ANFIS pattern for molecular membranes separation optimization

In this work, molecular separation of aqueous-organic was simulated by using combined soft computing-mechanistic approaches. The considered separation system was a microporous membrane contactor for separation of benzoic acid from water by contacting with an organic phase containing extractor molecules. Indeed, extractive separation is carried out using membrane technology where complex of solute-organic is formed at the interface. The main focus was to develop a simulation methodology for prediction of concentration distribution of solute (benzoic acid) in the feed side of the membrane system, as the removal efficiency of the system is determined by concentration distribution of the solute in the feed channel. The pattern of Adaptive Neuro-Fuzzy Inference System (ANFIS) was optimized by finding the optimum membership function, learning percentage, and a number of rules. The ANFIS was trained using the extracted data from the CFD simulation of the membrane system. The comparisons between the predicted concentration distribution by ANFIS and CFD data revealed that the optimized ANFIS pattern can be used as a predictive tool for simulation of the process. The R2 of higher than 0.99 was obtained for the optimized ANFIS model. The main privilege of the developed methodology is its very low computational time for simulation of the system and can be used as a rigorous simulation tool for understanding and design of membrane-based systems. Highlights are, Molecular separation using microporous membranes. Developing hybrid model based on ANFIS-CFD for the separation process, Optimization of ANFIS structure for prediction of separation proces

Applicability of BaTiO 3 /graphene oxide (GO) composite for enhanced photodegradation of methylene blue (MB) in synthetic wastewater under UV–vis irradiation

Abstract(#br)Methylene blue (MB) is a dye pollutant commonly present in textile wastewater. We investigate and critically evaluate the applicability of BaTiO 3 /GO composite for photodegradation of MB in synthetic wastewater under UV–vis irradiation. To enhance its performance, the BaTiO 3 /GO composite is varied based on the BaTiO 3 weight. To compare and evaluate any changes in their morphologies and crystalline structures before and after treatment, BET (Brunauer–Emmett–Teller), XRD (X-ray diffraction), FTIR (Fourier transform infrared spectroscopy), SEM (scanning electron microscopy) and TEM (transmission electron microscopy) tests are conducted, while the effects of reaction time, pH, dose of photocatalyst and initial MB concentration on its photodegradation by the composite are also investigated under identical conditions. The degradation pathways and removal mechanisms of MB by the BaTiO 3 /GO are elaborated. It is evident from this study that the BaTiO 3 /GO composite is promising for MB photodegradation through ·OH. Under optimized conditions (0.5 g/L of dose, pH 9.0, and 5 mg/L of MB concentration), the composite with 1:2 dose ratio of BaTiO 3 /GO has the highest MB degradation rate (95%) after 3 h of UV vis irradiation. However, its treated effluents still could not comply with the discharge standard limit of less than 0.2 mg/L imposed by national environmental legislation. This suggests that additional biological treatments are still required to deal with the remaining oxidation by-products of MB, still present in the wastewater samples such as 3,7-bis (dimethyl-amino)-10H-phenothiazine 5-oxide

Applicability of BaTiO3/graphene oxide (GO) composite for enhanced photodegradation of methylene blue (MB) in synthetic wastewater under UV-vis irradiation.

Methylene blue (MB) is a dye pollutant commonly present in textile wastewater. We investigate and critically evaluate the applicability of BaTiO3/GO composite for photodegradation of MB in synthetic wastewater under UV-vis irradiation. To enhance its performance, the BaTiO3/GO composite is varied based on the BaTiO3 weight. To compare and evaluate any changes in their morphologies and crystalline structures before and after treatment, BET (Brunauer-Emmett-Teller), XRD (X-ray diffraction), FTIR (Fourier transform infrared spectroscopy), SEM (scanning electron microscopy) and TEM (transmission electron microscopy) tests are conducted, while the effects of reaction time, pH, dose of photocatalyst and initial MB concentration on its photodegradation by the composite are also investigated under identical conditions. The degradation pathways and removal mechanisms of MB by the BaTiO3/GO are elaborated. It is evident from this study that the BaTiO3/GO composite is promising for MB photodegradation through ·OH. Under optimized conditions (0.5 g/L of dose, pH 9.0, and 5 mg/L of MB concentration), the composite with 1:2 dose ratio of BaTiO3/GO has the highest MB degradation rate (95%) after 3 h of UV vis irradiation. However, its treated effluents still could not comply with the discharge standard limit of less than 0.2 mg/L imposed by national environmental legislation. This suggests that additional biological treatments are still required to deal with the remaining oxidation by-products of MB, still present in the wastewater samples such as 3,7-bis (dimethyl-amino)-10H-phenothiazine 5-oxide

Sweat permeable and ultrahigh strength 3D PVDF piezoelectric nanoyarn fabric strain sensor

Commercial wearable piezoelectric sensors possess excellent anti-interference stability due to their electronic packaging. However, this packaging renders them barely breathable and compromises human comfort. To address this issue, we develop a PVDF piezoelectric nanoyarns with an ultrahigh strength of 313.3 MPa, weaving them with different yarns to form three-dimensional piezoelectric fabric (3DPF) sensor using the advanced 3D textile technology. The tensile strength (46.0 MPa) of 3DPF exhibits the highest among the reported flexible piezoelectric sensors. The 3DPF features anti-gravity unidirectional liquid transport that allows sweat to move from the inner layer near to the skin to the outer layer in 4 s, resulting in a comfortable and dry environment for the user. It should be noted that sweating does not weaken the piezoelectric properties of 3DPF, but rather enhances. Additionally, the durability and comfortability of 3DPF are similar to those of the commercial cotton T-shirts. This work provides a strategy for developing comfortable flexible wearable electronic devices

Ethylene glycol elimination in amine loop for more efficient gas conditioning

Abstract The gas sweetening unit of phase 2 and 3 in South Pars Gas Field (Asalouyeh, Iran) was first simulated to investigate the effect of mono ethylene glycol (MEG) in the amine loop. MEG is commonly injected into the system to avoid hydrate formation while a few amounts of MEG is usually transferred to amine gas sweetening plant. This paper aims to address the points where MEG has negative effects on gas sweetening process and what the practical ways to reduce its effect are. The results showed that in the presence of 25% of MEG in amine loop, H2S absorption from the sour gas was increased from 1.09 to 3.78 ppm. Also, the reboiler temperature of the regenerator (from 129 to 135 °C), amine degradation and required steam and consequently corrosion (1.10 to 17.20 mpy) were increased. The energy consumption and the amount of amine make-up increase with increasing MEG loading in amine loop. In addition, due to increasing benzene, toluene, ethylbenzene and xylene (BTEX) and heavy hydrocarbon solubility in amine solution, foaming problems were observed. Furthermore, side effects of MEG presence in sulfur recovery unit (SRU) such as more transferring BTEX to SRU and catalyst deactivation were also investigated. The use of total and/or partial fresh MDEA, install insulation and coating on the area with the high potential of corrosion, optimization of operational parameters and reduction of MEG from the source were carried out to solve the problem. The simulated results were in good agreement with industrial findings. From the simulation, it was found that the problem issued by MEG has less effect when MEG concentration in lean amine loop was kept less than 15% (as such observed in the industrial plant). Furthermore, the allowable limit, source and effects of each contaminant in amine gas sweetening were illustrated

Hormones removal from municipal wastewater using ultrasound

Abstract Estrogens are one of the micro-pollutants in the wastewater which have detrimental effects on water living organisms. The aim of this study was to evaluate the efficiency of ultrasound to reduce the estrogen (E1) and 17 beta-estradiol (E2) from municipal wastewater. Hence, a cylindrical batch reactor was designed. The effects of powers, frequency, exposure time and pH on reduction efficiency were investigated. The residual concentration of E1 and E2 hormones was measured in reactor effluent by electrochemiluminescence (ECL) method. The results showed that ultrasound removed 85–96% of both E1 and E2 hormones after 45 min while other parameters changes in the range of their operations. Also, the frequency and power of ultrasound had a significant effect on reduction efficiency of hormones while the exposure had no significant effect. Furthermore, the interaction of power and frequency reduced their efficacy to 64.3% (Pvalue = 0.005). The result also indicated that the ultrasound waves have high ability to reduce Steroid hormones from municipal wastewater. The proposed method can be considered as one of the significant strategies for reduction or destruction of hormones from wastewater due to the non-generation of dangerous by-products and the low energy consumption

High Loaded Synthetic Hazardous Wastewater Treatment Using Lab-Scale Submerged Ceramic Membrane Bioreactor

Submerged ceramic membrane bioreactors (SCMBRs) are more efficient combinations of traditional activated hazardous sludge and new membrane separation processes in wastewater treatment. Suspended solids are separated from hazardous effluent using microfilter ceramic membranes in SCMBRs. A high loaded wastewater was treated using an SCMBR employing a homemade tubular ceramic membrane in laboratory scale. Hydraulic Retention Time (HRT) was 32 h and COD range was varied from 2000 to 5000 mg/l. COD removal was evaluated to be more than 90% after a week and the lab scale SCMBR showed desired performance for the wastewater treatment. Mixed Liquor Suspended Solid (MLSS) was increased from 2000 to 4000 mg/L during the SCMBR operation time

ANFIS pattern for molecular membranes separation optimization

In this work, molecular separation of aqueous-organic was simulated by using combined soft computing-mechanistic approaches. The considered separation system was a microporous membrane contactor for separation of benzoic acid from water by contacting with an organic phase containing extractor molecules. Indeed, extractive separation is carried out using membrane technology where complex of solute-organic is formed at the interface. The main focus was to develop a simulation methodology for prediction of concentration distribution of solute (benzoic acid) in the feed side of the membrane system, as the removal efficiency of the system is determined by concentration distribution of the solute in the feed channel. The pattern of Adaptive Neuro-Fuzzy Inference System (ANFIS) was optimized by finding the optimum membership function, learning percentage, and a number of rules. The ANFIS was trained using the extracted data from the CFD simulation of the membrane system. The comparisons between the predicted concentration distribution by ANFIS and CFD data revealed that the optimized ANFIS pattern can be used as a predictive tool for simulation of the process. The R2 of higher than 0.99 was obtained for the optimized ANFIS model. The main privilege of the developed methodology is its very low computational time for simulation of the system and can be used as a rigorous simulation tool for understanding and design of membrane-based systems.</p

Wastewaters treatment containing phenol and ammonium using aerobic submerged membrane bioreactor

Abstract Phenolic wastewater was treated using anaerobic submerged membrane bioreactor (ASMBR). Effect of different solids retention times on MBR performance was studied. Various ratios of carbon to nitrogen were used in the synthetic wastewaters. During the operation, phenol concentration of feed was changed from 100 to 1000 mg L−1. Phenol concentration was increased stepwise over the first 30 days and kept constant at 1000 mg L−1, thereafter. For the first 100 days, a chemical oxygen demand (COD) to N ratio of 100:5.0 was used and this resulted in phenol and COD removal more than 99 and 95%, respectively. However, the ammonium removal decreased from 95 to 40% by increasing the phenol concentration of feed, from 100 to 1000 mg L−1. For the last 25 days, a COD to N ratio of 100:2.1 was used due to the ammonium accumulation in the ASMBR. This led to the complete ammonium removal and no ammonium was detected in the ASMBR permeate. These results suggest that in the ASMBR at high phenol loading of 1000 mg L−1, COD to N ratio of the phenolic wastewater must be 100:2.1 for ammonium removal, while at low phenol loading, COD to N ratio of 100:5.0 can be used