Is the Mott transition relevant to f-electron metals ?

We study how a finite hybridization between a narrow correlated band and a wide conduction band affects the Mott transition. At zero temperature, the hybridization is found to be a relevant perturbation, so that the Mott transition is suppressed by Kondo screening. In contrast, a first-order transition remains at finite temperature, separating a local moment phase and a Kondo- screened phase. The first-order transition line terminates in two critical endpoints. Implications for experiments on f-electron materials such as the Cerium alloy Ce$_{0.8}$La$_{0.1}$Th$_{0.1}$ are discussed.Comment: 5 pages, 3 figure

The origin and significance of euhedral apatite crystals on conodonts

Crystal overgrowth on fossil remains is well-documented in the literature. Attention has specifically focused on bioapatite (i.e., an apatite of biochemical origin regardless of post-mortem changes) configurations, in order to decipher any possible relation to fossilization/diagenesis. This study investigates the Rare Earth Element (REE) and other High-Field-Strength Element (HFSE) composition of euhedral crystals formed on the surface of conodont elements compared with that of crystal-free surfaces. Euhedral crystals are by definition crystals characterized by sharp faces, developing solids that, for apatite, assume the form of hexagonal prisms, reflecting its crystal symmetry. Late Ordovician (Amorphognathus ordovicicus Zone) conodonts from two localities in Sardinia and the Carnic Alps (Italy) are herein investigated. Conodont elements reveal the occurrence of smooth surfaces and surfaces partially covered with euhedral crystals. Since euhedral crystals did not reasonably grow during the organism’s lifetime, the REE and HFSE analysis can provide important insights into the crystal growth process. The experimental results indicated a substantial contribution of diagenetic imprinting for all the analyzed material, although more evident on euhedral crystals that are significantly enriched in middle and, subordinately, in heavy REE with respect to smooth surfaces. The positive correlations between La + Th vs log[ΣREE] and Ce + Th vs log[ΣREE] could support the hypothesis that the neoformed euhedral crystals grew also by depleting the pristine bioapatite of the conodont elements. Nevertheless, the occurrence of two types of apatite cannot be ruled out: euhedral crystals as neoformed products of diagenetic processes and smooth surfaces as remains of the pristine conodont bioapatite after diagenesis

Sobre la formación de los conceptos geométricos y sobre el léxico geométrico

El léxico geométrico está relacionado con un criterio de equivalencia entre figuras -normalmente dado por un grupo de transformación (K1ein) -. Puede haber un conflicto entre el lenguaje ordinario, el léxico geométrico tradicional y el criterio de equivalencia que puede sugerir una situación específica. En este artículo analizamos los resultados de un conjunto de preguntas con el objetivo de descubrir los criterios de equivalencia elegidos por los alumnos de entre 9 y 11 años, y la influencia de su léxico. Hemos observado una influencia considerable de los criterios basados en el grupo de traducciones y en el grupo de homoteties y traducciones. También hemos observado la influencia de ((modelos estándar)) (es decir, figuras que aparecen normalmente en sus libros), y algunas dificultades de conceptualización

To be or not to be a conodont. The controversial story of Pseudooneotodus and Eurytholia

The genus Pseudooneotodus (Drygant, 1974) is a genus of small and conical elements widely distributed from the Middle Ordovician to the Early Devonian throughout the world. Because of its unusual shape, Pseudooneotodus has long been considered enigmatic, and only in the late nineties of the last century the genus has been finally placed within conodonts according to histological data. This study investigates possible similarities between Pseudooneotodus and Eurytholia (Sutton et al., 2001), an incertae sedis genus of enigmatic plates with a phosphate composition. An association of over one hundred specimens of Pseudooneotodus beckmanni and Eurytholia bohemica was analyzed from conodont residues in two distinct geographical areas: the Prague Basin (Požáry and Mušlovka sections, Bohemia, Czech Republic) and the Carnic Alps (Rauchkofel Boden section, Austria). Through an investigation that combines the use of optical and electron microscopy (including focused ion beam scanning electron microscopy), X-ray microdiffraction, and trace element (HFSE) analysis by mass spectrometry, differences between these fossil groups were observed and compared with data resulting from typical conodonts (Dapsilodus obliquicostatus, Panderodus unicostatus and Wurmiella excavata) recovered from the same samples

Development and application of an electrochemical plate coupled with immunomagnetic beads (ELIME) array for salmonella enterica detection in meat samples

Salmonella is one of the main organisms causing outbreaks of foodborne illness, and meat is one of the major vehicles of salmonellosis throughout the world. A novel analytical immunosensor array, based on a 96-well electrochemical plate coupled with immunomagnetic beads (ELIME array), is proposed for the detection of Salmonella in meat samples. After an optimization study, using Salmonella enterica serotype Enteritidis as reference antigen, the ability of the method to interact with a large number of Salmonella serovars commonly present in food was evaluated. The assay was then used to analyze samples of pork, chicken, beef, and turkey experimentally inoculated with Salmonella as well as real samples. The results were compared with those from the International Standard of Organization (ISO) culture method. The comparison showed that the ELIME array is able to detect a low number of Salmonella cells (1-10 CFU per 25 g) after only 6 h of incubation in a pre-enrichment broth. The investigation revealed a very good agreement between culture and ELIME array methods for meat samples, reducing the time for performing the analysis and obtaining the results quickly

How Much Can We Trust Major Element Quantification in Bioapatite Investigation?

Bioapatite is probably the key factor in the unreplicated success of vertebrates. Chemical data on bioapatite composition can be achieved on a solid sample by using different analytical tools such as spectroscopic and spectrometric methods. As analytical outputs can be affected by the physical-chemical characteristics of the sample matrix, an internal standard is usually required to correct and validate the results. Bioapatite lattice can accommodate iso- and heterovalent substitutions during life or diagenesis varying its chemical composition through (geological) time. If on the one hand, this makes bioapatite a unique archive of physical and chemical information for both the living cycle and the events occurring after death, on the other, it excludes the identification of a sole internal standard. Here, we propose a method to measure major element concentration with specific care for P, Ca, Mg, Na, K, Si, Al, and Fe, which are the main substituent atoms in bioapatite, through homemade matrix-matched external calibration standards for laser ablation inductively coupled plasma mass spectrometry (LA-ICPMS). We tested the method on living and fossil shark teeth, critically comparing the results obtained using other analytical techniques and certified external standards. We demonstrated that matrix-matched calibration in LA-ICPMS is mandatory for obtaining a reliable chemical characterization even if factors such as matrix aggregation variability, diverse presence of volatile compounds, the fossilization footprint, and the instrumental variability can represent further variability parameters

SYBR Green Real-Time PCR for Salmonella detection in meat products

The objective of this study was to develop a SYBR Green Real-Time PCR method for detecting salmonellae in meat samples. The study was conducted both on S. Typhimurium experimentally and naturally contaminated meat samples analyzed in parallel with the standard cultural method (ISO 6579/2001). After the pre-enrichment phase, a boiling DNA extraction procedure combined wity SYBR-Green I Real Time PCR, using primers Styinva-JHO-2, was developed