Pathway Analysis of Contaminant Fate and Transport for Generic Soil Standards and Application to Kentucky Underground Storage Tanks

A generic contaminant migration pathway was used to develop concentration adjustment factors relating soil contamination levels to concentrations in migrating media. These concentration adjustments are based on relatively simple models and parameter values from the literature. The methodology is a screening level tool and is not designed to be used in the site specific analysis where additional information on the source of contamination and the local conditions is available. The results demonstrate that contaminant concentrations can be very sensitive to the processes which occur during the migration of contaminants.Because the rates of these processes may be site specific it is difficult to assign values to many of the parameters required to describe them. The parameter estimates used at the different steps in the analysis are based on the results of a literature investigation and an understanding of the hydrogeology of Kentucky. It is apparent from this study that the multipliers are quite sensitive to parameter values selected, particularly for degradation. The sensitivity of the multipliers reinforces the need to validate these results with monitoring at existing sites. Further research on the anticipated values and conditions will be valuable in refining estimates of contaminant biodegradation for generic standards determination

Evaluation of Solids Generation in Lagoon Treatment Systems: Application to Bardstown, Kentucky

This report summarizes the results of a study which investigated the sludge accumulation in lagoon systems through both literature review and evaluation of the Bardstown wastewater treatment plant. Much of the information in this report has been presented in more detail in the Master\u27s thesis of Jon Keeling (Keeling, 1994)

Kentucky Municipal Wastewater Treatment Plant Sludge Survey

A survey of solids removal from municipal wastewater treatment plants in Kentucky was conducted by the Department of Civil Engineering at the University of Kentucky. The survey was made using both a mailed form and a followed up phone communication through a period from June, 1993 to April, 1994. The results of that survey were compiled using a spreadsheet program and are available on diskette from the authors. The results of the survey are also presented in the eight Tables herein

Kentucky Municipal wastewater Sludge: Generation, Management and Pathogen Reduction

This document was prepared as part of an investigation into sludge quantities and pathogen reduction. It has been written as an introduction and reference for operators, municipal officials, engineers and regulators as they assess their sludge management options

Municipal Wastewater Sludges: Solids Generation and Pathogen Reduction

The qualities of sludge generated and the variations in potential processing technologies for pathogen reduction pose a challenge to those evaluating sludge management. Some of the key factors that should be considered when evaluating sludge management options include: Land requirements Equipment requirements Availability of Required additives Desired product end use The extent to which these factors influence the implementation of a particular processing technology will vary, but in all cases, they will influence the cost and application of any of the technologies

Sorption of Chlorinated Organic Compounds by Sedimentary Rocks

The sorption of dichlorobenzene and trichlorobenzene on carbonate and shale rocks collected in Kentucky demonstrate that rock organic matter content is a good indicator of sorptive reactivity in rock systems. Although this is similar to soil systems, significant differences between sorption in rock and soil systems exist. Sorption isotherms on these rocks are nonlinear and sorption can be an order of magnitude higher than predicted using correlations from soils and their organic matter content. This sorption reaction could lead to significant concentration tailing during contaminant cleanup. Experimental elution of trichloroethylene from rock filled columns verified that cleanup times might be extended due to both sorption and diffusion into rock

Novel Calixarene-Schiff Bases that Bind Silver(I) Ion

Two novel calix[4]arene-Schiff base receptors have been synthesized. One of the new compounds has two pendant aldimines, while the second has been prepared by two-point attachment of a calixarene-dialdehyde onto a calixarene-diamine to form a “calix-tube”. Preliminary binding studies with AgClO4 show large complexation-induced shifts in 1H NMR positions

Sorption phenomena in subsurface systems: Concepts, models and effects on contaminant fate and transport

The behavior, transport and ultimate fate of contaminants in subsurface environments may be affected significantly by their participation in sorption reactions and related phenomena. The degree to which the resulting effects can be quantified and predicted depends upon the extent to which certain fundamental aspects of sorption are understood, and upon the accuracy with which these phenomena can be characterized and modeled in complex subsurface systems. Current levels of understanding of the reactions and processes comprising sorption phenomena are discussed in this paper, as are the forms and utilities of different models used to describe them. Emphasis is placed on concept development, on the translation of these concepts into functional models for characterizing sorption rates and equilibria, and on the application of these concepts and models for explaining contaminant behavior in subsurface systems. Examples are provided to illustrate the impacts of sorption phenomena on contaminant transport.Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/29367/1/0000437.pd

Research Reports From Status Report: Identification of Appropriate Standards for Corrective Action for a Release from Petroleum Underground Storage Tanks

This document is a collection of research reports: Cost of Closure and Remediation for Petroleum Underground Storage Tanks Assessment of Number and Distribution of USTs Analysis of Potable Water Sources in Kentucky Analysis of Well Data and Soil Parameters as Related to the STATSGO Kentucky General Soil Map Petroleum Products: Chemical Composition, Tocxicological and Environmental Data Health Risk Analysis for Selected Petroleum Compounds Summary of Analytical Methods Soil Volume Calculations for UST Installations Generic Organic Containment Pathway Analysis for Components of Petroleum in Soil and Groundwate

Effect of dietary patterns differing in carbohydrate and fat content on blood lipidand glucose profiles based on weight-loss success of breast-cancer survivors

INTRODUCTION: Healthy body weight is an important factor for prevention of breast cancer recurrence. Yet, weight loss and weight gain are not currently included in clinical-practice guidelines for posttreatment of breast cancer. The work reported addresses one of the questions that must be considered in recommending weight loss to patients: does it matter what diet plan is used, a question of particular importance because breast cancer treatment can increase risk for cardiovascular disease. METHODS: Women who completed treatment for breast cancer were enrolled in a nonrandomized, controlled study investigating effects of weight loss achieved by using two dietary patterns at the extremes of macronutrient composition, although both diet arms were equivalent in protein: high fat, low carbohydrate versus low fat, high carbohydrate. A nonintervention group served as the control arm; women were assigned to intervention arms based on dietary preferences. During the 6-month weight-loss program, which was menu and recipe defined, participants had monthly clinical visits at which anthropometric data were collected and fasting blood was obtained for safety monitoring for plasma lipid profiles and fasting glucose. Results from 142 participants are reported. RESULTS: Adverse effects on fasting blood lipids or glucose were not observed in either dietary arm. A decrease in fasting glucose was observed with progressive weight loss and was greater in participants who lost more weight, but the effect was not statistically significant, even though it was observed across both diet groups (P = 0.21). Beneficial effects of weight loss on cholesterol (4.7%; P = 0.001), triglycerides (21.8%; P = 0.01), and low-density lipoprotein (LDL) cholesterol (5.8%; P = 0.06) were observed in both groups. For cholesterol (P = 0.07) and LDL cholesterol (P = 0.13), greater reduction trends were seen on the low-fat diet pattern; whereas, for triglycerides (P = 0.01) and high-density lipoprotein (HDL) cholesterol (P = 0.08), a decrease or increase, respectively, was greater on the low-carbohydrate diet pattern. CONCLUSIONS: Because an individual's dietary preferences can affect dietary adherence and weight-loss success, the lack of evidence of a negative effect of dietary pattern on biomarkers associated with cardiovascular risk is an important consideration in the development of breast cancer practice guidelines for physicians who recommend that their patients lose weight. Whether dietary pattern affects biomarkers that predict long-term survival is a primary question in this ongoing clinical trial