Novel Mode of Trisiloxane Application Reduces Spider Mite and Aphid Infestation of Fruiting Shrub and Tree Crops

Application of pesticides leads to contamination of the natural environment, which entails the necessity to seek solutions that use substances which do not pose ecological hazards. The presented investigations tested the efficacy of a preparation containing organomodified trisiloxane and a cross-linking agent (Siltac EC) to limit the number of two-spotted spider mite (Tetranychus urticae) on the leaves of raspberry (Rubus idaeus) and blackcurrant (Ribes nigrum), as well as the numbers of green apple aphid (Aphis pomi) on apple trees (Malus domestica). The high effectiveness (more than 90%) of Siltac against spider mite on raspberry and blackcurrant leaves was rapid and persisted at least by two- three weeks after spraying. There was observed an inhibition of pest developing (i.e. significant decrease of eggs and larvae). Similar effect occurred per an apple tree shoot and the number of living apple aphids was reduced by more than 93% in comparison to untreated trees. In all experiments, the effectiveness of Siltac was similar and usually longer lasting than control pesticides. Moreover, no phytotoxicity of the tested preparation was observed during the investigations. In conclusion, on the basis of the presented results it was found that Siltac EC could be a good alternative to the currently used plant protection chemicals

Identification and quantification of fatty acids in hunting web of adult Steatoda grossa (Theridiidae) female spiders

This is the first study on composition of fatty acids in hunting web of Steatoda grossa (Theridiidae) spiders and one of only four similar studies ever made. Its main contribution is a discovery that fatty acids not only cover an outside of the web fibers, but they are even more abundantly represented in the fibers’ inner structure. Although little attention has been so far attributed to the contents of fatty acids in spider silks, one has to remember that their biocompatibility combined with an extraordinary tensile strength make them a worth investigating template for material bioengineering studies

Preliminary evaluation of application of a 3-dimensional network structure of siloxanes Dergall preparation on chick embryo development and microbiological status of eggshells

The spatial network structure of Dergall is based on substances nontoxic to humans and the environment which, when applied on solid surfaces, creates a coating that reduces bacterial cell adhesion. The bacteriostatic properties of siloxanes are based on a purely physical action mechanism which excludes development of drug-resistant microorganisms. The aims of the present study were to 1) evaluate a Dergall layer formed on the eggshell surface regarding the potential harmful effects on the chick embryo; 2) evaluate antimicrobial activity and estimate the prolongation time of Dergall's potential antimicrobial activity. Dergall at a concentration of 0.6% formed a layer on the eggshell surface. In vitro testing of the potential harmful effects of Dergall by means of a hen embryo test of the chorioallantoic membrane showed no irritation reaction at a concentration of 3% and lower. The hatchability of the groups sprayed with a Dergall water solution with a concentration of 0 to 5% was 89.1 to 93.8% for fertilized eggs (P > 0.05) but decreased to 63.7% (P < 0.05) in the group sprayed with a 6% concentration of the solution. This phenomenon was caused by embryo mortality in the first week of incubation. At the concentration of 0.6%, Dergall exhibited strong antibacterial properties against bacteria such as Staphylococcus aureus, Escherichia coli, Shigella dysenteriae, Shigella flexneri, and Salmonella typhimurium. For Streptococcus pyogenes, the highest antibacterial activity of Dergall was reported in the concentrations of 100 and 50%. For Pseudomonas aeruginosa, no antibacterial activity of Dergall was generally observed, but in vivo testing showed a strong decrease of all gram-negative bacteria growth. Moreover, a prolonged antimicrobial effect lasting until 3 D after disinfection was observed, which makes Dergall a safe and efficient disinfectant

Preparation of Ruthenium Olefin Metathesis Catalysts Immobilized on MOF, SBA-15, and 13X for Probing Heterogeneous Boomerang Effect

Promoted by homogeneous Ru-benzylidene complexes, the olefin metathesis reaction is a powerful methodology for C-C double bonds formation that can find a number of applications in green chemical production. A set of heterogeneous olefin metathesis pre-catalysts composed of ammonium-tagged Ru-benzylidene complexes 4 (commercial FixCat&trade; catalyst) and 6 (in-house made) immobilized on solid supports such as 13X zeolite, metal-organic framework (MOF), and SBA-15 silica were obtained and tested in catalysis. These hybrid materials were doped with various amounts of ammonium-tagged styrene derivative 5&mdash;a precursor of a spare benzylidene ligand&mdash;in order to enhance pre-catalyst regeneration via the so-called release-return &ldquo;boomerang effect&rdquo;. Although this effect was for the first time observed inside the solid support, we discovered that non-doped systems gave better results in terms of the resulting turnover number (TON) values, and the most productive were hybrid catalysts composed of 4@MOF, 4@SBA-15, and 6@SBA-15

Hepatic Hemangioma: Review of Imaging and Therapeutic Strategies

Hepatic hemangiomas are the most common benign liver tumors. Typically, small- to medium-sized hemangiomas are asymptomatic and discovered incidentally through the widespread use of imaging techniques. Giant hemangiomas (>5 cm) have a higher risk of complications. A variety of imaging methods are used for diagnosis. Cavernous hemangioma is the most frequent type, but radiologists must be aware of other varieties. Conservative management is often adequate, but some cases necessitate targeted interventions. Although surgery was traditionally the main treatment, the evolution of minimally invasive procedures now often recommends transarterial chemoembolization as the treatment of choice