Historical and contemporary perspectives on the sediments of Lake Rotorua

Lake Rotorua is probably the oldest continuously inundated lake in New Zealand, occupying a caldera formed by or closely associated with the eruption of the Mamaku ignimbrite and the collapse of the Rotorua caldera (Healy, 1975; Lowe and Green, 1991). The lake has undergone drastic changes in size and depth as a result of tectonics, volcanic activity and erosion. Since the Rotoehu eruption, (~60 kyr), the lake level has fluctuated between 120 m above present (280 m asl) and 10 m below present level. The modern lake covers an area of 79 km2 and has a mean depth of 10 m. Despite its long history of sedimentation, Lake Rotorua has an irregular bathymetry with features including faulted blocks, slumps, hydrothermal explosion craters, springs and large methane discharge pock marks

Learning Incoherent Subspaces: Classification via Incoherent Dictionary Learning

In this article we present the supervised iterative projections and rotations (s-ipr) algorithm, a method for learning discriminative incoherent subspaces from data. We derive s-ipr as a supervised extension of our previously proposed iterative projections and rotations (ipr) algorithm for incoherent dictionary learning, and we employ it to learn incoherent sub-spaces that model signals belonging to different classes. We test our method as a feature transform for supervised classification, first by visualising transformed features from a synthetic dataset and from the ‘iris’ dataset, then by using the resulting features in a classification experiment

Improved acoustic emission source location during fatigue and impact events in metallic and composite structures

In order to overcome the difficulties in applying traditional Time-Of Arrival (TOA) techniques for locating Acoustic Emission (AE) events in complex structures and materials, a technique termed “delta-t mapping” was developed. This paper presents a significant improvement on this, in which the difficulties in identifying the precise arrival time of an AE signal are addressed by incorporating the Akaike Information Criteria (AIC). The performance of the TOA, the delta-t mapping and the AIC delta-t mapping techniques is assessed by locating artificial AE sources, fatigue damage and impact events in aluminium and composite materials respectively. For all investigations conducted the improved AIC delta-t technique shows a reduction in average Euclidean source location error irrespective of material or source type. For locating H-N sources on a complex aluminium specimen the average source location error (Euclidean) is 32.6, (TOA), 5.8 (delta-t) and 3mm (AIC delta-t). For locating fatigue damage on the same specimen the average error is 20.2, (TOA), 4.2 (delta-t) and 3.4mm (AIC delta-t). For locating H-N sources on a composite panel the average error is 19.3, (TOA), 18.9 (delta-t) and 4.2mm (AIC delta-t). Finally the AIC delta-t mapping technique had the lowest average error (3.3mm) when locating impact events when compared with the delta-t (18.9mm) and TOA (124.7mm) techniques. Overall the AIC delta-t mapping technique is the only technique which demonstrates consistently the lowest average source location error (greatest average error 4.2mm) when compared with the delta-t (greatest average error 18.9mm) and TOA (greatest average error 124.7mm) techniques. These results demonstrate that the AIC delta-t mapping technique is a viable option for AE source location, increasing the accuracy and likelihood of damage detection, irrespective of material, geometry and source type

Effects of Adding Sodium and Fluoride Ions to Glass Ionomer on its Interactions with Sodium Fluoride Solution

This investigates the effects of the addition of Na and F ions to a glass ionomer cement in which those ions are not inherently present on its interactions with dilute (0.2%) NaF solution. Both the effect of the solution on the cement\u27s surface morphology and the effect of the cement on the solution in terms of take up of Na+ and F- and of change in pH are to be investigated. These results are to be compared to previous results obtained with glasses which contained both, one, or neither of the ions as components of their glasses. NaF (1.3% by weight in the mixed cement) was added to the powder components of a glass ionomer based on LG30 glass (which contains Al, Si, Ca, P, and O only). Discs of cement were set in moulds at 37°C for 1h then stored in water at 37°C for 3 days. Each test disc was then immersed in 10ml 0.2% NaF solution whereas controls remained immersed in water (N=3 for test and control). Test and control disc surfaces were assessed both qualitatively by electron microscopy and quantitatively by linear profilometry (R(a) values). Potentiometry was used to measure solution pH and Na and F concentrations using a pH electrode and suitable ion selective electrodes both before and after cement immersion. The surface of test specimens was subject considerable disruption with the polysalt cement matrix being removed and residual glass particles being disclosed. The controls showed no such disruption. This effect was reflected in a significant difference of R(a). Such an effect was not shown by test and control surfaces of LG30 but a similar effect was to that shown by LG26 (which contains F as a glass component). Solution pH changed by 1 unit which was much more than the change shown by LG30 or LG26 but is similar to that of AH2 and MP4 cements which both contain Na. The Na and F uptake was much lower than for LG30 whereas that of LG26 was higher than LG30. The Na:F ratio was 0.29:1 compared to 1.26:1 for LG30 (LG26=1.01:1, AH2=1.02:1, MP4=1.04:1). Fluoride addition to a F-free glass ionomer renders it vulnerable to surface disruption by NaF solution showing that fluoride complexes produced in glass dissolution are not necessarily involved in this process. Sodium addition to a Na-free glass ionomer confirms the role of this cement in enhancing pH change in NaF solution. The level of uptake of F- from a NaF solution in much lower than that for the F-free glass ionomer which shows there is no direct relationship between F- uptake and surface disruption. The ratio of Na:F uptake is below 0.3:1, but the pH change is similar to cements where the ratio is close to unity which indicates that F-/OH- interchange is not a significant mechanism even when anion/cation uptake is not balanced. Copyright (C) 2000

Identification of lead chemotherapeutic agents from medicinal plants against blood flukes and whipworms

Schistosomiasis and trichuriasis are two of the most common neglected tropical diseases (NTD) that affect almost a billion people worldwide. There is only limited number of effective drugs to combat these NTD. Medicinal plants are a viable source of parasiticides. In this study, we have investigated six of the 19 phytochemicals isolated from two Bhutanese medicinal plants, Corydalis crispa and Pleurospermum amabile, for their anthelmintic properties. We used xWORM technique and Scanning Electron Microscope-based imaging to determine the activity of the compounds. Of the six compounds tested, isomyristicin and bergapten showed significant anthelmintic activity against Schistosoma mansoni and Trichuris muris with bergapten being the most efficacious one against both parasites (S. mansoni IC50 = 8.6 μg/mL and T. muris IC50 = 10.6 μg/mL) and also against schistosomula stage of S. mansoni. These two compounds induced tegumental damage to S. mansoni and affected the cuticle, bacillary bands and bacillary glands of T. muris. The efficacy against multiple phylogenetically distinct parasites and different life stages, especially the schistosomulum where praziquantel is ineffective, makes isomyristicin and bergapten novel scaffolds for broad-spectrum anthelmintic drug development that could be used for the control of helminths infecting humans and animals

Morphological transitions in the patterning of the crystalline Ge(001) surface induced by ion irradiation

We investigate the morphologies of the Ge(001) surface that are produced by bombardment with a normally incident, broad argon ion beam at sample temperatures above the recrystallization temperature. Two previously-observed kinds of topographies are seen, i.e., patterns consisting of upright and inverted rectangular pyramids, as well as patterns composed of shallow, isotropic basins. In addition, we observe the formation of an unexpected third type of pattern for intermediate values of the temperature, ion energy and ion flux. In this type of transitional morphology, isolated peaks with rectangular cross sections stand above a landscape of shallow, rounded basins. We also extend past theoretical work to include a second order correction term that comes from the curvature dependence of the sputter yield. For a range of parameter values, the resulting continuum model of the surface dynamics produces patterns that are remarkably similar to the transitional morphologies we observe in our experiments. The formation of the isolated peaks is the result of a term that is not ordinarily included in the equation of motion, a second order correction to the curvature dependence of the sputter yield

Budget Perspectives 2012. RESEARCH SERIES NUMBER 22 October 2011

The annual Budget Perspectives Conference, co‐hosted by the Economic and Social Research Institute (ESRI) and the Foundation for Fiscal Studies (FFS), provides a forum for discussing key public policy issues of both immediate and longer‐term concern. Against the current backdrop of major economic and fiscal challenges, budgetary policy must be seen to support Ireland’s return to a sustainable growth path. At a time when expenditure cuts are needed and more tax revenue must be generated, equity issues are of great importance to social solidarity. Research on the allocation of benefits and tax burdens allows these equity issues to be addressed systematically