Synthesis and X-ray Diffraction Study of thiosemicarbazone Palladacycles with dppm

Cyclometallated compounds have been extensively studied, in particular those with palladium and platinum. This is because of their possible applications in medicinal chemistry, as anticancer or antimicrobial agents; in some cases, with similar results as cisplatin, carboplatin or oxaliplatin. What is also remarkable is their use as homogeneous catalysts, for example, in cross coupling reactions such as Suzuki–Miyaura or Mizoroki–Heck. Herein, we report the synthesis of different thiosemicarbazone ligands, which will be reacted with a palladium or platinum salt, to give the corresponding cyclometallated compounds; in addition, their reactivity with bis(diphenylphosphino)methane (dppm) will be studied. Characterization has been carried out by elemental analysis, IR spectroscopy, 1H and 31P NMR spectroscopy. Additionally, 1c has been studied by X-ray diffractionFrancisco Reigosa wants to thank the Spanish Government (AEI) for their financial support through an FPU grant (number 13/05014). The authors thank funding from Xunta de Galicia (Galicia, Spain) under the Grupos de Referencia program (GRC 2019/014)S

Islanding detection in grid-connected power converters using harmonics due to the non-ideal behavior of the inverter

This paper analyzes the use of the voltage distortions in PWM voltage-source-inverters (VSIs) caused by the non-ideal behavior of the inverter for islanding detection purposes. The non-ideal characteristic of the inverters, mainly due to the dead-time needed to have safe commutations, produces fundamental frequency dependent harmonics (-5th, 7th...) in the output voltage. Although these harmonics are in principle an unwanted effect, since they reduce the power quality, they can potentially be used for islanding detection purposes. The physical principles of the method would be the same as for high frequency signal injection methods that have already been proposed but without the need of injecting a high frequency signa

Sensorless control of doubly-fed induction generators based on stator high frequency signal injection

High frequency signal injection based methods have been widely investigated for sensorless position/speed control of induction machines (IMs), permanent magnet synchronous machines (PMSMs) and more recently for doubly fed induction generators (DFIGs). When used with IMs and PMSMs, the high frequency signal is injected in the stator windings, an asymmetric (salient) rotor being required for this case. Contrary to this, both stator and rotor terminals are accessible and sensored in DFIGs, being therefore possible to inject the high frequency signal either in the stator or the rotor terminals. As consequence of this, the method can be used even if the machine is non-salient. In the implementation of the method with DFIGs, the high frequency voltage signal is typically injected in the rotor, the high frequency components (voltages of currents) induced in the stator being used for rotor position estimation. A drawback of this alternative is that the method is sensitive to the grid impedance in the stator side, which will be affected by the grid configuration, and is normally unknown. This paper proposes the sensorless control a DFIG injecting the high frequency voltage in the stator side, and using a high frequency current cancellation strategy in the rotor side. The main advantage of the proposed strategy is that the estimated position is independent of the grid characteristic

Coordinated operation of parallel-connected inverters for active islanding detection using high frequency signal injection

The high frequency impedance measured at the terminals of inverters connected in a microgrid by means of the injection of a small magnitude, high frequency voltage, has been shown to be a reliable metric to detect islanding. While the implementation of this method is simple when only an inverter injects the high frequency signal, this case is of limited applicability. On the other hand, several concerns arise when multiple inverters work in parallel, primarily due to risk interference among inverters. Islanding detection using high frequency signal injection in microgrids with multiple parallel-connected inverters is studied in this paper. A strategy for the coordinated operation of the inverters, without the need of communications or pre-established roles is proposed. Simulation and experimental results will be provided to demonstrate the viability of the concep

Islanding detection in three-phase and single-phase systems using pulsating high frequency signal injection

This paper analyzes the use of pulsating high frequency signal injection for islanding detection purposes. Active islanding detection using high frequency signal injection is an appealing option due to its reduced non-detection zone, reduced cost and ease of implementation. The use of a rotating high frequency signal has been reported and analyzed. However, this method can only be applied to three-phase systems. In this paper, the use of a pulsating high frequency signal injection is proposed. While it uses the same principles as rotating signal injection, it can be applied to both threephase and single-phase system

A simple, fast and accurate screening method to estimate maize (Zea mays L) tolerance to drought at early stages

There is a great need for the selection of plants with higher drought tolerance, so that fast and effective techniques to identify variations in drought tolerance are mandatory for screening large numbers of genotypes. This work presents a protocol for easy and reliable assessment of responses of maize genotypes to water stress conditions imposed during early stages of development. Three experiments using 11 commercial maize hybrids under four levels of water stress were carried out: i) germination, ii) seedling growth, and iii) early growth bioas- says. Constant and uniform water stress was imposed using solutions of polyethylene glycol 6000 (PEG 6000). Plant material was evaluated for several morphological, physiological and biochemical traits and monitored for photosynthetic efficiency. Principal component analysis (PCA) of these joint experiments revealed that germination percentage, early root development and stomatal conductance were the most useful traits for discriminating maize hybrids according to their tolerance to water stress. A subsequent greenhouse assay performed with two hybrids with contrasting responses under soil drying conditions validated the previous results. According to our results, the key of drought tolerance was a rapid response of stomatal conductance, which allowed a longer survival to stress even under severe desiccation. This work provides the researcher with a simple and reliable screening method that could be implemented as a decision support tool in the selection of the most suitable genotypes for cultivation in areas where water availability is a problem, as well as for the selection of tolerant genotypes to early drought in breeding programs

Application of indole-alkaloid harmaline induces physical damage to photosystem II antenna complexes in adult plants of Arabidopsis thaliana (L.) Heynh

Finding herbicides with new and multiple modes of action is a solution to stop the increase in resistant weed species. Harmaline, a natural alkaloid with proven phytotoxic potential, was tested on Arabidopsis adult plants by watering and spraying; watering resulted as the more effective treatment. Harmaline altered several photosynthetic parameters, reducing the efficiency of the light- (ΦII) and dark-adapted (Fv/Fm) PSII, suggesting physical damages in photosystem II, although dissipation of the energy in excess under the form of heat was not compromised as demonstrated by the significant increase in ΦNPQ. Metabolomic alterations, such as osmoprotectant accumulation and reduction in sugars’ content, also indicate a reduction of photosynthetic efficiency and suggest early senescence and water status alteration induced by harmaline. Data suggest that harmaline might be considered a new phytotoxic molecule interesting for further studies.Ministerio de Ciencia e Innovación | Ref. RTI2018-094716-B-100Universidade de Vigo/CISU