3,913 research outputs found
Viscosity and thermal conductivity coefficients of gaseous and liquid oxygen
Equations and tables are presented for the viscosity and thermal conductivity coefficients of gaseous and liquid oxygen at temperatures between 80 K and 400 K for pressures up to 200 atm. and at temperatures between 80 K and 2000 K for the dilute gas. A description of the anomalous behavior of the thermal conductivity in the critical region is included. The tabulated coefficients are reliable to within about 15% except for a region in the immediate vicinity of the critical point. Some possibilities for future improvements of this reliability are discussed
Characterization of Iridium Coated Rhenium Used in High-Temperature, Radiation-Cooled Rocket Thrusters
Materials used for radiation-cooled rocket thrusters must be capable of surviving under extreme conditions of high-temperatures and oxidizing environments. While combustion efficiency is optimized at high temperatures, many refractory metals are unsuitable for thruster applications due to rapid material loss from the formation of volatile oxides. This process occurs during thruster operation by reaction of the combustion products with the material surface. Aerojet Technical Systems has developed a thruster cone chamber constructed of Re coated with Ir on the inside surface where exposure to the rocket exhaust occurs. Re maintains its structural integrity at high temperature and the Ir coating is applied as an oxidation barrier. Ir also forms volatile oxide species (IrO2 and IrO3) but at a considerably slower rate than Re. In order to understand the performance limits of Ir-coated Re thrusters, we are investigating the interdiffusion and oxidation kinetics of Ir/Re. The formation of iridium and rhenium oxides has been monitored in situ by Raman spectroscopy during high temperature exposure to oxygen. For pure Ir, the growth of oxide films as thin as approximately 200 A could be easily detected and the formation of IrO2 was observed at temperatures as low as 600 C. Ir/Re diffusion test specimens were prepared by magnetron sputtering of Ir on Re substrates. Concentration profiles were determined by sputter Auger depth profiles of the heat treated specimens. Significant interdiffusion was observed at temperatures as low as 1000 C. Measurements of the activation energy suggest that below 1350 C, the dominant diffusion path is along defects, most likely grain boundaries, rather than bulk diffusion through the grains. The phases that form during interdiffusion have been examined by x ray diffraction. Analysis of heated test specimens indicates that the Ir-Re reaction produces a solid solution phase of Ir dissolved in the HCP structure of Re
Analytical Rescaling of Polymer Dynamics from Mesoscale Simulations
We present a theoretical approach to scale the artificially fast dynamics of
simulated coarse-grained polymer liquids down to its realistic value. As
coarse-graining affects entropy and dissipation, two factors enter the
rescaling: inclusion of intramolecular vibrational degrees of freedom, and
rescaling of the friction coefficient. Because our approach is analytical, it
is general and transferable. Translational and rotational diffusion of
unentangled and entangled polyethylene melts, predicted from mesoscale
simulations of coarse-grained polymer melts using our rescaling procedure, are
in quantitative agreement with united atom simulations and with experiments.Comment: 6 pages, 2 figures, 2 table
Origin of the Mosaicity in Graphene Grown on Cu(111)
We use low-energy electron microscopy to investigate how graphene grows on
Cu(111). Graphene islands first nucleate at substrate defects such as step
bunches and impurities. A considerable fraction of these islands can be
rotationally misaligned with the substrate, generating grain boundaries upon
interisland impingement. New rotational boundaries are also generated as
graphene grows across substrate step bunches. Thus, rougher substrates lead to
higher degrees of mosaicity than do flatter substrates. Increasing the growth
temperature improves crystallographic alignment. We demonstrate that graphene
growth on Cu(111) is surface diffusion limited by comparing simulations of the
time evolution of island shapes with experiments. Islands are dendritic with
distinct lobes, but unlike the polycrystalline, four-lobed islands observed on
(100)-textured Cu foils, each island can be a single crystal. Thus, epitaxial
graphene on smooth, clean Cu(111) has fewer structural defects than it does on
Cu(100).Comment: Article revised following reviewer comment
Multiscale Modeling of Binary Polymer Mixtures: Scale Bridging in the Athermal and Thermal Regime
Obtaining a rigorous and reliable method for linking computer simulations of
polymer blends and composites at different length scales of interest is a
highly desirable goal in soft matter physics. In this paper a multiscale
modeling procedure is presented for the efficient calculation of the static
structural properties of binary homopolymer blends. The procedure combines
computer simulations of polymer chains on two different length scales, using a
united atom representation for the finer structure and a highly coarse-grained
approach on the meso-scale, where chains are represented as soft colloidal
particles interacting through an effective potential. A method for combining
the structural information by inverse mapping is discussed, allowing for the
efficient calculation of partial correlation functions, which are compared with
results from full united atom simulations. The structure of several polymer
mixtures is obtained in an efficient manner for several mixtures in the
homogeneous region of the phase diagram. The method is then extended to
incorporate thermal fluctuations through an effective chi parameter. Since the
approach is analytical, it is fully transferable to numerous systems.Comment: in press, 13 pages, 7 figures, 6 table
How Polarized Have We Become? A Multimodal Classification of Trump Followers and Clinton Followers
Polarization in American politics has been extensively documented and
analyzed for decades, and the phenomenon became all the more apparent during
the 2016 presidential election, where Trump and Clinton depicted two radically
different pictures of America. Inspired by this gaping polarization and the
extensive utilization of Twitter during the 2016 presidential campaign, in this
paper we take the first step in measuring polarization in social media and we
attempt to predict individuals' Twitter following behavior through analyzing
ones' everyday tweets, profile images and posted pictures. As such, we treat
polarization as a classification problem and study to what extent Trump
followers and Clinton followers on Twitter can be distinguished, which in turn
serves as a metric of polarization in general. We apply LSTM to processing
tweet features and we extract visual features using the VGG neural network.
Integrating these two sets of features boosts the overall performance. We are
able to achieve an accuracy of 69%, suggesting that the high degree of
polarization recorded in the literature has started to manifest itself in
social media as well.Comment: 16 pages, SocInfo 2017, 9th International Conference on Social
Informatic
Mathematical and computer modeling of electro-optic systems using a generic modeling approach
The conventional approach to modelling electro-optic sensor systems is to develop separate models for individual systems or classes of system, depending on the detector technology employed in the sensor and the application. However, this ignores commonality in design and in components of these systems. A generic approach is presented for modelling a variety of sensor systems operating in the infrared waveband that also allows systems to be modelled with different levels of detail and at different stages of the product lifecycle. The provision of different model types (parametric and image-flow descriptions) within the generic framework can allow valuable insights to be gained
Flow Conductance of a Single Nanohole
The mass flow conductance of single nanoholes with diameter ranging from 75
to 100 nm was measured using mass spectrometry. For all nanoholes, a smooth
crossover is observed between single-particle statistical flow (effusion) and
the collective viscous flow emanating from the formation of a continuum. This
crossover is shown to occur when the gas mean free path matches the size of the
nanohole diameter. As a consequence of the pinhole geometry, the breakdown of
the Poiseuille approximation is observed in the power-law temperature exponent
of the measured conductance
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