7,266 research outputs found
Complexing additives to reduce the immiscible phase formed in the hybrid ZnBr2 flow battery
The zinc-bromine redox flow battery (RFB) is one of a very few commercially viable RFB energy storage system capable of integration with intermittent renewable energy sources to deliver improved energy management. However, due to the volatility of the electrogenerated bromine and potential for its crossover from positive to negative electrolytes, this system requires the use of quaternary ammonium complexes (N-methyl-N-ethylpyrrolidinium, (MEP)) to capture this bromine. This produces an immiscible phase with the Br2 which requires a complex network of pipes, pumps and automated controls to ensure access to the electroactive material during discharge. In this work, the use of novel quaternary ammonium complexes to capture the electrogenerated bromine but to keep it in the aqueous phase is examined. Three compounds, 1-(carboxymethyl) pyridine-1-ium, 1-(2-carboxymethyl)-1-methylmorpholin-1-ium and 1-(2-carboxymethyl)-1-methylpyrrolidin-1-ium, were found to successfully reduce the volume of the immiscible phase formed on complexing with the polybromide (Brx-) whilst displaying similar enthalpy of vaporisation values as that of MEP. Electrochemical analysis also revealed that these compounds did not impact on the electrode kinetics of the Br-/Brx- reaction indicating that the resulting surface film formed with these compounds behaved as a chemically modified electrode, in contrast to the surface film formed with MEP
Does the mode of delivery affect mathematics examination results?
At present most examinations are delivered on paper but there is a growing trend in many subjects to deliver some or part of these examinations by computer. It is therefore important to know whether there are any differences in the results obtained by candidates sitting examinations taken by computer compared with those obtained by candidates sitting conventional examinations using pen and paper. The purpose of this article is to describe the outcome of a pilot study designed to∗ investigate possible causes of any differences in results from the use of different modes of delivery in a mathematics examination. One outcome of this study was that the process of translating examination questions into a format required for use on the computer (but keeping this as a pen and paper test) can have a significant effect on examination results. However, the main conclusion is that changing the medium only has no effect on the results in mathematics examinations
Assessment of vitamin E status in patients with systemic inflammatory response syndrome: plasma, plasma corrected for lipids or red blood cell measurements?
<b>Background:</b>
There is some evidence that the plasma vitamin E status is perturbed as part of systemic inflammatory response and correcting this with other plasma markers may not lead to reliable results. The aim of the present study was to examine the longitudinal inter-relationships between plasma and red blood cell vitamin α-tocopherol in patients with systemic inflammatory response syndrome.
<b>Methods:</b>
α-tocopherol concentrations were measured, by HPLC, in plasma and red blood cells in normal subjects (n = 67) and in critically ill patients with systemic inflammatory response syndrome (n = 82) on admission and on follow-up.
<b>Results:</b>
Plasma α-tocopherol was significantly lower in the critically ill patients compared with the controls (all p < 0.001) with 41% of patients having concentrations below the 95% confidence interval. In contrast, when corrected for cholesterol, α-tocopherol concentrations were significantly higher in the critically ill patients compared with the control group (p < 0.001, 27% above the 95% confidence interval) and when corrected for triglycerides, α-tocopherol concentrations were significantly lower in the critically ill patients compared with the control group (p < 0.001). Red blood cell α-tocopherol corrected for haemoglobin was similar (p = 0.852) in the critically ill patients compared with control subjects. The longitudinal measurements (n = 53) gave similar results.
<b>Conclusions:</b>
These results indicate that there is a discrepancy between vitamin E measurements in plasma, in plasma corrected for lipids and in red blood cells. Although the value of correcting vitamin E concentrations by lipids is well established in population studies, the present study indicates that such correction is unreliable in the presence of systemic inflammatory response syndrome and that vitamin E status should be assessed using red blood cell α-tocopherol measurement
Automatic Abstraction in SMT-Based Unbounded Software Model Checking
Software model checkers based on under-approximations and SMT solvers are
very successful at verifying safety (i.e. reachability) properties. They
combine two key ideas -- (a) "concreteness": a counterexample in an
under-approximation is a counterexample in the original program as well, and
(b) "generalization": a proof of safety of an under-approximation, produced by
an SMT solver, are generalizable to proofs of safety of the original program.
In this paper, we present a combination of "automatic abstraction" with the
under-approximation-driven framework. We explore two iterative approaches for
obtaining and refining abstractions -- "proof based" and "counterexample based"
-- and show how they can be combined into a unified algorithm. To the best of
our knowledge, this is the first application of Proof-Based Abstraction,
primarily used to verify hardware, to Software Verification. We have
implemented a prototype of the framework using Z3, and evaluate it on many
benchmarks from the Software Verification Competition. We show experimentally
that our combination is quite effective on hard instances.Comment: Extended version of a paper in the proceedings of CAV 201
Finite-Size Scaling of the Domain Wall Entropy Distributions for the 2D Ising Spin Glass
The statistics of domain walls for ground states of the 2D Ising spin glass
with +1 and -1 bonds are studied for square lattices with , and = 0.5, where is the fraction of negative bonds, using periodic
and/or antiperiodic boundary conditions. When is even, almost all domain
walls have energy = 0 or 4. When is odd, most domain walls have
= 2. The probability distribution of the entropy, , is found
to depend strongly on . When , the probability distribution
of is approximately exponential. The variance of this distribution
is proportional to , in agreement with the results of Saul and Kardar. For
the distribution of is not symmetric about zero. In
these cases the variance still appears to be linear in , but the average of
grows faster than . This suggests a one-parameter scaling
form for the -dependence of the distributions of for .Comment: 13 page
On the Use of Finite-Size Scaling to Measure Spin-Glass Exponents
Finite-size scaling (FSS) is a standard technique for measuring scaling
exponents in spin glasses. Here we present a critique of this approach,
emphasizing the need for all length scales to be large compared to microscopic
scales. In particular we show that the replacement, in FSS analyses, of the
correlation length by its asymptotic scaling form can lead to apparently good
scaling collapses with the wrong values of the scaling exponents.Comment: RevTeX, 5 page
Planets in triple star systems--the case of HD188753
We consider the formation of the recently discovered ``hot Jupiter'' planet
orbiting the primary component of the triple star system HD188753. Although the
current outer orbit of the triple is too tight for a Jupiter-like planet to
have formed and migrated to its current location, the binary may have been much
wider in the past. We assume here that the planetary system formed in an open
star cluster, the dynamical evolution of which subsequently led to changes in
the system's orbital parameters and binary configuration. We calculate cross
sections for various scenarios that could have led to the multiple system
currently observed, and conclude that component A of HD188753 with its planet
were most likely formed in isolation to be swapped in a triple star system by a
dynamical encounter in an open star cluster. We estimate that within 500pc of
the Sun there are about 1200 planetary systems which, like Hd188753, have
orbital parameters unfavorable for forming planets but still having a planet,
making it quite possible that the HD188753 system was indeed formed by a
dynamical encounter in an open star cluster.Comment: ApJ Letters in pres
A Survey of Satisfiability Modulo Theory
Satisfiability modulo theory (SMT) consists in testing the satisfiability of
first-order formulas over linear integer or real arithmetic, or other theories.
In this survey, we explain the combination of propositional satisfiability and
decision procedures for conjunctions known as DPLL(T), and the alternative
"natural domain" approaches. We also cover quantifiers, Craig interpolants,
polynomial arithmetic, and how SMT solvers are used in automated software
analysis.Comment: Computer Algebra in Scientific Computing, Sep 2016, Bucharest,
Romania. 201
Statistics of lowest excitations in two dimensional Gaussian spin glasses
A detailed investigation of lowest excitations in two-dimensional Gaussian
spin glasses is presented. We show the existence of a new zero-temperature
exponent lambda describing the relative number of finite-volume excitations
with respect to large-scale ones. This exponent yields the standard thermal
exponent of droplet theory theta through the relation, theta=d(lambda-1). Our
work provides a new way to measure the thermal exponent theta without any
assumption about the procedure to generate typical low-lying excitations. We
find clear evidence that theta < theta_{DW} where theta_{DW} is the thermal
exponent obtained in domain-wall theory showing that MacMillan excitations are
not typical.Comment: 4 pages, 3 figures, (v2) revised version, (v3) corrected typo
Using Flow Specifications of Parameterized Cache Coherence Protocols for Verifying Deadlock Freedom
We consider the problem of verifying deadlock freedom for symmetric cache
coherence protocols. In particular, we focus on a specific form of deadlock
which is useful for the cache coherence protocol domain and consistent with the
internal definition of deadlock in the Murphi model checker: we refer to this
deadlock as a system- wide deadlock (s-deadlock). In s-deadlock, the entire
system gets blocked and is unable to make any transition. Cache coherence
protocols consist of N symmetric cache agents, where N is an unbounded
parameter; thus the verification of s-deadlock freedom is naturally a
parameterized verification problem. Parametrized verification techniques work
by using sound abstractions to reduce the unbounded model to a bounded model.
Efficient abstractions which work well for industrial scale protocols typically
bound the model by replacing the state of most of the agents by an abstract
environment, while keeping just one or two agents as is. However, leveraging
such efficient abstractions becomes a challenge for s-deadlock: a violation of
s-deadlock is a state in which the transitions of all of the unbounded number
of agents cannot occur and so a simple abstraction like the one above will not
preserve this violation. In this work we address this challenge by presenting a
technique which leverages high-level information about the protocols, in the
form of message sequence dia- grams referred to as flows, for constructing
invariants that are collectively stronger than s-deadlock. Efficient
abstractions can be constructed to verify these invariants. We successfully
verify the German and Flash protocols using our technique
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