Overcharging: The Crucial Role of Excluded Volume

In this Letter we investigate the mechanism for overcharging of a single spherical colloid in the presence of aqueous salts within the framework of the primitive model by molecular dynamics (MD) simulations as well as integral-equation theory. We find that the occurrence and strength of overcharging strongly depends on the salt-ion size, and the available volume in the fluid. To understand the role of the excluded volume of the microions, we first consider an uncharged system. For a fixed bulk concentration we find that upon increasing the fluid particle size one strongly increases the local concentration nearby the colloidal surface and that the particles become laterally ordered. For a charged system the first surface layer is built up predominantly by strongly correlated counterions. We argue that this a key mechanism to produce overcharging with a low electrostatic coupling, and as a more practical consequence, to account for charge inversion with monovalent aqueous salt ions.Comment: 7 pages, 3 figs (4 EPS files). To appear in Europhysics Letter

High Efficiency Detection of Argon Scintillation Light of 128nm Using LAAPDs

The possibility of efficient collection and detection of vacuum ultraviolet light as emitted by argon, krypton, and xenon gas is studied. Absolute quantum efficiencies of large area avalanche photodiodes (LAAPDs) are derived at these wavelengths. VUV light of wavelengths down to the 128nm of Ar emission is shown to be detectable with silicon avalanche photodiodes at quantum efficiencies above 42%. Flexible Mylar foil overcoated with Al+MgF$_2$ is measured to have a specular reflectivity of $\sim$91% at argon emission wavelength. Low-pressure argon gas is shown to emit significant amounts of non-UV radiation. The average energy expenditure for the creation of non-UV photons in argon gas at this pressure is measured to be below 378 eV.Comment: 5 pages, 4 figures, Talk given at IEEE 2005 Nuclear Science Symposium and Medical Imaging Conference, Puerto Ric

Patterning molecular scale paramagnets at Au Surface: A root to Magneto-Molecular-Electronics

Few examples of the exploitation of molecular magnetic properties in molecular electronics are known to date. Here we propose the realization of Self assembled monolayers (SAM) of a particular stable organic radical. This radical is meant to be used as a standard molecule on which to prove the validity of a single spin reading procedure known as ESR-STM. We also discuss a range of possible applications, further than ESR-STM, of magnetic monolayers of simple purely organic magnetic molecule.Comment: This preprint is currently partially under revisio

Stimulated Raman adiabatic passage in an open quantum system: Master equation approach

A master equation approach to the study of environmental effects in the adiabatic population transfer in three-state systems is presented. A systematic comparison with the non-Hermitian Hamiltonian approach [N. V. Vitanov and S. Stenholm, Phys. Rev. A {\bf 56}, 1463 (1997)] shows that in the weak coupling limit the two treatments lead to essentially the same results. Instead, in the strong damping limit the predictions are quite different: in particular the counterintuitive sequences in the STIRAP scheme turn out to be much more efficient than expected before. This point is explained in terms of quantum Zeno dynamics.Comment: 11 pages, 4 figure

Dissipation and entanglement dynamics for two interacting qubits coupled to independent reservoirs

We derive the master equation of a system of two coupled qubits by taking into account their interaction with two independent bosonic baths. Important features of the dynamics are brought to light, such as the structure of the stationary state at general temperatures and the behaviour of the entanglement at zero temperature, showing the phenomena of sudden death and sudden birth as well as the presence of stationary entanglement for long times. The model here presented is quite versatile and can be of interest in the study of both Josephson junction architectures and cavity-QED.Comment: 14 pages, 3 figures, submitted to Journal of Physics A: Mathematical and Theoretica

Resonant effects in a SQUID qubit subjected to non adiabatic changes

By quickly modifying the shape of the effective potential of a double SQUID flux qubit from a single-well to a double-well condition, we experimentally observe an anomalous behavior, namely an alternance of resonance peaks, in the probability to find the qubit in a given flux state. The occurrence of Landau-Zener transitions as well as resonant tunneling between degenerate levels in the two wells may be invoked to partially justify the experimental results. A quantum simulation of the time evolution of the system indeed suggests that the observed anomalous behavior can be imputable to quantum coherence effects. The interplay among all these mechanisms has a practical implication for quantum computing purposes, giving a direct measurement of the limits on the sweeping rates possible for a correct manipulation of the qubit state by means of fast flux pulses, avoiding transitions to non-computational states.Comment: 6 pages and 6 figures. The paper, as it is, has been accepted for publication on PRB on March 201

Asymptotic Entanglement Dynamics and Geometry of Quantum States

A given dynamics for a composite quantum system can exhibit several distinct properties for the asymptotic entanglement behavior, like entanglement sudden death, asymptotic death of entanglement, sudden birth of entanglement, etc. A classification of the possible situations was given in [M. O. Terra Cunha, {\emph{New J. Phys}} {\bf{9}}, 237 (2007)] but for some classes there were no known examples. In this work we give a better classification for the possibile relaxing dynamics at the light of the geometry of their set of asymptotic states and give explicit examples for all the classes. Although the classification is completely general, in the search of examples it is sufficient to use two qubits with dynamics given by differential equations in Lindblad form (some of them non-autonomous). We also investigate, in each case, the probabilities to find each possible behavior for random initial states.Comment: 9 pages, 2 figures; revised version accepted for publication in J. Phys. A: Math. Theo