂ Actinomorphic-Flower-like Microsphere Film via Ta Doping Using a Facile Solution Immersion Method for Humidity Sensing

This study fabricated tantalum (Ta)-doped titanium dioxide with a unique nanorod-assembled actinomorphic-flower-like microsphere structured film. The Ta-doped TiO2 actinomorphic-flower-like microsphere (TAFM) was fabricated via the solution immersion method in a Schott bottle with a home-made improvised clamp. The samples were characterised using FESEM, HRTEM, XRD, Raman, XPS, and Hall effect measurements for their structural and electrical properties. Compared to the undoped sample, the rutile-phased TAFM sample had finer nanorods with an average 42 nm diameter assembled to form microsphere-like structures. It also had higher oxygen vacancy sites, electron concentration, and mobility. In addition, a reversed double-beam photoacoustic spectroscopy measurement was performed for TAFM, revealing that the sample had a high electron trap density of up to 2.5 μmolg−1. The TAFM showed promising results when employed as the resistive-type sensing film for a humidity sensor, with the highest sensor response of 53,909% obtained at 3 at.% Ta doping. Adding rGO to 3 at.% TAFM further improved the sensor response to 232,152%

Contribution @ l' tude physico-chimique de la catalyse par transfert de phase solide-liquide

SIGLEBSE B226354K / UCL - Université Catholique de LouvainBEBelgiu

Evaluating Different TiO2 Nanoflower-Based Composites for Humidity Detection

Unique three-dimensional (3D) titanium dioxide (TiO2) nanoflowers (TFNA) have shown great potential for humidity sensing applications, due to their large surface area-to-volume ratio and high hydrophilicity. The formation of a composite with other materials could further enhance the performance of this material. In this work, the effect of different types of composites on the performance of a TNFA-based humidity sensor was examined. NiO, ZnO, rGO, and PVDF have been explored as possible composite pairing candidates with TiO2 nanoflowers, which were prepared via a modified solution immersion method. The properties of the composites were examined using field emission electron spectroscopy (FESEM), X-ray diffractometry (XRD), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), current-voltage (I-V) analysis, Hall effect measurement, and contact angle measurement. The performance of the humidity sensor was assessed using a humidity sensor measurement system inside a humidity-controlled chamber. Based on the result, the combination of TiO2 with rGO produced the highest sensor response at 39,590%. The achievement is attributed to the increase in the electrical conductivity, hydrophilicity, and specific surface area of the composite

Formation of a Nanorod-Assembled TiO2 ActinomorphicFlower-like Microsphere Film via Ta Doping Using a Facile Solution Immersion Method for Humidity Sensing

This study fabricated tantalum (Ta)-doped titanium dioxide with a unique nanorodassembled actinomorphic-flower-like microsphere structured film. The Ta-doped TiO2 actinomorphicflower-like microsphere (TAFM) was fabricated via the solution immersion method in a Schott bottle with a home-made improvised clamp. The samples were characterised using FESEM, HRTEM, XRD, Raman, XPS, and Hall effect measurements for their structural and electrical properties. Compared to the undoped sample, the rutile-phased TAFM sample had finer nanorods with an average 42 nm diameter assembled to form microsphere-like structures. It also had higher oxygen vacancy sites, electron concentration, and mobility. In addition, a reversed double-beam photoacoustic spectroscopy measurement was performed for TAFM, revealing that the sample had a high electron trap density of up to 2.5 µmolg1. The TAFM showed promising results when employed as the resistive-type sensing film for a humidity sensor, with the highest sensor response of 53,909% obtained at 3 at.% Ta doping. Adding rGO to 3 at.% TAFM further improved the sensor response to 232,152

Effects of Annealing Environments on the Solution-Grown, Aligned Aluminium-Doped Zinc Oxide Nanorod-Array-Based Ultraviolet Photoconductive Sensor

We have fabricated metal-semiconductor-metal- (MSM-) type ultraviolet (UV) photoconductive sensors using aluminium- (Al-) doped zinc oxide (ZnO) nanorod arrays that were annealed in different environments: air, oxygen, or a vacuum. The Al-doped ZnO nanorods had an average diameter of 60 nm with a thickness of approximately 600 nm that included the seed layer (with thickness ~200 nm). Our results show that the vacuum-annealed nanorod-array-based UV photoconductive sensor has the highest photocurrent value of   2.43  ×  10-4 A. The high photocurrent is due to the high concentration of zinc (Zn) interstitials in the vacuum-annealed nanorod arrays. In contrast, the oxygen-annealing process applied to the Al-doped ZnO nanorod arrays produced highly sensitive UV photoconductive sensors, in which the sensitivity reached 55.6, due to the surface properties of the oxygen-annealed nanorods, which have a higher affinity for oxygen adsorption than the other samples and were thereby capable of reducing the sensor’s dark current. In addition, the sensor fabricated using the oxygen-annealed nanorod arrays had the lowest rise and decay time constants. Our result shows that the annealing environment greatly affects the surface condition and properties of the Al-doped ZnO nanorod arrays, which influences the performance of the UV photoconductive sensors

Optimization of Aluminum Dopant Amalgamation Immersion Time on Structural, Electrical, and Humidity-Sensing Attributes of Pristine ZnO for Flexible Humidity Sensor Application

This study synthesized pristine and aluminum (Al)-doped zinc oxide (Al:ZnO) nanostructures through a simplistic low-temperature ultrasonicated solution immersion method. Al:ZnO nanostructures were synthesized as a sensing material using different immersion times varying from two to five hours. The Al:ZnO nanostructured-based flexible humidity sensor was fabricated by employing cellulose filter paper as a substrate and transparent paper glue as a binder through a simplistic brush printing technique. XRD, FESEM, HRTEM, EDS, XPS, a two-probe I–V measurement system, and a humidity measurement system were employed to investigate the structural, morphological, chemical, electrical, and humidity-sensing properties of the pristine ZnO and Al:ZnO nanostructures. The structural and morphological analysis confirmed that Al cations successfully occupied the Zn lattice or integrated into interstitial sites of the ZnO lattice matrix. Humidity-sensing performance analysis indicated that the resistance of the Al:ZnO nanostructure samples decreased almost linearly as the humidity level increased, leading to better sensitivity and sensing response. The Al:ZnO-4 h nanostructured-based flexible humidity sensor had a maximum sensing response and demonstrated the highest sensitivity towards humidity changes, which was noticeably superior to the other tested samples. Finally, this study explained the Al:ZnO nanostructures-based flexible humidity sensor sensing mechanism in terms of chemical adsorption, physical adsorption, and capillary condensation mechanisms

Optimization of Aluminum Dopant Amalgamation Immersion Time on Structural, Electrical, and Humidity-Sensing Attributes of Pristine ZnO for Flexible Humidity Sensor Application

This study synthesized pristine and aluminum (Al)-doped zinc oxide (Al:ZnO) nanostructures through a simplistic low-temperature ultrasonicated solution immersion method. Al:ZnO nanostructures were synthesized as a sensing material using different immersion times varying from two to five hours. The Al:ZnO nanostructured-based flexible humidity sensor was fabricated by employing cellulose filter paper as a substrate and transparent paper glue as a binder through a simplistic brush printing technique. XRD, FESEM, HRTEM, EDS, XPS, a two-probe I–V measurement system, and a humidity measurement system were employed to investigate the structural, morphological, chemical, electrical, and humidity-sensing properties of the pristine ZnO and Al:ZnO nanostructures. The structural and morphological analysis confirmed that Al cations successfully occupied the Zn lattice or integrated into interstitial sites of the ZnO lattice matrix. Humidity-sensing performance analysis indicated that the resistance of the Al:ZnO nanostructure samples decreased almost linearly as the humidity level increased, leading to better sensitivity and sensing response. The Al:ZnO-4 h nanostructured-based flexible humidity sensor had a maximum sensing response and demonstrated the highest sensitivity towards humidity changes, which was noticeably superior to the other tested samples. Finally, this study explained the Al:ZnO nanostructures-based flexible humidity sensor sensing mechanism in terms of chemical adsorption, physical adsorption, and capillary condensation mechanisms