The Impact Of Crystal Morphology On The Thermal Responses Of Ultrasonically-Excited Energetic Materials

The ability to detect explosive materials may be significantly enhanced with local increases in vapor pressure caused by an elevation of the materials\u27temperature. Recently, ultrasonic excitation has been shown to generate heat within plastic-bonded energetic materials. To investigate the impact of crystal morphology on this heating, samples of elastic binder are implanted with single ammonium perchlorate crystals of two distinct shape groups. Contact piezoelectric transducers are then used to excite the samples at ultrasonicfrequencies. The thermal responses of the crystals are recorded using infrared thermography, and the rate of heating is estimated. Surface temperature increases up to 15 °C are found to arise after 2 s of excitation, with much higher heating levels expected near the inclusions themselves as demonstrated by the chemical decomposition of some crystals under favorable excitation conditions. The rates of heat generation are compared to various crystal morphology features through 2D estimates of length scale, perimeter and irregularity. It is observed that crystals grown in the lab, featuring sharp geometric facets, exhibit a higher probability of significant heat generation than inclusions with more spherical shapes. However, no statistical link is found between the rates of heat generation and the crystal morphology in those samples that do generate significant heating, likely because variations in surface roughness cannot be entirely eliminated during experimentation. It is hoped that this study will lead to a better understanding of the nature of heat generation in energetic materialsfrom ultrasonic sources

Chaotic scattering with direct processes: A generalization of Poisson's kernel for non-unitary scattering matrices

The problem of chaotic scattering in presence of direct processes or prompt responses is mapped via a transformation to the case of scattering in absence of such processes for non-unitary scattering matrices, \tilde S. In the absence of prompt responses, \tilde S is uniformly distributed according to its invariant measure in the space of \tilde S matrices with zero average, < \tilde S > =0. In the presence of direct processes, the distribution of \tilde S is non-uniform and it is characterized by the average (\neq 0). In contrast to the case of unitary matrices S, where the invariant measures of S for chaotic scattering with and without direct processes are related through the well known Poisson kernel, here we show that for non-unitary scattering matrices the invariant measures are related by the Poisson kernel squared. Our results are relevant to situations where flux conservation is not satisfied. For example, transport experiments in chaotic systems, where gains or losses are present, like microwave chaotic cavities or graphs, and acoustic or elastic resonators.Comment: Added two appendices and references. Corrected typo

Heat generation in an elastic binder system with embedded discrete energetic particles due to high-frequency, periodic mechanical excitation

High-frequency mechanical excitation can induce heating within energetic materials and may lead to advances in explosives detection and defeat. In order to examine the nature of this mechanically induced heating, samples of an elastic binder (Sylgard 184) were embedded with inert and energetic particles placed in a fixed spatial pattern and were subsequently excited with an ultrasonic transducer at discrete frequencies from 100 kHz to 20 MHz. The temperature and velocity responses of the sample surfaces suggest that heating due to frictional effects occurred near the particles at excitation frequencies near the transducer resonance of 215 kHz. An analytical solution involving a heat point source was used to estimate heating rates and temperatures at the particle locations in this frequency region. Heating located near the sample surface at frequencies near and above 1 MHz was attributed to viscoelastic effects related to the surface motion of the samples. At elevated excitation parameters near the transducer resonance frequency, embedded particles of ammonium perchlorate and cyclotetramethylene-tetranitramine were driven to chemical decomposition

Caracterização dos sistemas de produção da agricultura familiar de Paragominas-PA: a pecuária e propostas de desenvolvimento.

Caracterização da região de estudo. Diagnóstico. Caracterização dos sistemas agrícolas.bitstream/item/57599/1/Oriental-Doc5.pd

Thermal And Mechanical Response Of PBX 9501 Under Contact Excitation

The thermal and mechanical responses of a cyclotetramethylene-tetranitramine-based explosive (PBX 9501) and two non-energetic mock materials (900-21 and PBS 9501) under high-frequency mechanical excitation are presented. Direct contact ultrasound transducers were used to excite samples through a frequency range of 50 kHz to 40 MHz. The mechanical response of each sample was approximated from a contact receiving transducer and trends were confirmed via laser Doppler vibrometry. The steady-state thermal response of the samples was measured at discrete excitation frequencies via infrared thermography. A maximum temperature rise of approximately 15 K was observed in PBX 9501, and the mock materials exhibited similar thermal characteristics. Temperature gradients were calculated to estimate the total heat generated within the samples due to the mechanical excitation. The active heating mechanisms were found to be highly dependent on the frequency of excitation. Possible mechanisms of heating at frequencies below 1 MHz are likely related to bulk motion. Above this frequency, the active heating mechanisms are likely related to particle-scale processes. The observed phenomena may prove useful in the aid of current trace vapor detection methods for explosives

Localized Heating Near a Rigid Spherical Inclusion in a Viscoelastic Binder Material Under Compressional Plane Wave Excitation

High-frequency mechanical excitation has been shown to generate heat within composite energetic materials and even induce reactions in single energetic crystals embedded within an elastic binder. To further the understanding of how wave scattering effects attributable to the presence of an energetic crystal can result in concentrated heating near the inclusion, an analytical model is developed. The stress and displacement solutions associated with the scattering of compressional plane waves by a spherical obstacle (Pao and Mow, 1963, “Scattering of Plane Compressional Waves by a Spherical Obstacle,” J. Appl. Phys., 34(3), pp. 493–499) are modified to account for the viscoelastic effects of the lossy media surrounding the inclusion (Gaunaurd and Uberall, 1978, “Theory of Resonant Scattering From Spherical Cavities in Elastic and Viscoelastic Media,” J. Acoust. Soc. Am., 63(6), pp. 1699–1712). The results from this solution are then utilized to estimate the spatial heat generation due to the harmonic straining of the material, and the temperature field of the system is predicted for a given duration of time. It is shown that for certain excitation and sample configurations, the elicited thermal response near the inclusion may approach, or even exceed, the decomposition temperatures of various energetic materials. Although this prediction indicates that viscoelastic heating of the binder may initiate decomposition of the crystal even in the absence of defects such as initial voids or debonding between the crystal and binder, the thermal response resulting from this bulk heating phenomenon may be a precursor to dynamic events associated with such crystal-scale effects

Giant negative magnetoresistance in semiconductors doped by multiply charged deep impurities

A giant negative magnetoresistance has been observed in bulk germanium doped with multiply charged deep impurities. Applying a magnetic field the resistance may decrease exponentially at any orientation of the field. A drop of the resistance as much as about 10000% has been measured at 6 T. The effect is attributed to the spin splitting of impurity ground state with a very large g-factor in the order of several tens depending on impurity.Comment: 4 pages, 4 figure

The visibility of IQHE at sharp edges: Experimental proposals based on interactions and edge electrostatics

The influence of the incompressible strips on the integer quantized Hall effect (IQHE) is investigated, considering a cleaved-edge overgrown (CEO) sample as an experimentally realizable sharp edge system. We propose a set of experiments to clarify the distinction between the large-sample limit when bulk disorder defines the IQHE plateau width and the small-sample limit smaller than the disorder correlation length, when self-consistent edge electrostatics define the IQHE plateau width. The large-sample or bulk QH regime is described by the usual localization picture, whereas the small-sample or edge regime is discussed within the compressible/incompressible strips picture, known as the screening theory of QH edges. Utilizing the unusually sharp edge profiles of the CEO samples, a Hall bar design is proposed to manipulate the edge potential profile from smooth to extremely sharp. By making use of a side-gate perpendicular to the two dimensional electron system, it is shown that the plateau widths can be changed or even eliminated altogether. Hence, the visibility of IQHE is strongly influenced when adjusting the edge potential profile and/or changing the dc current direction under high currents in the non-linear transport regime. As a second investigation, we consider two different types of ohmic contacts, namely highly transmitting (ideal) and highly reflecting (non-ideal) contacts. We show that if the injection contacts are non-ideal, however still ohmic, it is possible to measure directly the non-quantized transport taking place at the bulk of the CEO samples. The results of the experiments we propose will clarify the influence of the edge potential profile and the quality of the contacts, under quantized Hall conditions.Comment: Substantially revised version of manuscript arXiv:0906.3796v1, including new figures et

How to: interpret MICs of antifungal compounds according to the revised clinical breakpoints v. 10.0 European committee on antimicrobial susceptibility testing (EUCAST)

BACKGROUND: EUCAST has revised the definition of the susceptibility category "I" from "Intermediate" to "Susceptible, Increased exposure". This implies that "I" can be used where the drug-concentration at the site of infection is high, either because of dose escalation or through other means to ensure efficacy. Consequently, "I" is no longer used as a buffer-zone to prevent technical fact

QCD Sum Rules for Σ\Sigma Hyperons in Nuclear Matter

Within finite-density QCD sum-rule approach we investigate the self-energies of $\Sigma$ hyperons propagating in nuclear matter from a correlator of $\Sigma$ interpolating fields evaluated in the nuclear matter ground state. We find that the Lorentz vector self-energy of the $\Sigma$ is similar to the nucleon vector self-energy. The magnitude of Lorentz scalar self-energy of the $\Sigma$ is also close to the corresponding value for nucleon; however, this prediction is sensitive to the strangeness content of the nucleon and to the assumed density dependence of certain four-quark condensate. The scalar and vector self-energies tend to cancel, but not completely. The implications for the couplings of $\Sigma$ to the scalar and vector mesons in nuclear matter and for the $\Sigma$ spin-orbit force in a finite nucleus are discussed.Comment: 20 pages in revtex, 6 figures available under request as ps files, UMD preprint #94--11