3,622 research outputs found
The role of water in slip casting
Slips and casting are considered in terms of physical and colloidal chemistry. Casting slips are polydisperse suspensions of lyophobic particles in water, whose degree of coagulation is controlled by interaction of flocculating and deflocculating agents. Slip casting rate and viscosity are functions of temperature. Slip rheology and response to deflocculating agents varies significantly as the kinds and amounts of colloid modifiers change. Water is considered as a raw material. Various concepts of water/clay interactions and structures are discussed. Casting is a de-watering operation in which water moves from slip to cast to mold in response to a potential energy termed moisture stress. Drying is an evaporative process from a free water surface
Water turbidity detection using ERTS-1 imagery
ERTS-1 images of two federal reservoirs in Kansas exhibit good correlation with suspended load. The major reservoirs in Kansas, as well as in other Great Plains states, are playing increasingly important roles in flood control, recreation, agriculture, and urban water supply. Satellite imagery may prove useful for acquiring timely low cost water quality data required for optimum management of these fresh water resources
Statistical Mechanics of Quantum-Classical Systems with Holonomic Constraints
The statistical mechanics of quantum-classical systems with holonomic
constraints is formulated rigorously by unifying the classical Dirac bracket
and the quantum-classical bracket in matrix form.
The resulting Dirac quantum-classical theory, which conserves the holonomic
constraints exactly, is then used to formulate time evolution and statistical
mechanics. The correct momentum-jump approximation for constrained system
arises naturally from this formalism. Finally, in analogy with what was found
in the classical case, it is shown that the rigorous linear response function
of constrained quantum-classical systems contains non-trivial additional terms
which are absent in the response of unconstrained systems.Comment: Submitted to Journal of Chemical Physic
Structural anisotropy and orientation-induced Casimir repulsion in fluids
In this work we theoretically consider the Casimir force between two periodic
arrays of nanowires (both in vacuum, and on a substrate separated by a fluid)
at separations comparable to the period. Specifically, we compute the
dependence of the exact Casimir force between the arrays under both lateral
translations and rotations. Although typically the force between such
structures is well-characterized by the Proximity Force Approximation (PFA), we
find that in the present case the microstructure modulates the force in a way
qualitatively inconsistent with PFA. We find instead that effective-medium
theory, in which the slabs are treated as homogeneous, anisotropic dielectrics,
gives a surprisingly accurate picture of the force, down to separations of half
the period. This includes a situation for identical, fluid-separated slabs in
which the exact force changes sign with the orientation of the wire arrays,
whereas PFA predicts attraction. We discuss the possibility of detecting these
effects in experiments, concluding that this effect is strong enough to make
detection possible in the near future.Comment: 12 pages, 9, figure. Published version with expanded discussio
Structural anisotropy and orientation-induced Casimir repulsion in fluids
In this work we theoretically consider the Casimir force between two periodic
arrays of nanowires (both in vacuum, and on a substrate separated by a fluid)
at separations comparable to the period. Specifically, we compute the
dependence of the exact Casimir force between the arrays under both lateral
translations and rotations. Although typically the force between such
structures is well-characterized by the Proximity Force Approximation (PFA), we
find that in the present case the microstructure modulates the force in a way
qualitatively inconsistent with PFA. We find instead that effective-medium
theory, in which the slabs are treated as homogeneous, anisotropic dielectrics,
gives a surprisingly accurate picture of the force, down to separations of half
the period. This includes a situation for identical, fluid-separated slabs in
which the exact force changes sign with the orientation of the wire arrays,
whereas PFA predicts attraction. We discuss the possibility of detecting these
effects in experiments, concluding that this effect is strong enough to make
detection possible in the near future.Comment: 12 pages, 9, figure. Published version with expanded discussio
Variability in H9N2 haemagglutinin receptor-binding preference and the pH of fusion
H9N2 avian influenza viruses are primarily a disease of poultry; however, they occasionally infect humans and are considered a potential pandemic threat. Little work has been performed to assess the intrinsic biochemical properties related to zoonotic potential of H9N2 viruses. The objective of this study, therefore, was to investigate H9N2 haemagglutinins (HAs) using two well-known correlates for human adaption: receptor-binding avidity and pH of fusion. Receptor binding was characterized using bio-layer interferometry to measure virus binding to human and avian-like receptor analogues and the pH of fusion was assayed by syncytium formation in virus-infected cells at different pHs. We characterized contemporary H9N2 viruses of the zoonotic G1 lineage, as well as representative viruses of the zoonotic BJ94 lineage. We found that most contemporary H9N2 viruses show a preference for sulphated avian-like receptor analogues. However, the ‘Eastern’ G1 H9N2 viruses displayed a consistent preference in binding to a human-like receptor analogue. We demonstrate that the presence of leucine at position 226 of the HA receptor-binding site correlated poorly with the ability to bind a human-like sialic acid receptor. H9N2 HAs also display variability in their pH of fusion, ranging between pH 5.4 and 5.85 which is similar to that of the first wave of human H1N1pdm09 viruses but lower than the pH of fusion seen in zoonotic H5N1 and H7N9 viruses. Our results suggest possible molecular mechanisms that may underlie the relatively high prevalence of human zoonotic infection by particular H9N2 virus lineages
- …