Intense Source of Slow Positrons

We describe a novel design for an intense source of slow positrons based on pair production with a beam of electrons from a 10 MeV accelerator hitting a thin target at a low incidence angle. The positrons are collected with a set of coils adapted to the large production angle. The collection system is designed to inject the positrons in a Greaves-Surko trap [1]. Such a source could be the basis for a series of experiments in fundamental and applied research and would also be a prototype source for industrial applications which concern the field of defect characterization in the nanometer scale.Comment: submitted to N.I.M.

Simulated solvation of organic ions II: Study of linear alkylated

International audienceWe investigated the solvation of carboxylate ions from formate to hexanoate, in droplets of 50 to 1000 water molecules and neat water, by computations using standard molecular dynamics and sophisticated polarizable models. The carboxylate ions from methanoate to hexanoate show strong propensity for the air/water interface in small droplets. Only the ions larger than propanoate retain propensity for the interface in larger droplets, where their enthalpic stabilization by ion/water dispersion is reduced there by 3 kcal mol–1 per CH2 group. This is compensated by entropy effects over +3.3 cal mol–1 K–1 per CH2 group. On the surface, the anionic headgroups are strongly oriented toward the aqueous core, while the hydrophobic alkyl chains are repelled into air and lose their structure-making effects. These results reproduce the structure-making effects of alkyl groups in solution, and suggest that the hydrocarbon chains of ionic headgroups and alkyl substituents solvate independently. Extrapolation to bulk solution using standard extrapolation schemes yields absolute carboxylate solvation energies. The results for formate and acetate yield a proton solvation enthalpy of about 270 kcal mol–1, close to the experiment-based value. The largest carboxylate ions yield a value smaller by about 10 kcal mol–1, which requires studies in much larger droplets

Spin dynamic tool developments and study regarding the Super-B project

International audience

Modeling the actinides with disordered local moments

A first-principles disordered local moment (DLM) picture within the local-spin-density and coherent potential approximations (LSDA+CPA) of the actinides is presented. The parameter free theory gives an accurate description of bond lengths and bulk modulus. The case of $\delta$-Pu is studied in particular and the calculated density of states is compared to data from photo-electron spectroscopy. The relation between the DLM description, the dynamical mean field approach and spin-polarized magnetically ordered modeling is discussed.Comment: 6 pages, 4 figure

O- vs. N-protonation of 1-dimethylaminonaphthalene-8-ketones: formation of a peri N–C bond or a hydrogen bond to the pi-electron density of a carbonyl group

X-ray crystallography and solid-state NMR measurements show that protonation of a series of 1-dimethylaminonaphthalene-8-ketones leads either to O protonation with formation of a long N–C bond (1.637–1.669 Å) between peri groups, or to N protonation and formation of a hydrogen bond to the π surface of the carbonyl group, the latter occurring for the larger ketone groups (C(O)R, R = t-butyl and phenyl). Solid state 15N MAS NMR studies clearly differentiate the two series, with the former yielding significantly more deshielded resonances. This is accurately corroborated by DFT calculation of the relevant chemical shift parameters. In the parent ketones X-ray crystallography shows that the nitrogen lone pair is directed towards the carbonyl group in all cases

Search for Superscreening effect in Superconductor

4 pages, 3 figures, Expérience au GANIL avec SPIRAL/EXOGAMThe decay of $^{19}$O($\beta^-$) and $^{19}$Ne($\beta^+$) implanted in niobium in its superconducting and metallic phase was measured using purified radioactive beams produced by the SPIRAL/GANIL facility. Half-lives and branching ratios measured in the two phases are consistent within one-sigma error bar. This measurement casts strong doubts on the predicted strong electron screening in superconductor, the so-called superscreening. The measured difference in screening potential energy is 110(90) eV for $^{19}$Ne and 400(320) eV for $^{19}$O. Precise determinations of the half-lives were obtained for $^{19}$O: 26.476(9)~s and $^{19}$Ne: 17.254(5)~s

Zgoubi users guide

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Simulation of radiation damping in rings using stepwise ray-tracing methods

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