CLIMATE AND COOPERATION: A NEW PERSPECTIVE ON THE MANAGEMENT OF SHARED FISH STOCKS

Climate regime shifts occur at irregular intervals and have profound and persistent impacts on ocean temperature and circulation patterns and on the dynamics of marine fish populations. Despite a growing scientific literature and some attention to the implications of such regime shifts for domestic fisheries, the issue has received little attention in the context of international fishery management. This paper presents evidence for the significance of climatic regime shifts, and draws upon the recent history of conflict between Canada and the United States over Pacific salmon management to illustrate the dangers that unpredicted, unanticipated environmental regime shifts pose for efforts to maintain international cooperation. This suggests a need for greater attention to this issue. Fishery agreements can be made more resilient to the impacts of such environmental changes by explicitly building in flexibility — for example, by allowing the use of side payments. In addition, pre-agreements on procedures to be followed in the event of sustained changes in fish stock productivity or migration patterns, and cooperation on developing common scientific understandings, can help to prevent destructive conflicts. Finally, the literature employing game theoretic shared-fishery models could be further developed to focus on providing practical guidance for maintaining cooperation in the presence of unpredictable and persistent environmental changes.climate regimes, shared fisheries, potential conflicts, uncertainty, Q21, Q22, Resource /Energy Economics and Policy,

Temporary Enterostomy in the Correction of Intestinal Intussusception

Dr. Fred Neal, the clinician on this case, offers two reasons why a temporary enterostomy may be helpful in the successful surgical correction of intestinal intussusception

Preparation, crystal structure, heat capacity, magnetism, and the magnetocaloric effect of Pr5Ni1.9Si3 and PrNi

Single-phase Pr5Ni1.9Si3 and PrNi were prepared and characterized by using differential thermal analysis, single crystal, and powder x-ray diffraction. Their thermal and magnetic properties were studied by measuring heat capacity as a function of temperature in magnetic fields up to 100 kOe and magnetization as a function of magnetic field up to 50 kOe over the temperature range from 5 to 400 K. Pr5Ni1.9Si3 orders magnetically at 50 K, and it undergoes a second transition at 25 K. As inferred from the behavior of the magnetization and magnetocaloric effect (MCE), both ferromagnetic and antiferromagnetic components are present in the magnetic ground state of the material. The heat capacity and magnetocaloric effect of PrNi confirm that it orders ferromagnetically at 19 K. Both Pr5Ni1.9Si3 and PrNi exhibit moderate magnetocaloric effects. The maximum MCE for Pr5Ni1.9Si3 is 3.4 K and it is observed at 50 K for a magnetic field change from 0 to 75 kOe. The maximum MCE for PrNi is 4.2 K, which occurs at 19 K for a magnetic field change from 0 to 100 kOe

Los Angeles and the Owens River Aqueduct

The following pages recount the struggle and criticism that went into bringing the first imported water to Los Angeles, the reasons the water was necessary, the legal bases on which water was acquired, and the end results on the distant Owens River Valley

The Properties of Radio Galaxies and the Effect of Environment in Large Scale Structures at z∼1z\sim1

In this study we investigate 89 radio galaxies that are spectroscopically-confirmed to be members of five large scale structures in the redshift range of $0.65 \le z \le 0.96$. Based on a two-stage classification scheme, the radio galaxies are classified into three sub-classes: active galactic nucleus (AGN), hybrid, and star-forming galaxy (SFG). We study the properties of the three radio sub-classes and their global and local environmental preferences. We find AGN hosts are the most massive population and exhibit quiescence in their star-formation activity. The SFG population has a comparable stellar mass to those hosting a radio AGN but are unequivocally powered by star formation. Hybrids, though selected as an intermediate population in our classification scheme, were found in almost all analyses to be a unique type of radio galaxies rather than a mixture of AGN and SFGs. They are dominated by a high-excitation radio galaxy (HERG) population. We discuss environmental effects and scenarios for each sub-class. AGN tend to be preferentially located in locally dense environments and in the cores of clusters/groups, with these preferences persisting when comparing to galaxies of similar colour and stellar mass, suggesting that their activity may be ignited in the cluster/group virialized core regions. Conversely, SFGs exhibit a strong preference for intermediate-density global environments, suggesting that dusty starbursting activity in LSSs is largely driven by galaxy-galaxy interactions and merging.Comment: 28 pages, 10 figures, accepted to MNRA

Structure of Large Nitrate−Water Clusters at Ambient Temperatures: Simulations with Effective Fragment Potentials and Force Fields with Implications for Atmospheric Chemistry

Structural properties of large NO3−·(H2O)n (n = 15−500) clusters are studied by Monte Carlo simulations using effective fragment potentials (EFPs) and by classical molecular dynamics simulations using a polarizable empirical force field. The simulation results are analyzed with a focus on the description of hydrogen bonding and solvation in the clusters. In addition, a comparison between the electronic structure based EFP and the classical force field description of the 32 water cluster system is presented. The EFP simulations, which focused on the cases of n = 15 and 32, show an internal, fully solvated structure and a “surface adsorbed” structure for the 32 water cluster at 300 K, with the latter configuration being more probable. The internal solvated structure and the “surface adsorbed” structure differ considerably in their hydrogen bonding coordination numbers. The force field based simulations agree qualitatively with these results, and the local geometry of NO3− and solvation at the surface-adsorbed site in the force field simulations are similar to those predicted using EFPs. Differences and similarities between the description of hydrogen bonding of the anion in the two approaches are discussed. Extensive classical force field based simulations at 250 K predict that long time scale stability of “internal” NO3−, which is characteristic of extended bulk aqueous interfaces, emerges only for n \u3e 300. Ab initio Møller−Plesset perturbation theory is used to test the geometries of selected surface and interior anions for n = 32, and the results are compared to the EFP and MD simulations. Qualitatively, all approaches agree that surface structures are preferred over the interior structures for clusters of this size. The relatively large aqueous clusters of NO3− studied here are of comparable size to clusters that lead to new particle formation in air. Nitrate ions on the surface of such clusters may have significantly different photochemistry than the internal species. The possible implications of surface-adsorbed nitrate ions for atmospheric chemistry are discussed

Cassini/CIRS Observations of Water Vapor in Saturn's Stratosphere

The Composite Infrared Spectrometer (CIRS) on the Cassini spacecraft has obtained numerous spectra of Saturn at varying spectral and spatial resolutions since Saturn Orbit Insertion in 2001. Emission lines due to water vapor in Saturn's stratosphere were first detected using whole-disk observations from the Infrared Space Observatory [1] and subsequently confirmed by the Submillimeter Wave Astronomy Satellite [2], CIRS has detected water and the data permit the retrieval of the latitudinal variation of water on Saturn. Emission lines of H2O on Saturn are very weak in the CIRS data. Thus, large spectral averages as well as improvements in calibration are necessary to detect water vapor. long integrations at the full 0.5/cm spectral resolution were performed at targeted latitudes on Saturn. High emission angles were chosen to enhance stratospheric emission. Over the course of the prime and extended mission a set of observations has been built up spaced roughly every 10 degrees of latitude. Stratospheric temperatures in the 0.5 - 5.0 mbar range were obtained by inverting spectra of CH4 in the v'4 band centered at 1501/cm. The origin of water vapor is believed to be from the ablation of micrometeorites containing eater ice, followed by photochemistry. This external source of oxygen originates either from the Saturn system (from the rings or perhaps from Enceladus) or from the interplanetary medium. Connerney [3] proposed a mechanism to transport water from the inner edge of the B-ring along magnetic field lines to specific latitudes (50N and 44S) on Saturn. Prange et al [4] interpreted a minimum in the abundance of acetylene from ultraviolet spectra gear 41S on Saturn as possibly due to an enhanced influx of water. We will be able to test the "ring rain" mechanism by searching, for localized water vapor enhancement at mid-latitudes. Our results may be used to constrain photochemical models of Saturn's stratosphere [5]

Sidechain control of porosity closure in multiple peptide-based porous materials by cooperative folding

Porous materials find application in separation, storage and catalysis. We report a crystalline porous solid formed by coordination of metal centres with a glycylserine dipeptide. We prove experimentally that the structure evolves from a solvated porous into a non-porous state as result of ordered displacive and conformational changes of the peptide that suppress the void space in response to environmental pressure. This cooperative closure, which recalls the folding of proteins, retains order in three-dimensions and is driven by the hydroxyl groups acting as H-bond donors in the peptide sequence through the serine residue. This ordered closure is also displayed by multipeptide solid solutions in which the combination of different sequences of amino acids controls their guest response in a non-linear way. This functional control can be compared to the effect of single point mutations in proteins, where the exchange of single amino acids can radically alter structure and functio