Orthorhombic phase of La0.5_{0.5}Bi0.5_{0.5}NiO3_{3} studied by first principles

The aim of presented first principles study of La$_{0.5}$Bi$_{0.5}$NiO$_{3}$ is to investigate electronic structure of orthorhombic phase Pbnm. The calculations show that metallicity and magnetism of the system are strongly related with hybridization between Ni 3d and O 2p. To improve the quality of the electronic structure description of the system, especially the treatment of correlation for the Ni 3d, we employ GGA, LDA, and GGA+U, LDA+U. The LSDA results give good agreement with experiment. Thus, the screening effects originating from the hybridized 3d and O 2p electrons are sufficiently strong that they reduce the electronic correlations in the La$_{0.5}$Bi$_{0.5}$NiO$_{3}$, making it a weakly correlated metal.Comment: 4 pages, 3 figures; The European Conference Physics of Magnetism 2017, submitted to Acta Physica Polonica

Electronic structure and X-ray photoelectron spectra of YNi4B compound

The electronic structure of the tern ary Y Ni4 B compoun d, crystalli zin g in the hexagonal CeCo4 B structure ( P 6= m m m space group ), was studied by X -ray photo electron spectroscopy and ab initio calculations. Core levels and the valence band were investigated. T he X- ray photo electron spectroscopy valence band is compared with that obtained from ab initi o calculations. The valence band spectrum at the Fermi level exhibits the domination of the Ni( 3 d ) states, which are hybridized with 4d states of Y and 2p states of B. The theoretical electronic specific heat coeffcient Û derived from N ( E F ) is about 11.33 mJ /(mol K 2 ) for exp erimental lattice parameters. T he calculated bulk modulus is B 0 = 1 :61632 Mbar

Implications of GATT for Eastern Europe and the Baltics

The story of agriculture in Eastern Europe during the last quarter century is a story of policy driven by politics, rather than by sound economics. Even in the highly distorted economics of the socialist period, agricultural policy stands out as being singularly colored by ideological imperatives, and singularly vulnerable to interest group pressures. While the revolutions of 1989-91 did mark a sharp move towards liberalization, these moves are now being slowed and even reversed, as countries of the region adopt Western style interventionism on preparation for accession to the European Union

Effect of multi-component fertilizers on seeds yield, yield components and physiological parameters of winter oilseed rape (Brassica napus L.)

ArticleSubject of the discussed studies was an analysis of the impact of mineral multicomponent fertilizers, from Polish and foreign producers, on the yield and yield components of winter oilseed rape (Brassica napus var. oleifera). Two field experiments were carried out in 2015–2017 in Lipnik. The experimental crop was winter oilseed rape, hybrid cultivar DK EXPLICIT. Two factors were studied in the experiment A: 4 multi-component mineral fertilizers - two Belarusian (1 i 2), one Russian and one Polish (Polifoska 6) and 4 doses of fertilization (250, 500 and 750 kg ha-1 ). In the experiment (B) were compared two factors: 3 multi-component mineral fertilizers - Belarusian, Russian and Polish production - Polifoska 8 and 4 doses of fertilization (200, 400 and 600 kg ha-1 ). The fertilizers applied in the experiments, manufactured in Belarus, Russia and Poland, did not show variations in the amount of yield of winter rape. The number of winter rapeseed plants on the area unit (in autumn and spring) was independent of the type of fertilizers. In the experiment B, higher number of rapeseed siliques was obtained after application of Polifoska 8, than other fertilizers. Rapeseed grown on soil with the fertilizers manufactured in Belarus showed a lower value of greenness index (SPAD) and leaf area index (LAI). As a result of the application of multi-component fertilizers, manufactured in Belarus, Russia and Poland, the recorded differences in the winter rapeseed yield, yield components and physiological parameters did not exceed 10%

Modyfikacja powierzchni stopu Ti-6Al-4V metodą PEO-EPD w zawiesinie ZrSiO4

Investigations on the surface modification of the Ti-6Al-4V alloy by plasma electrolytic oxidation are reported here. The oxidation process was carried out in a solution containing a zirconium silicate (ZrSiO4) suspension and sodium hydroxide (NaOH). Anodising was realised at voltages in a range from 100 V to 250 V. It was found that the morphology of the sample surface did not change during the oxidation of the alloy at 100 V. Application of voltages higher than 100 V led to the incorporation of zirconium silicate into the formed oxide layer and to significant changes of the surface morphology