8 research outputs found
Monte Carlo simulation as an alternative approach for estimation of uncertainty measurement of 2,4 dimethylphenol
The estimation of uncertainty measurement using different approaches is increasingly applied to assess the reliability of results generated by applied analytical methods. This paper presents the Monte Carlo simulation model (MCS) for calculating the uncertainty of the measurement associated with the result of the analysis. The results of MCS were compared with the commonly used a standard method (GUM). The calculations of the measurement uncertainty were demonstrated in the case of the determination of 2,4-dimethylphenol by gas chromatography in concrete samples.14th international conference on fundamental and applied aspects of physical chemistry; 24-28 September 2018, Belgrade, Serbia
Validation and uncertainty estimation of an analytical method for the determination of phenolic compounds in concrete
Organic contaminants from building materials negatively affect the health of people. This study presents an analytical method for the simultaneous identification and quantification of 9 phenolic compounds, i.e., phenol, 2-chloro-phenol, 2,4-dimethylphenol, 2,4-dichlorophenol, 2,6-dichlorophenol, 4-chloro-3-methylphenol, 2,4,6-trichlorophenol, 2,3,4,6-tetrahlorophenol and pentachlorophenol, in concrete by a gas chromatographic method with mass spectrometric detection (GC–MS). By comparing the MS spectra of the test compounds with MS spectra of analytical standards, reliable identification was achieved. The method could be applied in a given range (from 0.01 to 7.5 mg kg -1 ) with appropriate parameters of precision, accuracy, repeatability and linearity. The developed method could be used for quality control testing of phenols in concrete during the construction of new buildings, old residences and construction waste. The measurement uncertainty of the phenolic compounds in concrete was evaluated using two approaches, i.e., GUM recommendations and a Monte Carlo method. Disagreement of those methods was observed. The Monte Carlo method could be used in the evaluation of combined measurement uncertainty for the determination of phenolic compounds in concrete. © 2019 Serbian Chemical Society. All rights reserved
Solar neutrino detection sensitivity in DARWIN via electron scattering
We detail the sensitivity of the proposed liquid xenon DARWIN observatory to solar neutrinos via elastic electron scattering. We find that DARWIN will have the potential to measure the fluxes of five solar neutrino components: pp, 7 Be, 13 N, 15 O and pep. The precision of the 13 N, 15 O and pep components is hindered by the double-beta decay of 136 Xe and, thus, would benefit from a depleted target. A high-statistics observation of pp neutrinos would allow us to infer the values of the electroweak mixing angle, sin 2 θ w , and the electron-type neutrino survival probability, P ee , in the electron recoil energy region from a few keV up to 200 keV for the first time, with relative precision of 5% and 4%, respectively, with 10 live years of data and a 30 tonne fiducial volume. An observation of pp and 7 Be neutrinos would constrain the neutrino-inferred solar luminosity down to 0.2%. A combination of all flux measurements would distinguish between the high- (GS98) and low-metallicity (AGS09) solar models with 2.1–2.5 σ significance, independent of external measurements from other experiments or a measurement of 8 B neutrinos through coherent elastic neutrino-nucleus scattering in DARWIN. Finally, we demonstrate that with a depleted target DARWIN may be sensitive to the neutrino capture process of 131 Xe.DARWIN Collaboration (ukupan broj autora: 166
A Next-Generation Liquid Xenon Observatory for Dark Matter and Neutrino Physics
The nature of dark matter and properties of neutrinos are among the mostpressing issues in contemporary particle physics. The dual-phase xenontime-projection chamber is the leading technology to cover the availableparameter space for Weakly Interacting Massive Particles (WIMPs), whilefeaturing extensive sensitivity to many alternative dark matter candidates.These detectors can also study neutrinos through neutrinoless double-beta decayand through a variety of astrophysical sources. A next-generation xenon-baseddetector will therefore be a true multi-purpose observatory to significantlyadvance particle physics, nuclear physics, astrophysics, solar physics, andcosmology. This review article presents the science cases for such a detector.<br
Validation and uncertainty estimation of an analytical method for the determination of phenolic compounds in concrete
Organic contaminants from building materials negatively affect the health of people. This study presents an analytical method for the simultaneous identification and quantification of 9 phenolic compounds, i.e., phenol, 2-chlorophenol, 2,4-dimethylphenol, 2,4-dichlorophenol, 2,6-dichlorophenol, 4-chloro-3- -methylphenol, 2,4,6-trichlorophenol, 2,3,4,6-tetrahlorophenol and pentachlorophenol, in concrete by a gas chromatographic method with mass spectrometric detection (GC–MS). By comparing the MS spectra of the test compounds with MS spectra of analytical standards, reliable identification was achieved. The method could be applied in a given range (from 0.01 to 7.5 mg kg-1) with appropriate parameters of precision, accuracy, repeatability and linearity. The developed method could be used for quality control testing of phenols in concrete during the construction of new buildings, old residences and construction waste. The measurement uncertainty of the phenolic compounds in concrete was evaluated using two approaches, i.e., GUM recommendations and a Monte Carlo method. Disagreement of those methods was observed. The Monte Carlo method could be used in the evaluation of combined measurement uncertainty for the determination of phenolic compounds in concrete. [Project of the Serbian Ministry of Education, Science and Technological Development, Grant no. TR 37021
Application of fuzzy logic for evaluation of the level of social acceptance of waste treatment
GPU-based optical simulation of the DARWIN detector
Understanding propagation of scintillation light is critical for maximizing the discovery potential of next-generation liquid xenon detectors that use dual-phase time projection chamber technology. This work describes a detailed optical simulation of the DARWIN detector implemented using Chroma, a GPU-based photon tracking framework. To evaluate the framework and to explore ways of maximizing efficiency and minimizing the time of light collection, we simulate several variations of the conventional detector design. Results of these selected studies are presented. More generally, we conclude that the approach used in this work allows one to investigate alternative designs faster and in more detail than using conventional Geant4 optical simulations, making it an attractive tool to guide the development of the ultimate liquid xenon observatory