42 research outputs found
Shaping electron wave functions in a carbon nanotube with a parallel magnetic field
A magnetic field, through its vector potential, usually causes measurable
changes in the electron wave function only in the direction transverse to the
field. Here we demonstrate experimentally and theoretically that in carbon
nanotube quantum dots, combining cylindrical topology and bipartite hexagonal
lattice, a magnetic field along the nanotube axis impacts also the longitudinal
profile of the electronic states. With the high (up to 17T) magnetic fields in
our experiment the wave functions can be tuned all the way from "half-wave
resonator" shape, with nodes at both ends, to "quarter-wave resonator" shape,
with an antinode at one end. This in turn causes a distinct dependence of the
conductance on the magnetic field. Our results demonstrate a new strategy for
the control of wave functions using magnetic fields in quantum systems with
nontrivial lattice and topology.Comment: 5 figure
Rehabilitation versus surgical reconstruction for non-acute anterior cruciate ligament injury (ACL SNNAP): a pragmatic randomised controlled trial
BackgroundAnterior cruciate ligament (ACL) rupture is a common debilitating injury that can cause instability of the knee. We aimed to investigate the best management strategy between reconstructive surgery and non-surgical treatment for patients with a non-acute ACL injury and persistent symptoms of instability.MethodsWe did a pragmatic, multicentre, superiority, randomised controlled trial in 29 secondary care National Health Service orthopaedic units in the UK. Patients with symptomatic knee problems (instability) consistent with an ACL injury were eligible. We excluded patients with meniscal pathology with characteristics that indicate immediate surgery. Patients were randomly assigned (1:1) by computer to either surgery (reconstruction) or rehabilitation (physiotherapy but with subsequent reconstruction permitted if instability persisted after treatment), stratified by site and baseline Knee Injury and Osteoarthritis Outcome Score—4 domain version (KOOS4). This management design represented normal practice. The primary outcome was KOOS4 at 18 months after randomisation. The principal analyses were intention-to-treat based, with KOOS4 results analysed using linear regression. This trial is registered with ISRCTN, ISRCTN10110685, and ClinicalTrials.gov, NCT02980367.FindingsBetween Feb 1, 2017, and April 12, 2020, we recruited 316 patients. 156 (49%) participants were randomly assigned to the surgical reconstruction group and 160 (51%) to the rehabilitation group. Mean KOOS4 at 18 months was 73·0 (SD 18·3) in the surgical group and 64·6 (21·6) in the rehabilitation group. The adjusted mean difference was 7·9 (95% CI 2·5–13·2; p=0·0053) in favour of surgical management. 65 (41%) of 160 patients allocated to rehabilitation underwent subsequent surgery according to protocol within 18 months. 43 (28%) of 156 patients allocated to surgery did not receive their allocated treatment. We found no differences between groups in the proportion of intervention-related complications.InterpretationSurgical reconstruction as a management strategy for patients with non-acute ACL injury with persistent symptoms of instability was clinically superior and more cost-effective in comparison with rehabilitation management
Solvent-solute hydrogen bonding in dilute solutions of CN - and CH 3 CN in water and methanol
Molecular-dynamics calculations have been carried out for dilute solutions of CN- and CH3CN in water and methanol at a temperature of 300 K. Results are reported for the numbers, energy distributions and lifetimes of hydrogen-bonded solute-solvent pairs. The numbers of bonds formed to methanol (c. 5.2 for CN-, 0.5 for CH3CN) are found to be fewer in number than those formed to water (c. 6.3 for CN-, 1.8 for CH3CN), but the lifetimes of the bonds in methanol are longer by factors of approximately three (for CN-) or eight (for CH3CN) than those in water. In the case of CN-, bonding to the nitrogen atom is favoured both in water and in methanol, and there is also evidence for the formation of short-lived, bifurcated structures. The results for CN- in solution present a more consistent pattern than those for CH3CN, and it is concluded that the description in terms of hydrogen bonding is less appropriate for the molecule than for the ion. However, the results for both solute species are in satisfactory overall agreement with those obtained experimentally by spectroscopic methods