Assessing the performance of international water management at Lake Titicaca

In this article, we study the performance of international water management at Lake Titicaca in order to assess the empirical applicability of a new concept for measuring policy performance. This performance measurement concept (PER) is a function of three variables: optimum performance (OP), actual performance (AP), and counterfactual performance (CP). In examining the joint management of Lake Titicaca by Bolivia and Peru, we identify practical difficulties in applying PER and suggest extensions of the concept to assess uncertainty. We find that this measurement concept has several advantages: it takes into account counterfactual performance; the analysis can be performed in a structured, standardized, and transparent manner; and the formal framework allows for an assessment of uncertainty. Problems in applying the concept include: choice of attributes, identification of optimum performance, time-scale, and subjectivity of information. We conclude that, on balance, this approach is superior to other policy performance assessment measures developed to dat

Assessing the performance of international water management at Lake Titicaca

ISSN:1015-1621ISSN:1420-905

Assessing the performance of international water management at Lake Titicaca

ISSN:1015-1621ISSN:1420-905

Assessing the performance of international water management at Lake Titicaca

ISSN:1015-1621ISSN:1420-905

Anaerobic stabilisation of urine diverting dehydrating toilet faeces (UDDT-F) in urban poor settlements: Biochemical energy recovery

Biochemical energy recovery using digestion and co-digestion of faecal matter collected from urine diverting dehydrating toilet faeces (UDDT-F) and mixed organic market waste (OMW) was studied under laboratory-and pilot-scale conditions. Laboratory-scale biochemical methane potential (BMP) tests showed an increase in methane production with an increase in OMW fraction in the feed substrate. In subsequent pilot-scale experiments, one-stage and two-stage plug flow digester were researched, applying UDDT-F:OMW ratios of 4:1 and 1:0, at about 10 and 12% total solids (TS) slurry concentrations. Comparable methane production was observed in one-stage (Ro-4:1,12%) (314 ± 15 mL CH4/g VS added) and two-stage (Ram-4:1,12%) (325 ± 12 mL CH4 /g VS added) digesters, when applying 12% TS slurry concentration. However, biogas production in Ram-4:1,12% digester (571 ± 25 mL CH4/g VS added) was about 12% higher than in Ro-4:1,12%, significantly more than the slight difference in methane production, i.e. 3–4%. The former was attributed to enhanced waste solubilisation and increased CO2 dissolution, resulting from mixing the bicarbonate-rich methanogenic effluent for neutralisation purposes with the low pH (4.9) influent acquired from the pre-acidification stage. Moreover, higher process stability was observed in the first parts of the plug flow two-stage digester, characterised by lower VFA concentrations.Sanitary Engineerin

Build-up and impact of volatile fatty acids on E. coli and A. lumbricoides during co-digestion of urine diverting dehydrating toilet (UDDT-F) faeces

This study examined the potential of Escherichia coli (E. coli) and Ascaris lumbricoides (A. lumbricoides) eggs inactivation in faecal matter coming from urine diverting dehydrating toilets (UDDT-F) by applying high concentrations of volatile fatty acids (VFAs) during anaerobic stabilization. The impact of individual VFAs on E. coli and A. lumbricoides eggs inactivation in UDDT-F was assessed by applying various concentrations of store-bought acetate, propionate and butyrate. High VFA concentrations were also obtained by performing co-digestion of UDDT-F with organic market waste (OMW) using various mixing ratios. All experiments were performed under anaerobic conditions in laboratory scale batch assays at 35±1 °C. A correlation was observed between E. coli log inactivation and VFA concentration. Store bought VFA spiked UDDT-F substrates achieved E. coli inactivation up to 4.7 log units/day compared to UDDT-F control sample that achieved 0.6 log units/day. In co-digesting UDDT-F and organic market waste (OMW), a ND-VFA concentration of 4800–6000 mg/L was needed to achieve E. coli log inactivation to below detectable levels and complete A. lumbricoides egg inactivation in less than four days. E. coli and A. lumbricoides egg inactivation was found to be related to the concentration of non-dissociated VFA (ND-VFA), increasing with an increase in the OMW fraction in the feed substrate. Highest ND-VFA concentration of 6500 mg/L was obtained at a UDDT-F:OMW ratio 1:1, below which there was a decline, attributed to product inhibition of acidogenic bacteria. Results of our present research showed the potential for E. coli and A. lumbricoides inactivation from UDDT-F up to WHO standards by allowing VFA build-up during anaerobic stabilization of faecal matter.Green Open Access added to TU Delft Institutional Repository ‘You share, we take care!’ – Taverne project https://www.openaccess.nl/en/you-share-we-take-care Otherwise as indicated in the copyright section: the publisher is the copyright holder of this work and the author uses the Dutch legislation to make this work public.Sanitary Engineerin

Volatile fatty acids build-up and its effect on E. coli inactivation during excreta stabilisation in single-stage and two-stage systems

Digestion and co-digestion of faecal matter collected from urine diverting dehydrating toilet faeces (UDDT-F) and mixed organic market waste (OMW) was studied in single stage pilot scale mesophilic plug-flow anaerobic reactors at UDDT-F:OMW ratios 4:1 and 1:0. Escherichia coli inactivation and volatile fatty acids (VFA) build-up was monitored at sampling points located along the reactor profile. When applying UDDT-F:OMW ratio of 4:1 at 12% total solids (TS), E. coli inactivation achieved was 2.3 log times higher than that achieved in UDDT-F:OMW ratio of 1:0. In subsequent trials, a two-stage reactor was researched, applying a UDDT-F:OMW ratio of 4:1 and 10 or 12% TS slurry concentrations. Highest VFA concentrations of 16.3 ± 1.3 g/L were obtained at a pH of 4.9 in the hydrolysis/ acidogenesis reactor, applying a UDDT-F:OMW ratio of 4:1 and 12% TS, corresponding to a non-dissociated (ND)-VFA concentration of 6.9 ± 2.0 g/L. The corresponding decay rate reached a value of 1.6 per day. In the subsequent methanogenic plug-flow reactor, a decay rate of 1.1 per day was attained within the first third part of the reactor length, which declined to 0.6 per day within the last third part of the reactor length. Results show that a two-stage system is an efficient way to enhance pathogen inactivation during anaerobic digestion.Green Open Access added to TU Delft Institutional Repository ‘You share, we take care!’ – Taverne project https://www.openaccess.nl/en/you-share-we-take-care Otherwise as indicated in the copyright section: the publisher is the copyright holder of this work and the author uses the Dutch legislation to make this work public.Sanitary Engineerin

Improvement of the global quantification of PFAS through TF, AOF and EOF measurements: Application to complex environmental matrices (sludge and compost) from wastewater treatment plants

International audienceMore than 4000 Per- and polyfluoroalkyl substances (PFAS) also called forever chemicals are attracting the warning of scientists and public authorities [1]. The application of ion chromatography to environmental matrices allows the global analysis of different halogens including fluorine thanks to initial sample combustion using CIC instrument [2]. Depending on the sample preparation, different fractions of the sample can be analysed by CIC [5]: TF (total fluorine), EOF (extractable organic fluorine) or AOF (adsorbable organic fluorine). Removal of inorganic fluorine (IF) is needed for discrimination of organic fluorine from TF content. Even though the analytical principle is relatively simple, different methodological issues may arise. Differences in analytical responses related to the forms (inorganic or organic) or chemical structure (easily or not incinerated during combustion step), and mismatch with standards used for calibration could lead either to under- or over-estimation of the fluorine content [3]. Due to the large range of polarity among PFAS, recoveries during solid phase extraction step both on activated carbon or other polymeric cartridges should be assessed to avoid underestimation of OF content. Effect of complex matrices such as compost or sludges for solid samples, or WWTP effluent for liquid samples need to be investigated to validate the robustness of the method. For this study, our objective is to propose validated robust and reliable methods for measuring global organic fluorine based on CIC measurements for TF and EOF for complex solids and AOF, SPE-AOF, EOF and TF for liquid samples. Methods will applied on biosolids and recovered fertilizers to evaluate the capacity of PFAS release to the environment through spreading of these materials

Determination of organic fluorinated compounds content in complex samples through combustion ion chromatography methods: a way to define a “Total Per- and Polyfluoroalkyl Substances (PFAS)” parameter?

International audienceEmerging contaminants are a growing concern for scientists and public authorities. The group of per-polyfluoroalkyl substances (PFAS), known as ‘forever chemicals', in complex environmental liquid and solid matrices was analysed in this study. The development of global analytical methods based on combustion ion chromatography (CIC) is expected to provide accurate picture of the overall PFAS contamination level via the determination of extractable organic fluorine (EOF) and adsorbable organic fluorine (AOF). The obtained results may be put into perspective with other methods such as targeted analyses (LC-MS/MS). The impact of pH, the presence of dissolved organic carbon and suspended particles on AOF measurements were explored. The effectiveness of the washing step to remove adsorbed inorganic fluorine (IF) has been proven for samples containing up to 8 mgF.L−1. CIC-based methods showed good repeatability and reproducibility for the complex matrices studied. Environmental applications of these methods have been tested. AOF and EOF analyses could explain between 1 % and 23 % and 0.1 % to 2 % of total organic fluorine (TOF), respectively. The sum of PFAS compounds expressed as fluorine could explain from 0.2 % to 11 % and from 0.003 % to 5 % for AOF and EOF, respectively. These results also suggest that some fluorinated compounds are not adsorbed or extractable and/or lost by volatilisation during the application of AOF and EOF analytical procedure. These findings highlight that AOF and EOF are not entirely efficient as proxy to assess “total PFAS” for assessing environmental contamination by PFAS. However, these methods could still be applied to gain a better understanding of the sources and fate of PFAS in the environmen