59 research outputs found
In-plane Anisotropy of the Magnetic Fluctuations in NaxCoO2-yH2O
We report the Co NMR studies of the in-plane anisotropy of bilayer
hydrated Na using a oriented
powder sample by a magnetic field in Fluorinert FC70. We found for the first
time the -plane anisotropy of the Co NMR Knight shift , the
nuclear spin-lattice relaxation rate 1/ and the nuclear spin-spin
relaxation rate 1/ at a magnetic field 7.5 T up to 200K. Below
75 K, the anisotropy of is large compared with that at high temperatures.
The hyperfine coupling constants seem to change around the temperature 150 K,
in which the bulk susceptibility shows broad minimum, suggesting a
change of the electronic state of CoO plane. 1/ also shows a
significant anisotropy, which cannot be explained only by the anisotropy of the
hyperfine coupling constants nor the anisotropic uniform spin susceptibility.
The difference in the in-plane anisotropy of from that of indicates
that the magnetic fluctuation at a finite wave vector is also
anisotropic and the anisotropy is different from that at .Comment: 4 pages, 5 figure
Weak Magnetic Order in the Bilayered-hydrate NaCoOHO Structure Probed by Co Nuclear Quadrupole Resonance - Proposed Phase Diagram in Superconducting NaCoO HO
A weak magnetic order was found in a non-superconducting bilayered-hydrate
NaCoOHO sample by a Co Nuclear Quadrupole Resonance
(NQR) measurement. The nuclear spin-lattice relaxation rate divided by
temperature shows a prominent peak at 5.5 K, below which a Co-NQR peak
splits due to an internal field at the Co site. From analyses of the Co NQR
spectrum at 1.5 K, the internal field is evaluated to be 300 Oe and is
in the -plane. The magnitude of the internal field suggests that the
ordered moment is as small as using the hyperfine coupling
constant reported previously. It is shown that the NQR frequency
correlates with magnetic fluctuations from measurements of NQR spectra and
in various samples. The higher- sample has the stronger
magnetic fluctuations. A possible phase diagram in NaCoOHO is depicted using and , in which the crystal distortion
along the c-axis of the tilted CoO octahedron is considered to be a
physical parameter. Superconductivity with the highest is seemingly
observed in the vicinity of the magnetic phase, suggesting strongly that the
magnetic fluctuations play an important role for the occurrence of the
superconductivity.Comment: 5 pages, 6 figures, submitted to J. Phys. Soc. Jp
23Na NMR study of non-superconducting double-layer hydrate NaxCoO2.yH2O
We report 23Na NMR studies of the polycrystalline samples of double-layer
hydrated cobalt oxides NaxCoO2.yH2O (x ~ 0.35 and y ~ 1.3) with the
superconducting transition temperatures Tc < 1.8K and ~4.5K, and the dehydrated
NaxCoO2 (x ~ 0.35). The hyperfine field and the electric field gradient at the
Na sites in the non-hydrated Na0.7CoO2 and the dehydrated Na0.35CoO2 are found
to be significantly reduced by the hydration, which indicates a strong
shielding effect of the intercalated water molecules on the Na sites. The
temperature dependence of 23 Na nuclear spin-lattice relaxation rate 1/23T1 of
the non-superconducting double-layer hydrate NaxCoO2.yH2O is found to be
similar to that of the non-hydrated Na0.7CoO2, whose spin dynamics is
understood by A-type (intra-layer ferromagnetic and inter-layer
antiferromagnetic) spin fluctuations. The superconducting phase is located
close to the quantum critical point with the A-type magnetic instability.Comment: 4 pages, 4 figure
Co-NMR Knight Shift of NaxCoO2 \dot yH2O Studied in Both Superconducting Regions of the Tc-nuQ3 Phase Diagram Divided by the Nonsuperconducting Phase
In the temperature (T)-nuQ3 phase diagram of NaxCoO2 \dot yH2O, there exist
two superconducting regions of nuQ3 separated by the nonsuperconducting region,
where nuQ3 is usually estimated from the peak position of the 59Co-NQR spectra
of the 5/2-7/2 transition and well-approximated here as nuQ3~3nuQ,nuQ being the
interaction energy between the nuclear quadrupole moment and the electric field
gradient. We have carried out measurements of the 59Co-NMR Knight shift (K) for
a single crystal in the higher-nuQ3 superconducting phase and found that K
begins to decrease with decreasing T at Tc for both magnetic field directions
parallel and perpendicular to CoO2-planes. The result indicates together with
the previous ones that the superconducting pairs are in the spin-singlet state
in both phases, excluding the possibility of the spin-triplet superconductivity
in this phase diagram. The superconductivity of this system spreads over the
wide nuQ3 regions, but is suppressed in the narrow region located at the middle
point of the region possibly due to charge instability.Comment: 8 pages, 5 figures, submitted to J. Phys. Soc. Jp
Site-selective Cu NMR study of the vortex cores of TlBaCuO
We report site-selective Cu NMR studies of the vortex core states of
an overdoped TlBaCuO with = 85 K. We observed
a relatively high density of low-energy quasi-particle excitations at the
vortex cores in a magnetic field of 7.4847 T along the c axis, in contrast to
YBaCuO.Comment: 5 pages, 6 figures, submitted to J. Phys. Chem. Solids (QuB2006,
Tokai
Itinerant electron magnetism of η-carbides Co6M6C and Ni6M6C (M=Mo and W)
Magnetic, transport, and thermal properties of metallic η-carbides Co6M6C and Ni6M6C (M = Mo and W) with the cubic Ni6Mo6C-type structure have been characterized. The Ni-based compounds Ni6Mo6C and Ni6W6C are Pauli paramagnets with temperature-independent susceptibilities. Susceptibilities of the Co-based compounds Co6Mo6C and Co6W6C are enhanced and temperature-dependent. Co6Mo6C remains paramagnetic down to the lowest temperature, while Co6W6C undergoes an antiferromagnetic-type transition at 46 K. A metamagnetic transition was observed for Co6W6C at 20–30 T at the lowest temperatures. The correlation among the enhancements in the susceptibility, the resistivity, and the electronic specific heat suggests the presence of moderate electron correlation in these compounds
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