45 research outputs found
The critical current density of advanced internal-Mg-diffusion-processed MgB2 wires
Recent advances in MgB2 conductors are leading to a new level of performance.
Based on the use of proper powders, proper chemistry, and an architecture which
incorporates internal Mg diffusion (IMD), a dense MgB2 structure with not only
a high critical current density Jc, but also a high engineering critical
current density, Je, can be obtained. In this paper, a series of these advanced
(or second - generation, "2G") conductors has been prepared. Scanning electron
microscopy and associated energy dispersive X-ray spectroscopy were applied to
characterize the microstructures and compositions of the wires, and a dense
MgB2 layer structure was observed. The best layer Jc for our sample is 1.07x105
A/cm2 at 10 T, 4.2 K, and our best Je is seen to be 1.67x104 A/cm2 at 10 T, 4.2
K. Optimization of the transport properties of these advanced wires is
discussed in terms of B-powder choice, area fraction, and the MgB2 layer growth
mechanism.Comment: 13 pages, 3 tables, 7 figures (or 8 pp in published version
Superconductivity in MgB_2 doped with Ti and C
Measurements of the superconducting upper critical field, H_{c2}, and
critical current density, J_c, have been carried out for MgB_2 doped with Ti
and/or C in order to explore the problems encountered if these dopants are used
to enhance the superconducting performance. Carbon replaces boron in the MgB_2
lattice and apparently shortens the electronic mean free path thereby raising
H_c2. Titanium forms precipitates of either TiB or TiB_2 that enhance the flux
pinning and raise J_c. Most of these precipitates are intra-granular in the
MgB_2 phase. If approximately 0.5% Ti and approximately 2% C are co-deposited
with B to form doped boron fibers and these fibers are in turn reacted in Mg
vapor to form MgB_2, the resulting superconductor has H_{c2}(T=0) ~ 25 T and
J_c ~ 10,000 A/cm**2 at 5 K and 2.2 T.Comment: 11 pages, 10 figure
The Effect of Excess Carbon on the Crystallographic, Microstructural, and Mechanical Properties of CVD Silicon Carbide Fibers
Silicon carbide (SiC) fibers made by chemical vapor deposition (CVD) are of interest for organic, ceramic, and metal matrix composite materials due their high strength, high elastic modulus, and retention of mechanical properties at elevated processing and operating temperatures. The properties of SCS-6{trademark} silicon carbide fibers, which are made by a commercial process and consist largely of stoichiometric SiC, were compared with an experimental carbon-rich CVD SiC fiber, to which excess carbon was added during the CVD process. The concentration, homogeneity, and distribution of carbon were measured using energy dispersive x-ray spectroscopy (SEM/EDS). The effect of excess carbon on the tensile strength, elastic modulus, and the crystallographic and microstructural properties of CVD silicon carbide fibers was investigated using tensile testing, x-ray diffraction, scanning electron microscopy (SEM), and transmission electron microscopy (TEM)
Plasma Synthesized Doped Boron Nanopowder for MgB2 Superconductors
Under this program, a process to synthesize nano-sized doped boron powder by a plasma synthesis process was developed and scaled up from 20 gram batches at program start to over 200 grams by program end. Over 75 batches of boron nanopowder were made by RF plasma synthesis. Particle sizes were typically in the 20-200 nm range. The powder was synthesized by the reductive pyrolysis of BCl{sub 3} in hydrogen in an RF plasma. A wide range of process parameters were investigated including plasma power, torch geometry, gas flow rates, and process pressure. The powder-in-tube technique was used to make monofilament and multifilament superconducting wires. MgB{sub 2} wire made with Specialty Materials plasma synthesized boron nanopowder exhibited superconducting properties that significantly exceeded the program goals. Superconducting critical currents, J{sub c}, in excess of 10{sup 5} A cm{sup -2} at magnetic fields of 8 tesla were reproducibly achieved. The upper critical magnetic field in wires fabricated with program boron powder were H{sub c2}(0) = 37 tesla, demonstrating the potential of these materials for high field magnet applications. T{sub c} in carbon-doped MgB{sub 2} powder showed a systematic decrease with increasing carbon precursor gas flows, indicating the plasma synthesis process can give precise control over dopant concentrations. Synthesis rates increased by a factor of 400% over the course of the program, demonstrating the scalability of the powder synthesis process. The plasma synthesis equipment at Specialty Materials has successfully and reproducibly made high quality boron nanopowder for MgB{sub 2} superconductors. Research and development from this program enabled Specialty Materials to successfully scale up the powder synthesis process by a factor of ten and to double the size of its powder pilot plant. Thus far the program has been a technical success. It is anticipated that continued systematic development of plasma processing parameters, dopant chemistry and concentration, wire processing technology, and collection technology will lead to the commercialization of boron nanopowder as a precursor for MgB{sub 2} superconductors. Potential commercial applications include magnets for magnetic resonance imaging (MRI), fault current limiters, wind turbine generators
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Fabrication of Chemically Doped, High Upper Critical Field Magnesium Diboride Superconducting Wires
Controlled chemical doping of magnesium diboride (MgB2) has been shown to substantially improve its superconducting properties to the levels required for high field magnets, but the doping is difficult to accomplish through the usual route of solid state reaction and diffusion. Further, superconducting cables of MgB2 are difficult to fabricate because of the friable nature of the material. In this Phase I STTR project, doped and undoped boron fibers were made by chemical vapor deposition (CVD). Several >100m long batches of doped and undoped fiber were made by CVD codeposition of boron plus dopants. Bundles of these fibers infiltrated with liquid magnesium and subsequently converted to MgB2 to form Mg-MgB2 metal matrix composites. In a parallel path, doped boron nano-sized powder was produced by a plasma synthesis technique, reacted with magnesium to produce doped MgB2 superconducting ceramic bodies. The doped powder was also fabricated into superconducting wires several meters long. The doped boron fibers and powders made in this program were fabricated into fiber-metal composites and powder-metal composites by a liquid metal infiltration technique. The kinetics of the reaction between boron fiber and magnesium metal was investigated in fiber-metal composites. It was found that the presence of dopants had significantly slowed the reaction between magnesium and boron. The superconducting properties were measured for MgB2 fibers and MgB2 powders made by liquid metal infiltration. Properties of MgB2 products (Jc, Hc2) from Phase I are among the highest reported to date for MgB2 bulk superconductors. Chemically doped MgB2 superconducting magnets can perform at least as well as NbTi and NbSn3 in high magnetic fields and still offer an improvement over the latter two in terms of operating temperature. These characteristics make doped MgB2 an effective material for high magnetic field applications, such as magnetic confined fusion, and medical MRI devices. Developing fusion as an energy source will dramatically reduce energy costs, global warming, and radioactive waste. Cheaper and more efficient medical MRI devices could lower examination costs, find potential health problems earlier, and thus also benefit society as a whole. Other potential commercial applications for this material are devices for the generation and storage of electrical power, thus lowering the cost of delivered electricity
Superior critical current density obtained in MgB2 bulks through low-cost carbon-encapsulated boron powder
Synthesen und thermisches Verhalten voncis-Bis(4-tert-butyl-phenyl)platin(II)- undcis-(4-tert-Butylphenyl)(phenyl)platin(II)-Verbindungen mit Substituenten unterschiedlichen Charakters in den Phenylringen
Superconductivity in MgB2 doped with Ti and C
Measurements of the superconducting upper critical field, Hc2, and critical current density, Jc, have been carried out for MgB2 doped with Ti and/or C in order to explore the problems encountered if these dopants are used to enhance the superconducting performance. Carbon replaces boron on the MgB2 lattice and apparently shortens the electronic mean free path of MgB2 and raising Hc2. Titanium forms precipitates of either TiB or TiB2 that enhance the flux pinning and raise Jc. Most of these precipitates are intra-granular in the MgB2 phase. For samples containing both C and Ti doping, the C appears to still replace B in the MgB2 lattice and the Ti precipitates out as a boride. If approximately 0.5%Ti and approximately 2%C are co-deposited with B to form doped boron fibers and these fibers are in turn reacted in Mg vapor to form doped MgB2, the resulting superconductor has μ0Hc2(T = 0) ∼ 25 T and Jc ∼ 10,000 A/cm2 at 5 K and 2.2 T.This is a manuscript of an article published as Wilke, R. H. T., S. L. Bud’ko, P. C. Canfield, M. J. Kramer, Y. Q. Wu, D. K. Finnemore, R. J. Suplinskas, J. V. Marzik, and S. T. Hannahs. "Superconductivity in MgB2 doped with Ti and C." Physica C: Superconductivity 418, no. 3-4 (2005): 160-167.
DOI: 10.1016/j.physc.2004.11.022.
Copyright 2004 Elsevier B.V.
Attribution-NonCommercial-NoDerivatives 4.0 International (CC BY-NC-ND 4.0).
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