26 research outputs found
Correlations in two-component log-gas systems
A systematic study of the properties of particle and charge correlation
functions in the two-dimensional Coulomb gas confined to a one-dimensional
domain is undertaken. Two versions of this system are considered: one in which
the positive and negative charges are constrained to alternate in sign along
the line, and the other where there is no charge ordering constraint. Both
systems undergo a zero-density Kosterlitz-Thouless type transition as the
dimensionless coupling is varied through . In
the charge ordered system we use a perturbation technique to establish an
decay of the two-body correlations in the high temperature limit.
For , the low-fugacity expansion of the asymptotic
charge-charge correlation can be resummed to all orders in the fugacity. The
resummation leads to the Kosterlitz renormalization equations.Comment: 39 pages, 5 figures not included, Latex, to appear J. Stat. Phys.
Shortened version of abstract belo
Metastable liquid-liquid phase transition in a single-component system with only one crystal phase and no density anomaly
We investigate the phase behavior of a single-component system in 3
dimensions with spherically-symmetric, pairwise-additive, soft-core
interactions with an attractive well at a long distance, a repulsive soft-core
shoulder at an intermediate distance, and a hard-core repulsion at a short
distance, similar to potentials used to describe liquid systems such as
colloids, protein solutions, or liquid metals. We showed [Nature {\bf 409}, 692
(2001)] that, even with no evidences of the density anomaly, the phase diagram
has two first-order fluid-fluid phase transitions, one ending in a
gas--low-density liquid (LDL) critical point, and the other in a
gas--high-density liquid (HDL) critical point, with a LDL-HDL phase transition
at low temperatures. Here we use integral equation calculations to explore the
3-parameter space of the soft-core potential and we perform molecular dynamics
simulations in the interesting region of parameters. For the equilibrium phase
diagram we analyze the structure of the crystal phase and find that, within the
considered range of densities, the structure is independent of the density.
Then, we analyze in detail the fluid metastable phases and, by explicit
thermodynamic calculation in the supercooled phase, we show the absence of the
density anomaly. We suggest that this absence is related to the presence of
only one stable crystal structure.Comment: 15 pages, 21 figure