3 research outputs found
The Quest to Quit: an Exploration of the Cessation - Relapse Cycle of Cigarette Smoking
The smoker's perspective is seldom sought in cessation research. Consequently, cessation approaches may be less effective because they are not based on assumptions and interpretations shared by those who smoke. Understanding how chronic relapsing smokers interpret their predicament could enhance cessation approaches,
improving the chances for complete, permanent cessation. To generate such an understanding, five participants were recruited who had attempted to quit smoking several times. Aiming for depth rather than breadth, multiple interviews were conducted with each participant, who also kept an event diary, recording current smoking,
nicotine withdrawal, lapsing and relapsing. Narratology, a biographical method of symbolic interactionism drawing on thematic, structural, and dialogic analysis, was used to elicit the participants' points of view from interview and diary data. The findings show that participants make sense of their chronic relapsing through a master narrative of 'willpower versus weakness'. Meanwhile, the tobacco control domain is largely driven by 'cost', and subsidised treatments are driven by the 'addiction' master narrative. This gap between ways of making sense of smoking and relapse can cause self-stigma, reducing the likelihood that quitting will be attempted and that quit attempts will succeed. Changes are proposed to mitigate the negative effects on self-efficacy
brought about through the present approach to tobacco control. Ways to improve the effectiveness of existing treatments are suggested. Finally, the value of the narrative method is highlighted, with suggestions for its use in research where elucidating the insider
point of view may improve treatment outcomes
Excited States of Pt(PF<sub>3</sub>)<sub>4</sub> and Their Role in Focused Electron Beam Nanofabrication
Electron
induced chemistry of metal-containing precursor molecules
is central in focused electron beam induced deposition (FEBID). While
some elementary processes leading to precursor decomposition were
quantitatively characterized, data for neutral dissociation is missing.
We provide this data for the model precursor Pt(PF<sub>3</sub>)<sub>4</sub> by using the available cross sections for electronic excitation
and characterizing fragmentation of the excited states theoretically
by TDDFT. The potential energy curves for a number of states visible
in the experimental electron energy loss spectra are dissociative,
either directly or via conical intersections, indicating that the
quantum yield for dissociation is close to 100%. Taking into account
typical electron energy distribution at the FEBID spot reveals that
the importance of neutral dissociation exceeds that of dissociative
electron attachment, which has been so far considered to be the dominant
decomposition process. We thus established neutral dissociation as
an important, albeit often neglected, channel for FEBID using Pt(PF<sub>3</sub>)<sub>4</sub>. The calculations revealed a number of other
phenomena that can play a role in electron induced chemistry of this
compound, e.g., a considerable increase of bond dissociation energy
with sequential removal of multiple ligands
Joint Experimental and Theoretical Study on Vibrational Excitation Cross Sections for Electron Collisions with Diacetylene
We have measured and calculated differential
and integral cross
sections for elastic and vibrationally inelastic electron scattering
by diacetylene molecules at electron energies from 0.5 to 20 eV in
the whole range of scattering angles from 0 to 180°. The calculations
were carried out using the discrete momentum representation method
(DMR), which is based on the two-channel Lippmann–Schwinger
equation in the momentum space. The interaction between the scattered
electron and the target molecule is described by the exact static-exchange
potential. Correlation–polarization forces are included by
a local density functional theory. Energy dependences of integral
and differential cross sections are presented for all nine vibrational
modes. A detailed comparison of theoretical and experimental electron
energy loss spectra is presented for electron energies of 1, 5.5,
10, and 20 eV. The theory assigns symmetry of resonances that could
not be determined by empirical analysis alone. The theory reveals,
and quantitatively describes, the switching of partial waves accompanying
excitation of nontotally symmetrical vibrations. Limitations of the
theory in reproducing experimental data for the narrow π* resonance
below 2 eV are mentioned