Microdistribution of oxygen in silicon and its effects on electronic properties

The effects of interstitial oxygen on the electrical characteristics of Czochralski-grown silicon crystals were investigated for the first time on a microscale. It was found that the generation of thermal donors is not a direct function of the oxygen concentration. It was further found that the minority carrier life-time decreases with increasing oxygen concentration, on a microscale in as-grown crystals. It was thus shown, again for the first time, that oxygen in as grown crystals is not electronically inert as generally believed. Preannealing at 1200 C commonly employed in device fabrication, was found to suppress the donor generation at 450 C and to decrease the deep level concentrations

Discrete Razumikhin-type technique and stability of the Euler-Maruyama method to stochastic functional differential equations

A discrete stochastic Razumikhin-type theorem is established to investigate whether the Euler--Maruyama (EM) scheme can reproduce the moment exponential stability of exact solutions of stochastic functional differential equations (SFDEs). In addition, the Chebyshev inequality and the Borel-Cantelli lemma are applied to show the almost sure stability of the EM approximate solutions of SFDEs. To show our idea clearly, these results are used to discuss stability of numerical solutions of two classes of special SFDEs, including stochastic delay differential equations (SDDEs) with variable delay and stochastically perturbed equations

Measurement of atmospheric nitrous acid at Blodgett Forest during BEARPEX2007

Nitrous acid (HONO) is an important precursor of the hydroxyl radical (OH) in the lower troposphere. Understanding HONO chemistry, particularly its sources and contribution to HO_x (=OH+HO_2) production, is very important for understanding atmospheric oxidation processes. A highly sensitive instrument for detecting atmospheric HONO based on wet chemistry followed by liquid waveguide long path absorption photometry was deployed in the Biosphere Effects on Aerosols and Photochemistry Experiment (BEARPEX) at Blodgett Forest, California in late summer 2007. The median diurnal variation shows minimum HONO levels of about 20–30 pptv during the day and maximum levels of about 60–70 pptv at night, a diurnal pattern quite different from the results at various other forested sites. Measured HONO/NO_2 ratios for a 24-h period ranged from 0.05 to 0.13 with a mean ratio of 0.07. Speciation of reactive nitrogen compounds (NO_y) indicates that HONO accounted for only ~3% of total NO_y. However, due to the fast HONO loss through photolysis, a strong HONO source (1.59 ppbv day^(−1)) existed in this environment in order to sustain the observed HONO levels, indicating the significant role of HONO in NO_y cycling. The wet chemistry HONO measurements were compared to the HONO measurements made with a Chemical Ionization Mass Spectrometer (CIMS) over a three-day period. Good agreement was obtained between the measurements from the two different techniques. Using the expansive suite of photochemical and meteorological measurements, the contribution of HONO photolysis to HO_x budget was calculated to be relatively small (6%) compared to results from other forested sites. The lower HONO mixing ratio and thus its smaller contribution to HO_x production are attributed to the unique meteorological conditions and low acid precipitation at Blodgett Forest. Further studies of HONO in this kind of environment are needed to test this hypothesis and to improve our understanding of atmospheric oxidation and nitrogen budget

Gravitational Lenses With More Than Four Images: I. Classification of Caustics

We study the problem of gravitational lensing by an isothermal elliptical density galaxy in the presence of a tidal perturbation. When the perturbation is fairly strong and oriented near the galaxy's minor axis, the lens can produce image configurations with six or even eight highly magnified images lying approximately on a circle. We classify the caustic structures in the model and identify the range of models that can produce such lenses. Sextuple and octuple lenses are likely to be rare because they require special lens configurations, but a full calculation of the likelihood will have to include both the existence of lenses with multiple lens galaxies and the strong magnification bias that affects sextuple and octuple lenses. At optical wavelengths these lenses would probably appear as partial or complete Einstein rings, but at radio wavelengths the individual images could probably be resolved.Comment: 30 pages, including 12 postscript figures; accepted for publication in Ap

The Application of Micro-Raman Spectroscopy to Analysis and Identification of Minerals in Thin Section

Micro-Raman spectroscopy is a useful analytical tool for studying minerals in thin section. The advantages of this technique as a structural probe for analysis of micron-size minerals are demonstrated with a study of polymorphism of SiO2 and MgSiO3. Three polymorphs of silica, -quartz, coesite, and glass, in a thin section of Coconino sandstone were identified in situ with a Raman microprobe. The Raman spectra of these phases were compared to that measured for stishovite obtained from the same rock. Spectra of protoenstatite, orthoenstatite, and clinoenstatite, three polymorphs of MgSiO3, are consistent with their similar pyroxene chain structures but different space groups. The characteristic Raman spectra in each instance could be used for finger-printing identification of the phases and their orientations

The Alignment between Satellites and Central Galaxies: Theory vs. Observations

Recent studies have shown that the distribution of satellite galaxies is preferentially aligned with the major axis of their central galaxy. The strength of this alignment has been found to depend strongly on the colours of the satellite and central galaxies, and only weakly on the mass of the halo in which the galaxies reside. In this paper we study whether these alignment signals, and their dependence on galaxy and halo properties, can be reproduced in a hierarchical structure formation model of a $\Lambda$CDM concordance cosmology. To that extent we use a large $N$-body simulation which we populate with galaxies following a semi-analytical model for galaxy formation. We find that if the orientation of the central galaxy is perfectly aligned with that of its dark matter halo, then the predicted central-satellite alignment signal is much stronger than observed. If, however, the minor axis of a central galaxy is perfectly aligned with the angular momentum vector of its dark matter halo, we can accurately reproduce the observed alignment strength as function of halo mass and galaxy color. Although this suggests that the orientation of central galaxies is governed by the angular momentum of their dark matter haloes, we emphasize that any other scenario in which the minor axes of central galaxy and halo are misaligned by $\sim 40^{\circ}$ (on average) will match the data equally well. Finally, we show that dependence of the alignment strength on the color of the central galaxy is most likely an artefact due to interlopers in the group catalogue. The dependence on the color of the satellite galaxies, on the other hand, is real and owes to the fact that red satellites are associated with subhaloes that were more massive at their time of accretion.Comment: 13 Pages, 10 Figures, one figure replaced. added in discussion about comparison with others results, Updated version to match accepted version to MNRA

Oceanic influence on atmospheric mercury at coastal and inland sites: a springtime noreaster in New England

Continuous measurements of elemental (Hg<sup>0</sup>) and reactive mercury were conducted at two sites in New Hampshire during a powerful April 2007 noreaster. During the most intense period of the storm, enhancements of ~30–50 ppqv in Hg<sup>0</sup> were observed at a coastal and a high elevation inland site. This enhancement occurred simultaneously with elevated mixing ratios of three marine tracers, CH<sub>3</sub>I, CH<sub>2</sub>Br<sub>2</sub> and CHBr<sub>3</sub>. These observations suggest a marine source of Hg<sup>0</sup>, possibly outgassing from the ocean surface during strong turbulence. The Hg<sup>0</sup> enhancement observed 100 km inland suggests that the impact of coastal storms on terrestrial Hg cycling may not be limited to near-shore environments. Combining Hg<sup>0</sup> and marine tracer measurements during the storm with estimates of oceanic tracer fluxes during previous strong storms yields an order-of-magnitude estimate of the oceanic source of Hg<sup>0</sup> during the storm (~7 ppqv h<sup>−1</sup>) which can account for the observed enhancement at the field sites