848 research outputs found

    Metal-polymer functionally graded materials for removing guided wave reflections at beam end boundaries

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    This paper investigates the potential of a metal-polymer functionally graded material (FGM) to remove beam end boundary wave reflections that produce complicated interference patterns in the response signals used for guided wave damage identification methodologies. The metal-polymer FGM matches the material properties to a metal beam for total wave transmission on one side and is continuously graded to a viscoelastic polymer on the other side. An Aluminium-Polycarbonate (Al-PC) FGM was fabricated and characterised using microscopy, hardness testing and through-transmission ultrasonics to verify the continuous gradient. Measurements of guided waves on an aluminium beam attached to the FGM on one end show reduction in boundary wave reflections that varies with wave frequency. A damaged aluminium beam attached with the FGM produced promising improvements in a damage identification system

    Variability of postnatal ossification timing and evidence for a “dosage” effect

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    Although absolute variability in postnatal ossification timing is generally larger in boys than in girls, relative, conception-corrected variability is significantly larger in girls, suggestive of a “dosage” effect and consistent with the hypothesis of partial X-linkage. These findings, together with the excess of sister-sister over brother-brother timing similarities are inconsistent with the hypothesis of selective inactivation of either the paternal or the maternal X chromosome.Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/37498/1/1330320116_ftp.pd

    Relationship of skinfolds and muscle size to growth of children. I. Costa Rica

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    The relationships between triceps skinfolds and stature and between upper arm muscle size and stature were studied on 874 pairs matched for age derived from a cross-sectional sample of 2,445 Costa Rican rural subjects, aged 0 to 20 years. The results indicate that fatter children for their age, on the average, are not taller than their leaner counterparts. On the other hand, more muscular children, on the average, are taller than their less muscular counterparts of the same age.Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/37511/1/1330350110_ftp.pd

    Quality Improvement in Hospitals: Identifying and Understanding Behaviors

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    Improving operational performance in hospitals is complicated, particularly if process improvement requires complex behavioral changes. Using single-loop and double-loop learning theory as a foundation, the purpose of this research is to empirically uncover key improvement behaviors and the factors that may be associated with such behaviors in hospitals. A two-phased approach was taken to collect data regarding improvement behaviors and associated factors, and data analysis was conducted using methods proposed by grounded theorists. The contributions of this research are twofold. First, five key behaviors related to process improvement are identified, namely Quick Fixing, Initiating, Conforming, Expediting, and Enhancing. Second, based on these observed behaviors, a set of force field diagrams is developed to structure and organize possible factors that are important to consider when attempting to change improvement behaviors. This begins to fill the gap in the knowledge about what factors drive effective improvement efforts in hospital settings

    Quality Improvement in Hospitals: Identifying and Understanding Behaviors

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    ABSTRACT Improving operational performance in hospitals is complicated, particularly if process improvement requires complex behavioral changes. Using single-loop and double-loop learning theory as a foundation, the purpose of this research is to empirically uncover key improvement behaviors and the factors that may be associated with such behaviors in hospitals. A two-phased approach was taken to collect data regarding improvement behaviors and associated factors, and data analysis was conducted using methods proposed by grounded theorists. The contributions of this research are twofold. First, five key behaviors related to process improvement are identified, namely Quick Fixing, Initiating, Conforming, Expediting, and Enhancing. Second, based on these observed behaviors, a set of force field diagrams is developed to structure and organize possible factors that are important to consider when attempting to change improvement behaviors. This begins to fill the gap in the knowledge about what factors drive effective improvement efforts in hospital settings

    Raman Optical Activity Using Twisted Photons

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    Raman optical activity underpins a powerful vibrational spectroscopic technique for obtaining detailed structural information about chiral molecular species. The effect centers on the discriminatory interplay between the handedness of material chirality with that of circularly polarized light. Twisted light possessing an optical orbital angular momentum carries helical phase fronts that screw either clockwise or anticlockwise and, thus, possess a handedness that is completely distinct from the polarization. Here a novel form of Raman optical activity that is sensitive to the handedness of the incident twisted photons through a spin-orbit interaction of light is identified, representing a new chiroptical spectroscopic technique

    A new view of electrochemistry at highly oriented pyrolytic graphite

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    Major new insights on electrochemical processes at graphite electrodes are reported, following extensive investigations of two of the most studied redox couples, Fe(CN)64–/3– and Ru(NH3)63+/2+. Experiments have been carried out on five different grades of highly oriented pyrolytic graphite (HOPG) that vary in step-edge height and surface coverage. Significantly, the same electrochemical characteristic is observed on all surfaces, independent of surface quality: initial cyclic voltammetry (CV) is close to reversible on freshly cleaved surfaces (>400 measurements for Fe(CN)64–/3– and >100 for Ru(NH3)63+/2+), in marked contrast to previous studies that have found very slow electron transfer (ET) kinetics, with an interpretation that ET only occurs at step edges. Significantly, high spatial resolution electrochemical imaging with scanning electrochemical cell microscopy, on the highest quality mechanically cleaved HOPG, demonstrates definitively that the pristine basal surface supports fast ET, and that ET is not confined to step edges. However, the history of the HOPG surface strongly influences the electrochemical behavior. Thus, Fe(CN)64–/3– shows markedly diminished ET kinetics with either extended exposure of the HOPG surface to the ambient environment or repeated CV measurements. In situ atomic force microscopy (AFM) reveals that the deterioration in apparent ET kinetics is coupled with the deposition of material on the HOPG electrode, while conducting-AFM highlights that, after cleaving, the local surface conductivity of HOPG deteriorates significantly with time. These observations and new insights are not only important for graphite, but have significant implications for electrochemistry at related carbon materials such as graphene and carbon nanotubes
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