Degradation and reuse of radiative thermal protection system materials for the space shuttle

Three silicide coated columbium alloys and two cobalt alloys were subjected to identical simulated reentry profiling exposures in both static (controlled vacuum leak) and dynamic (hypersonic plasma shear) environments. Primary emphasis in the columbium alloy evaluation was on the Cb752 and C129Y alloys with a lesser amount on FS85. Commercial silicide coatings of the R512E and VH109 formulations were used. The coated specimens were intentionally defected to provide the types of coating flaws that are expected in service. Temperatures were profiled up to peak temperatures of either 2350 F or 2500 F for 15 minutes in each cycle

DEVELOPMENT OF CORROSION-RESISTANT NIOBIUM-BASE ALLOYS

The hot-water corrosion resistance and mechanical properties of niobium and a number of its alloys were evaluated relative to their usefulness in pressurized-water thermal reactors. Unalloyed niobium was found to be rapidly attacked by 600 and 680 deg F water and 750 F steam. A number of alloying additions were found which markedly improve the corrosion resistance of niobium. Of these, binary and ternary combinations of chromium, molybdenum, titanium, vanadium, and zirconium were among the most effective. Many of these alloys exhibited as low or lower weight gains than those obtained for Zircaloy-2 under similar test conditions. Most of the niobium-base alloys tested for strength exhibited excellent resistance to creep at temperatures up to 1200 deg F under stresses through 20,000 psi. (auth

Reaction Between Nitrogen and Spinel in Chromium

Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/66029/1/j.1151-2916.1968.tb15671.x.pd

Development of Corrosion-Resistant Niobium-Base Alloys

The hot-water corrosion resistance and mechanical properties of niobium and a number of its alloys were evaluated relative to their usefulness in pressurized-water thermal reactors. Unalloyed niobium was found to be rapidly attacked by 600 and 680 deg F water and 750 F steam. A number of alloying additions were found which markedly improve the corrosion resistance of niobium. Of these, binary and ternary combinations of chromium, molybdenum, titanium, vanadium, and zirconium were among the most effective. Many of these alloys exhibited as low or lower weight gains than those obtained for Zircaloy-2 under similar test conditions. Most of the niobium-base alloys tested for strength exhibited excellent resistance to creep at temperatures up to 1200 deg F under stresses through 20,000 psi. (auth

Compositional factors affecting corrosion resistance of zirconium in high-temperature water and steam /

"Navy Department, Bureau of Ships, Contract No. NObs-65057, Index No. NS-200-023.""Metallurgy and Ceramics ; (TID-4500, 10th Ed.).""November 18, 1955.""Report No. BMI-1056."Includes bibliographical references (p. 89).Mode of access: Internet

Development of corrosion-resistant niobium-base alloys /

"Contract No. W-7405-eng-92.""UC-25 Metallurgy and Ceramics (TID-4500, 15th Ed.).""May 12, 1960.""Report No. BMI-1437."Includes bibliographical references (p. 89).Work performed by the Battelle Memorial InstituteMode of access: Internet