Radiocarbon dating of late Quaternary sediments using fossil gastropod shells

Terrestrial gastropods are one of the most successful groups of organisms on Earth. Their distribution includes all continents except Antarctica, and they occupy exceptionally diverse habitats, from marshes and wet meadows to alpine forests and Arctic tundra. Their shells are also commonly preserved in Quaternary deposits and potentially could be used for 14C dating. However, terrestrial gastropods are known to ingest limestone and incorporate the old carbon in their shells, resulting in apparent ages that are often too old. Recent studies have shown that many small (\u3c1 cm diameter) terrestrial gastropods avoid this “limestone problem” even when living in areas in which carbonate rocks are readily available. However, the shells must also behave as closed systems with respect to carbon if their ages are to be considered reliable. Our latest work has been aimed at testing if small gastropod shells do, in fact, remain closed systems in late Quaternary deposits over a wide array of climate conditions across North America. Our results demonstrate that ages derived from Succineidae shells are identical to wood and charcoal ages in loess in Alaska, glacial deposits in the upper Midwest, loess in the Great Plains, and paleowetlands in the desert southwest. Moreover, Succineidae shell ages routinely fall within permitted limits set by stratigraphic boundaries, require less interpretation than humic acid ages that are commonly used in loess studies, can provide additional stratigraphic coverage to previous dating efforts, and maintain stratigraphic order more often than luminescence ages from the same stratigraphic intervals. Thus, we conclude that fossil Succineidae shells, and shells of a few other small gastropods, can be used for 14C dating regardless of the local lithology, past climate, or environmental conditions

On the importance of stratigraphic control for vertebrate fossil sites in Channel Islands National Park, California, USA: Examples from new Mammuthus finds on San Miguel Island

Quaternary vertebrate fossils, most notably mammoth remains, are relatively common on the northern Channel Islands of California. Well-preserved cranial, dental, and appendicular elements of Mammuthus exilis (pygmy mammoth) and Mammuthus columbi (Columbian mammoth) have been recovered from hundreds of localities on the islands during the past half-century or more. Despite this paleontological wealth, the geologic context of the fossils is described in the published literature only briefly or not at all, which has hampered the interpretation of associated 14C ages and reconstruction of past environmental conditions. We recently discovered a partial tusk, several large bones, and a tooth enamel plate (all likely mammoth) at two sites on the northwest flank of San Miguel Island, California. At both localities, we documented the stratigraphic context of the fossils, described the host sediments in detail, and collected charcoal and terrestrial gastropod shells for radiocarbon dating. The resulting 14C ages indicate that the mammoths were present on San Miguel Island between ~20 and 17 ka as well as between ~14 and 13 ka (thousands of calibrated 14C years before present), similar to other mammoth sites on San Miguel, Santa Cruz, and Santa Rosa Islands. In addition to documenting the geologic context and ages of the fossils, we present a series of protocols for documenting and reporting geologic and stratigraphic information at fossil sites on the California Channel Islands in general, and in Channel Islands National Park in particular, so that pertinent information is collected prior to excavation of vertebrate materials, thus maximizing their scientific value

Holocene loess deposition and soil formation as competing processes, Matanuska Valley, southern Alaska

Although loess–paleosol sequences are among the most important records of Quaternary climate change and past dust deposition cycles, few modern examples of such sedimentation systems have been studied. Stratigraphic studies and 22 new accelerator mass spectrometry radiocarbon ages from the Matanuska Valley in southern Alaska show that loess deposition there began sometime after ~6500 14C yr B.P. and has continued to the present. The silts are produced through grinding by the Matanuska and Knik glaciers, deposited as outwash, entrained by strong winds, and redeposited as loess. Over a downwind distance of ~40 km, loess thickness, sand content, and sand-pluscoarse- silt content decrease, whereas fine-silt content increases. Loess deposition was episodic, as shown by the presence of paleosols, at distances \u3e10 km from the outwash plain loess source. Stratigraphic complexity is at a maximum (i.e., the greatest number of loesses and paleosols) at intermediate (10–25 km) distances from the loess source. Surface soils increase in degree of development with distance downwind from the source, where sedimentation rates are lower. Proximal soils are Entisols or Inceptisols, whereas distal soils are Spodosols. Ratios of mobile CaO, K2O, and Fe2O3 to immobile TiO2 show decreases in surface horizons with distance from the source. Thus, as in China, where loess deposition also takes place today, eolian sedimentation and soil formation are competing processes. Study of loess and paleosols in southern Alaska shows that particle size can vary over short distances, loess deposition can be episodic over limited time intervals, and soils developed in stabilized loess can show considerable variability under the same vegetation

Mineral pigments at Huaca Tacaynamo (Chan Chan, Peru)

X-ray diffraction analyses of five samples of pigments from a recently excavated mural at the archaeological site of Huaca Tacaynamo, a part of the Chan Chan archaeological complex, northern Peru, show that minerals related to metal occurrences known to have been exploited by ancient Andeans were also used as pigments. These minerals include: atacamite [Cu2Cl(OH3)] for green; azurite [Cu3(CO3)2(OH)2] for blue; calcite [CaCO3] for white; cinnabar [HgS] for red; and goethite [HFeO2] for yellow. Woven plant material from Tacaynamo gave a calibrated, 2 sigma 14C date of AD 1412-1614; however, initial occupation of the site and painting of the murals may have been earlier.Los análisis de difracción de rayos x en 5 muestras de pigmentos de un mural, recientemente excavado en el sitio arqueológico de Huaca Tacaynamo —una parte del complejo de Chan Chan en el norte del Perú—, muestran ciertos minerales relacionados con presencias metálicas que, como se sabe, han sido aprovechados por los antiguos habitantes de los Andes, también, como pigmentos. Estos minerales incluyen atacamita [Cu2Cl(OH3)] para el color verde; azurita [Cu3(CO3)2(OH)2] para el azul; calcita [CaCO3] para el blanco; cinabrio [HgS] para el rojo; y goetita [HFeO2] para el amarillo. La datación de los tejidos a partir de materiales vegetales de Tacaynamo con el 14C dio como resultado: AD 1412-1614. Sin embargo, la ocupación inicial del sitio y la pintura de los murales bien podría haber sido previas.Les analyses de diffraction des rayons X sur cinq échantillons de pigments d’une peinture murale récemment découverte sur le site archéologique de Huaca Tacaynamo — qui fait partie du complexe de Chan Chan, au nord du Pérou —, indiquent la présence de minéraux connus pour avoir servi de pigments aux anciens habitants des Andes. Ces minéraux sont l’atacamite [Cu2Cl(OH3)] pour la couleur verte; l’azurite [Cu3(CO3)2(OH)2] pour le bleu; la calcite [CaCO3] pour le blanc; le cinabre [HgS] pour le rouge; et la goethite [HFeO2] pour le jaune. Le matériel tissé d’origine végétale retrouvé à Tacaynamo a donné un calibrage de 2 sigma 14C avec une date de AD 1412-1614; cependant, la première occupation du site et les peintures murales pourraient bien être antérieures

A 1200 Year Record of Hydrologic Variability in the Sierra Nevada from Sediments in Walker Lake, Nevada

Measurements of the oxygen isotopic composition (δ18O) of the total inorganic carbon (TIC) fraction from cored sediments of Walker Lake, Nevada, were conducted at an average resolution of ∼3 years per sample over the last 1200 years. On the basis of radiocarbon analysis on the total organic carbon (TOC) fraction, a δ18O time series was created to reconstruct changes in hydrologic conditions back to AD 800. The timings of variations in the TIC δ18O record are generally consistent with the tree ring-based Sacramento River flow record spanning AD 869 to 1977, indicating that Walker Lake δ18O contains information about past changes in at least regional hydrologic conditions. Comparison with the δ18O record from Pyramid Lake sediments indicates that both basins have recorded five century-scale oscillations in regional hydrologic conditions since AD 800. Several of these changes in hydrologic conditions appear synchronous with century-scale California Current water temperature changes derived from analysis of sediment cores from the Santa Barbara Basin also attesting to the regional extent of these climatic fluctuations. Nearly synchronous oscillations in the Sierra wetness and the California Current suggest that regional changes in atmospheric circulation may have played an important role in century-scale climate variability over the last millennium

Geochemical evidence for seasonal controls on the transportation of Holocene loess, Matanuska Valley, southern Alaska, USA

Loess is a widespread Quaternary deposit in Alaska and loess accretion occurs today in some regions, such as the Matanuska Valley. The source of loess in the Matanuska Valley has been debated for more than seven decades, with the Knik River and the Matanuska River, both to the east, being the leading candidates and the Susitna River, to the west, as a less favorable source. We report here new stratigraphic, mineralogic, and geochemical data that test the competing hypotheses of these river sources. Loess thickness data are consistent with previous studies that show that a source or sources lay to the east, which rules out the Susitna River as a source. Knik and Matanuska River silts can be distinguished using Sc–Th–La, LaN/YbN vs. Eu/Eu*, Cr/Sc, and As/Sb. Matanuska Valley loess falls clearly within the range of values for these ratios found in Matanuska River silt. Dust storms from the Matanuska River are most common in autumn, when river discharge is at a minimum and silt-rich point bars are exposed, wind speed from the north is beginning to increase after a low-velocity period in summer, snow depth is still minimal, and soil temperatures are still above freezing. Thus, seasonal changes in climate and hydrology emerge as critical factors in the timing of aeolian silt transport in southern Alaska. These findings could be applicable to understanding seasonal controls on Pleistocene loess accretion in Europe, New Zealand, South America, and elsewhere in North America

Late Holocene Lake-Level Fluctuations in Walker Lake, Nevada, USA

alker Lake, a hydrologically closed, saline, and alkaline lake, is situated along the western margin of the Great Basin in Nevada of the western United States. Analyses of the magnetic susceptibility (χ), total inorganic carbon (TIC), and oxygen isotopic composition (δ18O) of carbonate sediments including ostracode shells (Limnocythere ceriotuberosa) from Walker Lake allow us to extend the sediment record of lake-level fluctuations back to 2700 years B.P. There are approximately five major stages over the course of the late Holocene hydrologic evolution in Walker Lake: an early lowstand (\u3e 2400 years B.P.), a lake-filling period (∼ 2400 to ∼ 1000 years B.P.), a lake-level lowering period during the Medieval Warm Period (MWP) (∼ 1000 to ∼ 600 years B.P.), a relatively wet period (∼ 600 to ∼ 100 years B.P.), and the anthropogenically induced lake-level lowering period (\u3c 100 years B.P.). The most pronounced lowstand of Walker Lake occurred at ∼ 2400 years B.P., as indicated by the relatively high values of δ18O. This is generally in agreement with the previous lower resolution paleoclimate results from Walker Lake, but contrasts with the sediment records from adjacent Pyramid Lake and Siesta Lake. The pronounced lowstand suggests that the Walker River that fills Walker Lake may have partially diverted into the Carson Sink through the Adrian paleochannel between 2700 to 1400 years B.P

Radiocarbon dating loess deposits in the Mississippi Valley using terrestrial gastropod shells (Polygyridae, Helicinidae, and Discidae)

Small terrestrial gastropod shells (mainly Succineidae) have been used successfully to date late Quaternary loess deposits in Alaska and the Great Plains. However, Succineidae shells are less common in loess deposits in the Mississippi Valley compared to those of the Polygyridae, Helicinidae, and Discidae families. In this study, we conducted several tests to determine whether shells of these gastropods could provide reliable ages for loess deposits in the Mississippi Valley. Our results show that most of the taxa that we investigated incorporate small amounts (1–5%) of old carbon from limestone in their shells, meaning that they should yield ages that are accurate to within a few hundred years. In contrast, shells of the genus Mesodon (Mesodon elevatus and Mesodon zaletus) contain significant and variable amounts of old carbon, yielding ages that are up to a couple thousand 14C years too old. Although terrestrial gastropod shells have tremendous potential for 14C dating loess deposits throughout North America,weacknowledge that accuracy to within a few hundred years may not be sufficient for those interested in developing high-resolution loess chronologies. Even with this limitation, however, 14C dating of terrestrial gastropod shells present in Mississippi Valley loess deposits may prove useful for researchers interested in processes that took place over multi-millennial timescales or in differentiating stratigraphic units that have significantly different ages but similar physical and geochemical properties. The results presented here may also be useful to researchers studying loess deposits outside North America that contain similar gastropod taxa