Modelling of Electroluminescence in Polymers Using a Bipolar Charge Transport Model

Electroluminescence (EL) in polymeric materials is thought to occur due to the energy dissipation process from the recombination of opposite polarity charge carriers. It is considered as an indication of storage and transport of charge carriers in cable insulation subject to electrical stresses and may indicate the change in charge movement due to aging or degradation processes. Under ac electric fields, the interaction of opposite polarity charge carriers at the interface of polymer/conductor is enhanced compared with dc conditions, and seems to contribute a lot to the electroluminescence rather than the charge behaviours in the bulk of polymers. The dynamics of charge carriers both at the interface of polymer/conductor and in the bulk of polymers is investigated through a simulation work using a bipolar charge transport model. Figure 1 compares experimental electroluminescence results with simulated data from the recombination of injected charge carriers. The paper will give more details on EL model and comparison under various waveforms and frequencies

A Comparison between Electroluminescence Models and Experimental Results

Electrical insulation ages and degrades until its eventual failure under electrical stress. One cause of this relates to the movement and accumulation of charge within the insulation. The emission of a low level of light from polymeric materials while under electrical stressing occurs before the onset of currently detectable material degradation. This light is known as electroluminescence (EL) and under an ac electric field is thought to relate to the interaction of charge in close proximity to the electrode-polymer interface. Understanding the cause of this light emission gives a very high-resolution method of monitoring charge interaction and its influence on material ageing. A possible cause of this light emission is the bipolar charge recombination theory. This theory involves the injection, trapping and recombination of charge carriers during each half cycle of the applied field [1]. This work compares two models that to simulate the EL emission according to this bipolar charge recombination theory. Model 1 assumes a fixed space charge region and all injected charge is uniformly distributed in this region with charges able to either become trapped or to recombine with opposite polarity charge carriers [2]. This recombination relates directly the excitation needed for the emission of a photon of light as measured in experiments. Model 2 develops on this by accounting for the transport and extraction of charge with an exponential distribution of trap levels rather than a uniform distribution [3]. Figure 1 shows a good correlation between the two models and experimental data. The full paper will describe the models in more detail and present results comparing the simulated and experimental results under various applied waveforms. Model 1 and model 2 both provide a good correlation with experimental data but model 2 allows a greater understanding of the space charge profile in the region close to the electrodes as well as the shape of the conduction current. Further work involves developing these models to support changes in the charge trapping profiles due to material ageing and supporting simulated results with measured conduction current

Do earplugs stop noise from driving critical care patients into delirium?

Quality sleep is a problem for the critically ill who are cared for in an environment where interventions night and day are common, staff members are constantly present in relatively high numbers, and treatment is accompanied by a range of changing warning tones and alarms and lights. These critical care units are generally designed without a focus on patient comfort, sleep, and rest and often lack access to appropriate natural daylight. To add to this problem, critical illness, particularly sepsis, disrupts circadian rhythms and sleep patterns, and disruption of circadian rhythms, in turn, impairs immunity and contributes to delirium. In a randomized controlled trial in the previous issue of Critical Care, Van Rompaey and colleagues have intervened to reduce noise, which is a key factor in this disruption, by having patients use earplugs at night. Delirium was assessed by using the NEECHAM (Neelon and Champagne) confusion scale, and sleep perception was assessed by patients' responses to a set of five questions. After the first night, patients reported a better sleep perception and the occurrence of delirium was reduced (hazard ratio of 0.47 for the development of delirium) or was delayed. The study did not quantify adequacy of pain control in post-surgical patients and used patient reporting to assess sleep. Whether patients were receiving respiratory or other organ support was not reported. The potential benefit of earplugs is an important practical finding that could be implemented in most intensive care units

Effect Of Defaults And Credit Deterioration On Yields Of Corporate Bonds

Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/91112/1/j.1540-6261.1961.tb02839.x.pd

Have ozone effects on carbon sequestration been overestimated?: a new biomass response function for wheat

Elevated levels of tropospheric ozone can significantly impair the growth of crops. The reduced removal of CO2 by plants leads to higher atmospheric concentrations of CO2, enhancing radiative forcing. Ozone effects on economic yield, e.g. the grain yield of wheat (Triticum aestivum L.), are currently used to model effects on radiative forcing. However, changes in grain yield do not necessarily reflect changes in total biomass. Based on an analysis of 22 ozone exposure experiments with field-grown wheat, we investigated whether the use of effects on grain yield as a proxy for effects on biomass under- or overestimates effects on biomass. First, we confirmed that effects on partitioning and biomass loss are both of significant importance for wheat yield loss. Then we derived ozone dose response functions for biomass loss and for harvest index (the proportion of above-ground biomass converted to grain) based on 12 experiments and recently developed ozone uptake modelling for wheat. Finally, we used a European-scale chemical transport model (EMEP MSC-West) to assess the effect of ozone on biomass (−9%) and grain yield (−14%) loss over Europe. Based on yield data per grid square, we estimated above-ground biomass losses due to ozone in 2000 in Europe, totalling 22.2 million tonnes. Incorrectly applying the grain yield response function to model effects on biomass instead of the biomass response function of this paper would have indicated total above-ground biomass losses totalling 38.1 million (i.e. overestimating effects by 15.9 million tonnes). A key conclusion from our study is that future assessments of ozone-induced loss of agroecosystem carbon storage should use response functions for biomass, such as that provided in this paper, not grain yield, to avoid overestimation of the indirect radiative forcing from ozone effects on crop biomass accumulation

Effects of air pollution on natural vegetation and crops

The present report is being submitted for the consideration of the Working Group on Effects in accordance with the request of the Executive Body for the Convention on Longrange Transboundary Air Pollution in the 2012–2013 workplan for the implementation of the Convention (ECE/EB.AIR/109/Add.2, items 3.1 (c) and 3.5). The report of the International Cooperative Programme on Effects of Air Pollution on Natural Vegetation and Crops presents the results of ozone impacts on ecosystem services and biodiversity, and the results of the pilot study on mosses as biomonitors of persistent organic pollutants as part of the European moss survey conducted in 2010/11. In addition, the results of the workplan items common to all programmes are presented