8 research outputs found
Bi(III)-Catalyzed Intermolecular Reactions of (<i>Z</i>)-Pent-2-en-4-yl Acetates with Ethynylarenes for the Construction of Multisubstituted Fluorene Skeletons through a Cascade Electrophilic Addition/Cycloisomerization Sequence
A BiÂ(III)-catalyzed method for the synthesis of highly
conjugated
aromatic multisubstituted fluorene with (<i>Z</i>)-pent-2-en-4-yl
acetates and ethynylarenes via domino reaction is described. In this
process, the reaction appears to be very general and suitable for
a variety of multisubstituted fluorene
Synthesis of Tetrasubstituted Cyclopentadienes via Palladium-Catalyzed Reaction of (<i>Z</i>)‑2-En-4-yn Acetates and <i>N</i>‑Methyl Indoles
An efficient approach for the synthesis of tetrasubstituted
cyclopentadienes
through Pd-catalyzed reactions of (<i>Z</i>)-2-en-4-yn acetates
with substituted indoles was developed. This methodology has the advantages
of broad scope, simple conditions and easily accessible starting materials
Synthesis of Tetrasubstituted Cyclopentadienes via Palladium-Catalyzed Reaction of (<i>Z</i>)‑2-En-4-yn Acetates and <i>N</i>‑Methyl Indoles
An efficient approach for the synthesis of tetrasubstituted
cyclopentadienes
through Pd-catalyzed reactions of (<i>Z</i>)-2-en-4-yn acetates
with substituted indoles was developed. This methodology has the advantages
of broad scope, simple conditions and easily accessible starting materials
Synthesis of Tetrasubstituted Cyclopentadienes via Palladium-Catalyzed Reaction of (<i>Z</i>)‑2-En-4-yn Acetates and <i>N</i>‑Methyl Indoles
An efficient approach for the synthesis of tetrasubstituted
cyclopentadienes
through Pd-catalyzed reactions of (<i>Z</i>)-2-en-4-yn acetates
with substituted indoles was developed. This methodology has the advantages
of broad scope, simple conditions and easily accessible starting materials
Brønsted Acid Catalyzed and NIS-Promoted Cyclization of Diynones: Selective Synthesis of 4‑Pyrone, 4‑Pyridone, and 3‑Pyrrolone Derivatives
Brønsted
acid catalyzed tandem cyclization was found to be
highly effective for the preparation of a series of polysubstituted
4-pyrones from diynones (yield up to 99%). 4-Pyridone and 3-pyrrolone
derivatives were also selectively synthesized by employing NIS and/or
Brønsted acid. NIS as an electrophilic reagent could promote
these reactions efficiently and rapidly under very mild reaction conditions
Brønsted Acid Catalyzed and NIS-Promoted Cyclization of Diynones: Selective Synthesis of 4‑Pyrone, 4‑Pyridone, and 3‑Pyrrolone Derivatives
Brønsted
acid catalyzed tandem cyclization was found to be
highly effective for the preparation of a series of polysubstituted
4-pyrones from diynones (yield up to 99%). 4-Pyridone and 3-pyrrolone
derivatives were also selectively synthesized by employing NIS and/or
Brønsted acid. NIS as an electrophilic reagent could promote
these reactions efficiently and rapidly under very mild reaction conditions
Brønsted Acid Catalyzed and NIS-Promoted Cyclization of Diynones: Selective Synthesis of 4‑Pyrone, 4‑Pyridone, and 3‑Pyrrolone Derivatives
Brønsted
acid catalyzed tandem cyclization was found to be
highly effective for the preparation of a series of polysubstituted
4-pyrones from diynones (yield up to 99%). 4-Pyridone and 3-pyrrolone
derivatives were also selectively synthesized by employing NIS and/or
Brønsted acid. NIS as an electrophilic reagent could promote
these reactions efficiently and rapidly under very mild reaction conditions
Brønsted Acid Catalyzed and NIS-Promoted Cyclization of Diynones: Selective Synthesis of 4‑Pyrone, 4‑Pyridone, and 3‑Pyrrolone Derivatives
Brønsted
acid catalyzed tandem cyclization was found to be
highly effective for the preparation of a series of polysubstituted
4-pyrones from diynones (yield up to 99%). 4-Pyridone and 3-pyrrolone
derivatives were also selectively synthesized by employing NIS and/or
Brønsted acid. NIS as an electrophilic reagent could promote
these reactions efficiently and rapidly under very mild reaction conditions