Temperature dependence of surface stress across an order-disorder transition: p(1x2)O/W(110)

Strain relaxations of a p(1x2) ordered oxygen layer on W(110) are measured as a function of temperature across the disordering transition using low-energy electron diffraction. The measured strains approach values of 0.027 in the [1-10] and -0.053 in the [001] direction. On the basis of the measured strain relaxations, we give quantitative information on temperature-dependent surface stress using the results of ab initio calculations. From the surface formation energy for different strains, determined by first-principles calculations, we estimate that surface stress changes from -1.1 for the ordered phase to -0.2N/m for the disordered one along [1-10], and from 5.1 to 3.4 N/m along [001]. Moreover, our observation that the strains scale inversely with domain size confirms that the strain relaxation takes place at the domain boundaries.Comment: 8 pages, 5 figure

Spectromicroscopy of pulses transporting alkali metal in a surface reaction

The NO + H2 reaction on a potassium promoted Rh(110) surface is shown to sustain the formation of spatio-temporal periodic patterns leading to mass transport phenomena. The excitation of pulses and the mass transport mechanism are studied in the 10-7 and 10-6 mbar pressure range, with the potassium coverage varying between K = 0.05 and K = 0.12 ML. Using spectroscopic photoemission and spectroscopic low energy electron microscopy (SPELEEM) as well as related microprobe diffraction techniques, we show that the excitation mechanism comprises a cyclic structural transformation: K + O-coadsorbate → (2 × 1)-N → c(2 × 4)-2O,N → K + O coadsorbate. Laterally resolved spectroscopy demonstrates that potassium is accumulated in front of the nitrogen pulses, suggesting that adsorbed nitrogen acts as a diffusion barrier for potassium. © 2013 The Owner Societies

Strain relaxation in small adsorbate islands: O on W(110)

The stress-induced lattice changes in a p(1x2) ordered oxygen layer on W(110) are measured by low-energy electron diffraction. We have observed that small oxygen islands show a mismatch with the underlying lattice. Our results indicate that along [1-10] the average mismatch scales inversely with the island size as 1/L for all oxygen coverages up to 0.5 ML, while along [001] it is significant only for the smallest oxygen islands and scales as a higher power of the inverse island size. The behaviour along [1-10] is described by a one-dimensional finite-size Frenkel-Kontorova model. Using this model, together with calculated force constants, we make a quantitative estimate for the change of surface-stress upon oxygen adsorption. The result is consistent with our ab-initio calculations, which give a relative compressive stress of -4.72 N/m along [1-10] and a minute relative tensile stress of 0.15 N/m along [001]. The scaling along [001] is qualitatively explained as an effect induced by the lattice relaxation in the [1-10] direction.Comment: 22 pages, 5 figure

phase coexistence in two dimensional fe 0 70 ni 0 30 films on w 110

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Stress engineering at the nanometer scale: Two-component adlayer stripes

Spontaneously formed equilibrium nanopatterns with long-range order are widely observed in a variety of systems, but their pronounced temperature dependence remains an impediment to maintain such patterns away from the temperature of formation. Here, we report on a highly ordered stress-induced stripe pattern in a two-component, Pd-O, adsorbate monolayer on W(110), produced at high temperature and identically preserved at lower temperatures. The pattern shows a tunable period (down to 16 nm) and orientation, as predicted by a continuum model theory along with the surface stress and its anisotropy found in our DFT calculations. The control over thermal fluctuations in the stripe formation process is based on the breaking/restoring of ergodicity in a high-density lattice gas with long-range interactions upon turning off/on particle exchange with a heat bath.Comment: 6 pages, 4 figure

Quantitative analysis of shadow X-ray Magnetic Circular Dichroism Photo-Emission Electron Microscopy

Shadow X-ray Magnetic Circular Dichroism Photo-Emission Electron Microscopy (XMCD-PEEM) is a recent technique, in which the photon intensity in the shadow of an object lying on a surface, may be used to gather information about the three-dimensional magnetization texture inside the object. Our purpose here is to lay the basis of a quantitative analysis of this technique. We first discuss the principle and implementation of a method to simulate the contrast expected from an arbitrary micromagnetic state. Text book examples and successful comparison with experiments are then given. Instrumental settings are finally discussed, having an impact on the contrast and spatial resolution : photon energy, microscope extraction voltage and plane of focus, microscope background level, electric-field related distortion of three-dimensional objects, Fresnel diffraction or photon scattering

Chemistry-dependent magnetic properties at the FeNi oxide–metal interface

Fe and Ni compounds and their oxides offer stoichiometry dependent magnetic properties, exploitable for the design of magnetic heterojunctions

Domain-wall depinning assisted by pure spin currents

We study the depinning of domain walls by pure diffusive spin currents in a nonlocal spin valve structure based on two ferromagnetic permalloy elements with copper as the nonmagnetic spin conduit. The injected spin current is absorbed by the second permalloy structure with a domain wall and from the dependence of the wall depinning field on the spin current density we find an efficiency of 6*10^{-14}T/(A/m^2), which is more than an order of magnitude larger than for conventional current induced domain wall motion. Theoretically we reproduce this high efficiency, which arises from the surface torques exerted by the absorbed spin current that lead to efficient depinning.Comment: 11 pages, 3 figures, accepted for publication in Phys. Rev. Let

Surface stress of Ni adlayers on W(110): the critical role of the surface atomic structure

Puzzling trends in surface stress were reported experimentally for Ni/W(110) as a function of Ni coverage. In order to explain this behavior, we have performed a density-functional-theory study of the surface stress and atomic structure of the pseudomorphic and of several different possible 1x7 configurations for this system. For the 1x7 phase, we predict a different, more regular atomic structure than previously proposed based on surface x-ray diffraction. At the same time, we reproduce the unexpected experimental change of surface stress between the pseudomorphic and 1x7 configuration along the crystallographic surface direction which does not undergo density changes. We show that the observed behavior in the surface stress is dominated by the effect of a change in Ni adsorption/coordination sites on the W(110) surface.Comment: 14 pages, 3 figures Published in J. Phys.: Condens. Matter 24 (2012) 13500

Pnictogens Allotropy and Phase Transformation during van der Waals Growth

Pnictogens have multiple allotropic forms resulting from their ns2 np3 valence electronic configuration, making them the only elemental materials to crystallize in layered van der Waals (vdW) and quasi-vdW structures throughout the group. Light group VA elements are found in the layered orthorhombic A17 phase such as black phosphorus, and can transition to the layered rhombohedral A7 phase at high pressure. On the other hand, bulk heavier elements are only stable in the A7 phase. Herein, we demonstrate that these two phases not only co-exist during the vdW growth of antimony on weakly interacting surfaces, but also undertake a spontaneous transformation from the A17 phase to the thermodynamically stable A7 phase. This metastability of the A17 phase is revealed by real-time studies unraveling its thickness-driven transition to the A7 phase and the concomitant evolution of its electronic properties. At a critical thickness of ~4 nm, A17 antimony undergoes a diffusionless shuffle transition from AB to AA stacked alpha-antimonene followed by a gradual relaxation to the A7 bulk-like phase. Furthermore, the electronic structure of this intermediate phase is found to be determined by surface self-passivation and the associated competition between A7- and A17-like bonding in the bulk. These results highlight the critical role of the atomic structure and interfacial interactions in shaping the stability and electronic characteristics of vdW layered materials, thus enabling a new degree of freedom to engineer their properties using scalable processes