Electrochemistry of thorium in LiCl-KCl eutectic melts

This work presents a study of the electrochemical properties of Th chloride ions dissolved in a molten LiCl-KCl eutectic, in a temperature range of 693-823 K. Transient electrochemical techniques such as cyclic voltammetry and chronopotentiommetry have been used in order to investigate the reduction mechanism on a tungsten electrode and the diffusion coefficient of dissolved Th ions. All techniques showed that only one valence state was stable in the melt. The reduction into Th metal was found to occur according to a one-step mechanism, through an irreversible reaction controlled by a nucleation process which requires an overpotential of several 100 mV. At 723 K, the diffusion coefficient is DTh(723K) = 3.7 ± 0.2·10-5 cm2.s-1. EMF measurements indicated that, at 723 K, the standard apparent potential is *0ThCl4 /Th) E (723 K) = - 2.582 V vs. Cl2/Cl-, and the activity coefficient γThCl4(723 K) = 8·10-3 on the mole fraction scale (based on a pure liquid reference state)

Strengthening financial innovations in energy supply projects for rural exploitations in developing countries

Sustainable energy supply models are needed to achieve the Millennium Development Goals established by the United Nations for 2015. On the other hand, sustainability of agricultural exploitations in rural areas is a pre-requisite to achieve the objective of halving the proportion of people that lives in poverty, and productivity of such exploitations is closely related to energy supply. This article analyses the results of a survey of experts, suggesting that there may be good chances to innovate in the financing of agricultural electrification projects in developing countries. The experts’ opinion suggests that new sources of financing could be mobilised and oriented towards the promotion of sustainable initiatives in developing countries. Financial mechanisms should be adapted to the characteristics of decentralised systems of energy production with renewable sources or with mixed technologies, in order to overcome the barriers derived from the high initial price of the applications, and to the specific conditions of the agricultural sector. The participation of funds from the beneficiaries and the incorporation of the beneficiaries in the initial phases of project organisation would allow for the development of productive solutions with a higher potential to generate resources and to articulate sustainable proposals. r 2007 Elsevier Ltd. All rights reserved

Barriers to Investment in Energy from Renewable Sources

This paper attempts to create an overview of the current situation in the Romanian energy sector, pointing out elements of energy demand, production, investment in the sector and not least the potential of renewable energy sources. As Romania has aligned itself with the European Commission's 20-20-20 program, an important step in achieving the set targets is represented by a significant amount of investments in the development of energy from renewable sources. But there are a number of challenges that investment projects may face, namely, barriers more or less deliberate, more difficult or easier to overcome or remove, some of them real market distortions and others coming from the comparison between green energy and classic sources of energy. So, the last part of the work is dedicated to these barriers. Dividing them into four categories administrative barriers, technical and technological barriers, market barriers and economic barriers allows a better distribution of the identified barriers. It is a comprehensive and equitable approach than their splitting into cost barriers and non-cost barriers, which would have meant a long list for the second category specified.barriers, energy potential, investment, renewable energy.

Interferon free antiviral treatment of chronic hepatitis C in patients affected by β-thalassemia major

Chronic hepatitis C (CHC) significantly affects the prognosis of liver disease [1] and health related quality of life (HRQOL) in patients with β-thalassemia major [2, 3]. CHC cure is a crucial event in the prognosis of the disease, since prevents fibrosis progression, decreases the risk of hepatocellular carcinoma (HCC), and improves survival. Standard antiviral therapy with Pegylated Interferon (PEG-IFN) and Ribavirin (RBV) has long been the standard of care, despite its limited efficacy and increased ribavirin induced hematological adverse events in thalassemic patients [4]. Recently, several novel highly effective direct antiviral agents (DAAs) have been approved for HCV treatment, with impressive cure rates, higher than 90%, after 8–12 weeks of therapy and mild adverse events [5], but there are no published reports documenting the efficacy, safety and impact on QOL of available interferon-free antiviral regimens in patients with βthalassemia majo

Off the record?: Arrestee concerns about the manipulation, modification, and misrepresentation of police body-worn camera footage

Police body-worn cameras (BWC) have become the latest technological device introduced to policing on a wave of panacean promises. Recent research has reported the perspectives of police officers, police management, and the general public, but there have been no studies examining the views of police arrestees. Remedying this significant omission, this article presents findings generated from interviews with 907 individuals shortly after their arrest. Overall, we report a strong in principle support for police body-worn cameras amongst this cohort, particularly if the cameras can be operated impartially. The findings are organised into a trilogy of prominent and interrelated concerns voiced by the police detainees, namely the potential for the manipulation, modification, and misrepresentation of events captured by police body-worn cameras. The findings are discussed in a broader context of the “new visibility” of police encounters and contribute much needed findings to understand the culturally specific ways in which different publics experience and respond to visual surveillance

Energy for Development: The Potential Role of Renewable Energy in Meeting the Millennium Development Goals

This report identifies renewable energy options that are currently in wide use in some regions and that are now ready for large-scale introduction in many areas of the developing world. Through 26 case studies, the report cites biogas, small hydro, solar, wind, ethanol, and biodiesel, among other technologies, as viable options for poverty alleviation in developing countries.As their cost has declined and their reliability has improved, renewable energy technologies have often emerged as more affordable and practical means of providing essential energy services. Although the strongest renewable energy growth has been in grid-connected power systems and liquid fuels for transportation, several technologies are well-suited to providing modern energy services for low-income people. Scaling up a broad portfolio of renewable energy options can make a major contribution to achieving the Millennium Development Goals, concludes the report.The creation of REN 21 was sponsored by the German Federal Ministry for Economic Cooperation and Development and the German Federal Ministry for the Environment, Nature Conservation and Nuclear Safety. Formally established in Copenhagen in June 2005, REN 21 is now supported by a steering committee of 11 governments, five intergovernmental organizations, five non-governmental organizations, and several regional, local and private organizations

Technology without borders: case studies of successful technology transfer

Technology Without Borders presents case studies of successful transfer of climate-friendly technology and practices. It explores the causes for success and draws the lessons learned. Key messages are presented for the fight against climate destabilisation. The terms “climate-friendly technology” and “climate technology” used here refer to technologies, practices or techniques, which reduce greenhouse-gas emissions or assist countries in adapting to climate change

The constraining role of political culture in the deepening of new democracies: the case of Chile

A thesis submitted in partial fulfillment of the requirements for the degree of Bachelor of Arts in Political Science with Honors.This paper examines the role of political culture in the development of Chilean democracy as a case study for other third-wave democracies in the Latin American region. The prioritization of political stability during the years of democratic transition - seen as essential by the political elite to prevent the political polarization that led to the 1973 coup d’etat - resulted in limited social reform and the dissatisfaction of the average Chilean with his political parties. Differences in the political culture of the political elite and at the mass level resulted in a delegitimization of democracy for the average citizen. The Chilean case highlights a growing issue of representation in Latin America and a general loss of faith in the democratic project

Overcoming barriers to electrical energy storage: Comparing California and Europe

Multiple market drivers suggest that electrical energy storage (EES) systems are going to be essential for future power systems within the next decade. However, the deployment of the technology is proceeding at very different rates around the world. Whereas the sector is progressing quickly in California, it is not gaining much traction, so far, in Europe. This research aims to clarify why the prospects for energy storage in Europe are not as good as they are in California. The market and regulatory framework in California and Europe are analysed critically, and changes to overcome the main barriers are recommended. The research shows that the main barriers are: inadequate definition and classification of EES in legislation; lack of markets for some ancillary services; inadequate market design that benefits traditional technologies; and the lack of need for EES in some jurisdictions. The prospects are better in California because regulation is more advanced and favourable for the technology, and regulators are collaborating with developers and utilities to analyse barriers and solutions for the technology. In Europe, there is a need to clarify the definition of EES, create new markets for ancillary services, design technology-neutral market rules and study more deeply the necessity of EES

Resurrecting Class

By means of a re-analysis of the most relevant data source - the international social mobility and politics file - this paper criticizes the newly grown consensus in political sociology that class voting has declined since World War II. An increase of crosscutting cultural voting, rooted in educational differences