Matrix isolation as a tool for studying interstellar chemical reactions

Since the identification of the OH radical as an interstellar species, over 50 molecular species were identified as interstellar denizens. While identification of new species appears straightforward, an explanation for their mechanisms of formation is not. Most astronomers concede that large bodies like interstellar dust grains are necessary for adsorption of molecules and their energies of reactions, but many of the mechanistic steps are unknown and speculative. It is proposed that data from matrix isolation experiments involving the reactions of refractory materials (especially C, Si, and Fe atoms and clusters) with small molecules (mainly H2, H2O, CO, CO2) are particularly applicable to explaining mechanistic details of likely interstellar chemical reactions. In many cases, matrix isolation techniques are the sole method of studying such reactions; also in many cases, complexations and bond rearrangements yield molecules never before observed. The study of these reactions thus provides a logical basis for the mechanisms of interstellar reactions. A list of reactions is presented that would simulate interstellar chemical reactions. These reactions were studied using FTIR-matrix isolation techniques

Thermophysical property measurements in electromagnetic levitators

Proper measurements of thermophysical properties of hot levitated liquid drops require the following: accurate temperature measurement (brightness measurement, emissivity measurement); precise drop shape measurements with submillisecond time resolution (density determination, rotational and vibrational shape information); precise control of drop shape (high symmetry variable gap levitators); accurate energy transfer measurements (direct measurements of energy transfer rates for defined gas flows over samples with quantitative measurements of energy transfer rates for defined flows over samples with known shapes); and precise measurements of repetitive sample motions (rapid repetitive shape measurements, frequency measurements with reflected laser light, measurements in the levitator and as a freely falling drop). Recent advances in coil design and control of sample rotation in an electromagnetic levitator are discussed with respect to the above requirements