The Insect Growth Regulator, Triflumuron (Oms-2015) Against Aedes Aegypti in Jakarta, Indonesia

Uji laboratorium dan lapangan dengan IGR Triflumuron (OMS-2015) terhadap larva nyamuk Aedes aegypti telah dilakukan di Jakarta. Uji laboratorium dilakukan dengan 6 variasi dosis, yaitu 0,004; 0,011; 0,034; 0,10; 0,33 dan 1,0 ppm Triflumuron terhadap perkembangan larva nyamuk Ae. aegypti di dalam tempayan. Dari uji laboratorium dapat diketahui bahwa Triflumuron dengan dosis 0,004 ppm dapat menekan perkembangan pupa untuk menjadi dewasa dalam waktu 2 minggu, sedangkan dosis 0,10 ppm menekan padat populasi nyamuk Ae. aegypti selama 4 minggu dan dosis 1,0 ppm menekan padat populasi nyamuk Ae. aegypti selama 8 minggu. Uji lapangan dengan menggunakan Triflumuron di daerah pelabuhan Tanjung Priok, Jakarta, seluas 27 hektar dengan dua kali perlakuan, dengan dosis 0,042 dan 0,075 ppm, terjadi penurunan populasi nyamuk Ae. aegypti dewasa dan indeks pupa menjadi 0 dalam 4 hari setelah perlakuan. Penurunan populasi nyamuk Ae. aegypti dewasa terlihat setelah 2 minggu se­sudah perlakuan dengan tidak berhasilnya larva/pupa menjadi nyamuk dewasa

Particle separation by phase modulated surface acoustic waves

High efficiency isolation of cells or particles from a heterogeneous mixture is a critical processing step in lab-on-a-chip devices. Acoustic techniques offer contactless and label-free manipulation, preserve viability of biological cells, and provide versatility as the applied electrical signal can be adapted to various scenarios. Conventional acoustic separation methods use time-of-flight and achieve separation up to distances of quarter wavelength with limited separation power due to slow gradients in the force. The method proposed here allows separation by half of the wavelength and can be extended by repeating the modulation pattern and can ensure maximum force acting on the particles. In this work, we propose an optimised phase modulation scheme for particle separation in a surface acoustic wave microfluidic device. An expression for the acoustic radiation force arising from the interaction between acoustic waves in the fluid was derived. We demonstrated, for the first time, that the expression of the acoustic radiation force differs in surface acoustic wave and bulk devices, due to the presence of a geometric scaling factor. Two phase modulation schemes are investigated theoretically and experimentally. Theoretical findings were experimentally validated for different mixtures of polystyrene particles confirming that the method offers high selectivity. A Monte-Carlo simulation enabled us to assess performance in real situations, including the effects of particle size variation and non-uniform acoustic field on sorting efficiency and purity, validating the ability to separate particles with high purity and high resolution

Theoretical Framework of Radiation Force in Surface Acoustic Waves for Modulated Particle Sorting

Sorting specific target entities from sample mixtures is commonly used in many macroscale laboratory processing, such as disease diagnosis or treatment. Downscaling of sorting systems enables less laboratory space and fewer quantities of sample and reagent. Such lab-on-a-chip devices can perform separation functions using passive or active sorting methods. Such a method, acoustic sorting, when used in microfluidics, offers contactless, label-free, non-invasive manipulation of target cells or particles and is therefore the topic of active current research. Our phase-modulated sorting technique complements traditional time-of-flight techniques and offers higher sensitivity separation using a periodic signal. By cycling of this periodic signal, the target entities are gradually displaced compared to the background debris, thereby achieving sorting. In this paper, we extend the knowledge on phase-modulated sorting techniques. Firstly, using numerical simulations, we confirm the sorting role of our proposed primary acoustic radiation force within surface wave devices. Secondly, a threefold agreement between analytical, numerical and experimental sorting trajectories is presented

Tracing the Mass during Low-Mass Star Formation. III. Models of the Submillimeter Dust Continuum Emission from Class 0 Protostars

Seven Class 0 sources mapped with SCUBA at 850 and 450 micron are modeled using a one dimensional radiative transfer code. The modeling takes into account heating from an internal protostar, heating from the ISRF, realistic beam effects, and chopping to model the normalized intensity profile and spectral energy distribution. Power law density models, n(r) ~ r^{-p}, fit all of the sources; best fit values are mostly p = 1.8 +/- 0.1, but two sources with aspherical emission contours have lower values (p ~ 1.1). Including all sources, = 1.63 +/- 0.33. Based on studies of the sensitivity of the best-fit p to variations in other input parameters, uncertainties in p for an envelope model are \Delta p = +/- 0.2. If an unresolved source (e.g., a disk) contributes 70% of the flux at the peak, p is lowered in this extreme case and \Delta p = ^{+0.2}_{-0.6}. The models allow a determination of the internal luminosity ( = 4.0 \lsun) of the central protostar as well as a characteristic dust temperature for mass determination ( = 13.8 +/- 2.4 K). We find that heating from the ISRF strongly affects the shape of the dust temperature profile and the normalized intensity profile, but does not contribute strongly to the overall bolometric luminosity of Class 0 sources. There is little evidence for variation in the dust opacity as a function of distance from the central source. The data are well-fitted by dust opacities for coagulated dust grains with ice mantles (Ossenkopf & Henning 1994). The density profile from an inside-out collapse model (Shu 1977) does not fit the data well, unless the infall radius is set so small as to make the density nearly a power-law.Comment: Accepted to ApJ. 28 pages, 13 figures, uses emulateapj5.st

Carbon Nitrogen, and Oxygen Galactic Gradients: A Solution to the Carbon Enrichment Problem

Eleven models of Galactic chemical evolution, differing in the carbon, nitrogen,and oxygen yields adopted, have been computed to reproduce the Galactic O/H values obtained from H II regions. All the models fit the oxygen gradient, but only two models fit also the carbon gradient, those based on carbon yields that increase with metallicity due to stellar winds in massive stars (MS) and decrease with metallicity due to stellar winds in low and intermediate mass stars (LIMS). The successful models also fit the C/O versus O/H evolution history of the solar vicinity obtained from stellar observations. We also compare the present day N/H gradient and the N/O versus O/H and the C/Fe, N/Fe, O/Fe versus Fe/H evolution histories of the solar vicinity predicted by our two best models with those derived from H II regions and from stellar observations. While our two best models fit the C/H and O/H gradients as well as the C/O versus O/H history, only Model 1 fits well the N/H gradient and the N/O values for metal poor stars but fails to fit the N/H values for metal rich stars. Therefore we conclude that our two best models solve the C enrichment problem, but that further work needs to be done on the N enrichment problem. By adding the C and O production since the Sun was formed predicted by Models 1 and 2 to the observed solar values we find an excellent agreement with the O/H and C/H values of the solar vicinity derived from H II regions O and C recombination lines. One of the most important results of this paper is that the fraction of carbon due to MS and LIMS in the interstellar medium is strongly dependent on time and on the galactocentric distance; at present about half of the carbon in the interstellar medium of the solar vicinity has been produced by MS and half by LIMS.Comment: 34 pages, 6 tables, 7 figures. Accepted for publication in Ap

How chemistry controls electron localization in 3d1 perovskites: A Wannier-function study

In the series of 3d1 t2g perovskites, SrVO3--CaVO3--LaTiO3--YTiO3 the transition-metal d electron becomes increasingly localized and undergoes a Mott transition between CaVO3 and LaTiO3. By defining a low-energy Hubbard Hamiltonian in the basis of Wannier functions for the t2g LDA band and solving it in the single-site DMFT approximation, it was recently shown[1] that simultaneously with the Mott transition there occurs a strong suppression of orbital fluctuations due to splitting of the t2g levels. The present paper reviews and expands this work, in particular in the direction of exposing the underlying chemical mechanisms by means of ab initio LDA Wannier functions generated with the NMTO method. The Wannier functions for the t2g band exhibit covalency between the transition-metal t2g, the large cation-d, and the oxygen-p states; this covalency, which increases along the series, turns out to be responsible not only for the splittings of the t2g levels, but also for non-cubic perturbations of the hopping integrals, both of which are decisive for the Mott transition. We find good agreement with the optical and photoemission spectra, with the crystal-field splittings and orbital polarizations recently measured for the titanates, and with the metallization volume for LaTiO3. The metallization volume for YTiO3 is predicted. Using super-exchange theory, we reproduce the observed magnetic orders in LaTiO3 and YTiO3, but the results are sensitive to detail, in particular for YTiO3 which, without the Jahn-Teller distortion, would be AFM C- or A-type, rather than FM. Finally, we show that it possible to unfold the orthorhombic t2g LDA bandstructure to a pseudocubic zone. In this zone, the lowest band is separated from the two others by a direct gap and has a width, W_I, which is significantly smaller than that, W, of the entire t2g band. The progressive GdFeO3-type distortion favours electron localization by decreasing W, by increasing the splitting of the t2g levels and by decreasing W_I. Our conclusions concerning the roles of GdFeO3-type and JT distortions agree with those of Mochizuki and Imada [2].Comment: Published version, final. For high resolution figures see http://www.fkf.mpg.de/andersen/docs/pub/abstract2004+/pavarini_02.pd

Giant exciton Fano resonance in quasi-one-dimensional Ta2NiSe5

This work was partly supported by JSPS KAKENHI Grants No. 24224010, No. 15H05852, and No. 17H01140.We report the complex dielectric function of the quasi-one-dimensional chalcogenide Ta2NiSe5, which undergoes a structural phase transition presumably associated with exciton condensation below Tc = 326 K [Y. Wakisaka et al., Phys. Rev. Lett. 103, 026402 (2009); Y. F. Lu et al., Nat. Commun. 8, 14408 (2017)], and of the isostructural Ta2NiSe5, which does not exhibit such a transition. Using spectroscopic ellipsometry, we have detected exciton doublets with pronounced Fano line shapes in both the compounds. The exciton Fano resonances in Ta2NiSe5 display an order-of-magnitude higher intensity than those in Ta2NiSe5. In conjunction with prior theoretical work [E. Rashba, Sov. Phys. Semicond. 8, 807 (1975)], we attribute this observation to the giant oscillator strength of spatially extended exciton-phonon bound states in Ta2NiSe5. The formation of exciton-phonon complexes in Ta2NiSe5 and Ta2NiSe5 is confirmed by the pronounced temperature dependence of sharp interband transitions in the optical spectra, the peak energies and widths of which scale with the thermal population of optical phonon modes. The description of the optically excited states in terms of strongly overlapping exciton complexes is in good agreement with the hypothesis of an exciton insulator ground state.PostprintPeer reviewe

Vibrational signature of hydrated protons confined in MXene interlayers

The hydration structure of protons has been studied for decades in bulk water and protonated clusters due to its importance but has remained elusive in planar confined environments. Two dimensional 2D transition metal carbides known as MXenes show extreme capacitance in protic electrolytes, which has attracted attention in the energy storage field. We report here that discrete vibrational modes related to protons intercalated in the 2D slits between Ti3C2Tx MXene layers can be detected using operando infrared spectroscopy. The origin of these modes, not observed for protons in bulk water, is attributed to protons with reduced coordination number in confinement based on Density Functional Theory calculations. This study therefore demonstrates a useful tool for the characterization of chemical species under 2D confinemen

The Mid-Infrared Colors of the ISM and Extended Sources at the Galactic Center

A mid-infrared (3.6-8 um) survey of the Galactic Center has been carried out with the IRAC instrument on the Spitzer Space Telescope. This survey covers the central 2x1.4 degree (~280x200 pc) of the Galaxy. At 3.6 and 4.5 um the emission is dominated by stellar sources, the fainter ones merging into an unresolved background. At 5.8 and 8 um the stellar sources are fainter, and large-scale diffuse emission from the ISM of the Galaxy's central molecular zone becomes prominent. The survey reveals that the 8 to 5.8 um color of the ISM emission is highly uniform across the surveyed region. This uniform color is consistent with a flat extinction law and emission from polycyclic aromatic hydrocarbons (PAHs). Models indicate that this broadband color should not be expected to change if the incident radiation field heating the dust and PAHs is <10^4 times that of the solar neighborhood. The few regions with unusually red emission are areas where the PAHs are underabundant and the radiation field is locally strong enough to heat large dust grains to produce significant 8 um emission. These red regions include compact H II regions, Sgr B1, and wider regions around the Arches and Quintuplet Clusters. In these regions the radiation field is >10^4 times that of the solar neighborhood. Other regions of very red emission indicate cases where thick dust clouds obscure deeply embedded objects or very early stages of star formation.Comment: 37 pages, 15 Postscript figures (low resolution). Accepted for publication in the Ap