Unusual quantum states: nonlocality, entropy, Maxwell's daemon, and fractals

This paper analyses the mathematical properties of some unusual quantum states that are constructed by inserting an impenetrable barrier into a chamber confining a single particle.Comment: 9 Figure

Geometry of PT-symmetric quantum mechanics

Recently, much research has been carried out on Hamiltonians that are not Hermitian but are symmetric under space-time reflection, that is, Hamiltonians that exhibit PT symmetry. Investigations of the Sturm-Liouville eigenvalue problem associated with such Hamiltonians have shown that in many cases the entire energy spectrum is real and positive and that the eigenfunctions form an orthogonal and complete basis. Furthermore, the quantum theories determined by such Hamiltonians have been shown to be consistent in the sense that the probabilities are positive and the dynamical trajectories are unitary. However, the geometrical structures that underlie quantum theories formulated in terms of such Hamiltonians have hitherto not been fully understood. This paper studies in detail the geometric properties of a Hilbert space endowed with a parity structure and analyses the characteristics of a PT-symmetric Hamiltonian and its eigenstates. A canonical relationship between a PT-symmetric operator and a Hermitian operator is established. It is shown that the quadratic form corresponding to the parity operator, in particular, gives rise to a natural partition of the Hilbert space into two halves corresponding to states having positive and negative PT norm. The indefiniteness of the norm can be circumvented by introducing a symmetry operator C that defines a positive definite inner product by means of a CPT conjugation operation.Comment: 22 Page

Faster than Hermitian Quantum Mechanics

Given an initial quantum state |psi_I> and a final quantum state |psi_F> in a Hilbert space, there exist Hamiltonians H under which |psi_I> evolves into |psi_F>. Consider the following quantum brachistochrone problem: Subject to the constraint that the difference between the largest and smallest eigenvalues of H is held fixed, which H achieves this transformation in the least time tau? For Hermitian Hamiltonians tau has a nonzero lower bound. However, among non-Hermitian PT-symmetric Hamiltonians satisfying the same energy constraint, tau can be made arbitrarily small without violating the time-energy uncertainty principle. This is because for such Hamiltonians the path from |psi_I> to |psi_F> can be made short. The mechanism described here is similar to that in general relativity in which the distance between two space-time points can be made small if they are connected by a wormhole. This result may have applications in quantum computing.Comment: 4 page

Robust non-adiabatic molecular dynamics for metals and insulators

We present a new formulation of the correlated electron-ion dynamics (CEID) scheme, which systematically improves Ehrenfest dynamics by including quantum fluctuations around the mean-field atomic trajectories. We show that the method can simulate models of non-adiabatic electronic transitions, and test it against exact integration of the time-dependent Schroedinger equation. Unlike previous formulations of CEID, the accuracy of this scheme depends on a single tunable parameter which sets the level of atomic fluctuations included. The convergence to the exact dynamics by increasing the tunable parameter is demonstrated for a model two level system. This algorithm provides a smooth description of the non-adiabatic electronic transitions which satisfies the kinematic constraints (energy and momentum conservation) and preserves quantum coherence. The applicability of this algorithm to more complex atomic systems is discussed.Comment: 36 pages, 5 figures. Accepted for publication in Journal of Chemical Physic