Non-thermal plasma technology for the abatement of NOx and SOx from the exhaust of marine diesel engine

Non-thermal plasma based technology is proposed to the abatement of NOx and SOx of the exhaust gas from marine diesel engine. Proposed technology uses electron gun and microwave energy to generate the plasma. Fundamentals of non-thermal plasma and chemistry are presented with a set of simulation results of the reduction of NOx and SO2 for a typical two stoke marine diesel exhaust engine which is supported by an experimental results obtained with microwave plasma. A new scheme is also proposed in this paper to generate required plasma for the treatment of NOx and SOx form high exhaust flow rate

Reduction of NOx and PM in Marine Diesel Engine Exhaust Gas using Microwave Plasma

Abatement of NOx and particulate matters (PM) of marine diesel exhaust gas using microwave (MW) non-thermal plasma is presented in this paper. NOx mainly consist of NO and less concentration of NO2 in a typical two stoke marine diesel engine and microwave plasma generation can completely remove NO. MW was generated using two 2kW microwave sources and a saw tooth passive electrode. Passive electrode was used to generate high electric field region within microwave environment where high energetic electrons (1-3eV) are produced for the generation of non-thermal plasma (NTP). 2kW gen-set diesel exhaust gas was used to test our pilot-scale MW plasma reactor. The experimental results show that almost 100% removal of NO is possible for the exhaust gas flow rate of 60l/s. It was also shown that MW can significantly remove soot particles (PM, 10nm to 365nm) entrained in the exhaust gas of 200kW marine diesel engine with 40% engine load and gas flow rate of 130l/s. MW without generating plasma showed reduction up to 50% reduction of PM and with the plasma up to 90% reduction. The major challenge in these experiments was that igniting the desired plasma and sustaining it with passive electrodes for longer period (10s of minutes) as it required fine tuning of electrode position, which was influenced by many factors such as gas flow rate, geometry of reactor and MW power

Qualitative trait loci analysis for seed yield and component traits in sunflower

The present investigation was carried out to identify the molecular markers associated with various characters in sunflower using recombinant inbred lines. Linkage analysis was carried out and five linkage groups were  obtained with 19 simple sequence repeats (SSR) markers. Linkage mapconstruction, single marker analysis (SMA) and composite interval mapping analysis were carried out with SSR primers and quantitative traits. In SMA, out of 50 SSR markers, a total of 29 SSR markers were found to be significantly linked to various traits. The adjusted R2 for the regression equation varies from 3.2 to 29.8%. Two traits namely, days to flowering and seed color recorded above 20% R2 value. Hull weight recorded above 10% R2 value. In inclusive composite interval mapping (ICIM), the quantitative trait loci (QTL) analysis resulted into two QTLs namely, seed and volume weight. QTL analyses were performed through inclusive  composite interval mapping (ICIM). The QTL analysis revealed each oneQTL for traits namely, stripes on seed margin, stripes between seed  margin, 100-seed weight and seed yield. The LOD ranged from 1.5 to 1.9. The adjusted R2 value ranged 10.6 (seed yield) to 65.0 (stripes between seed margin) percent. Among these QTL, QTL on stripes on seed margin and stripes between seed margin may be considered as potential as they recorded very high phenotypic variation accounted. As the distance between the flanking marker is more than 5 cm, fine mapping of this QTL region with more markers may be attempted to utilize these QTL in the marker assisted back cross programme.Key words: Sunflower, Simple sequence repeats (SSR), quantitative trait loci (QTL), hundred seed weight, stripes on seed margin, stripes between seed margin, seed yield

3-Amino­phenyl naphthalene-1-sulfonate

In the title compound, C16H13NO3S, the plane of the naphthalene ring system forms a dihedral angle of 64.66 (10)° with the benzene ring. The mol­ecular structure is stabilized by weak intra­molecular C—H⋯O inter­actions and the crystal packing is stabilized by weak inter­molecular N—H⋯O and C—H⋯O inter­actions and by π–π stacking inter­actions of the inversion-related naphthalene units [centroid–centroid distance of 3.7373 (14) Å]

Effect of sulphur, zinc and boron on the growth and yield enhancement of sunflower (Helianthus annuus L.)

Oilseed crops grown in different types of soil experience nutrient deficiency, especially sulphur, zinc and boron, which affect crop productivity. To tackle it, nutrient management practices must be streamlined to avoid improper fertilizations and deterioration of soil health. With this background, experimental trials were conducted to study the effect of sulphur, zinc and boron application on the growth, yield components and yield of hybrid sunflower at AyanAthur village, Ariyalur district (TN) during the summer seasons of 2016 and 2017. The experiments were laid out in Randomized Block Design (RBD) with three replications. The growth components of sunflower (plant height, leaf area index, dry matter production, leaf area duration (LAD) and growth analysis parameters such as crop growth rate (CGR), relative growth rate(RGR), net assimilation rate(NAR) and chlorophyll content, yield components and seed yield were significantly (level of significance P>0.05) influenced by foliar application of 0.5% Zn on bud initiation stage and seed formation stage and B @ 0.3% on bud initiation stage and ray floret formation stage along with S(sulphur) @ 40 kg ha-1 and RDF(recommended dose of fertilizers) as a soil application. Growth and yield parameters responded very little with the RDF alone. From both experimental results, we found that foliar application of Zn @ 0.5%and B @ 0.3% along with S @ 40 kg ha-1 and RDF recorded the highest percentage of dry matter production (44.4%), number of filled seeds (30.1%) and yield (32.4%) of hybrid sunflower

4′-Ferrocenyl-1′-methylacenapthylene-1-spiro-2′-pyrrolidine-3′-spiro-2′′-indane-2,1′′,3′′(1H)-trione

In the title compound, [Fe(C5H5)(C29H20NO3)], the acenaphthyl­ene ring system makes a dihedral angle of 83.77 (3)° with the indane-1,3-dione ring system. The central pyrrolidine ring exhibits a twist conformation. In the crystal, mol­ecules are linked by a weak inter­molecular C—H⋯O inter­action into a chain along the b axis. Two weak intra­molecular C—H⋯O inter­actions are also present

Methyl 9-p-tolyl-8a,9,9a,10,11,12,13,14a-octa­hydro-8H-benzo[f]chromeno[3,4-b]indolizine-8a-carboxyl­ate

In the title compound, C28H29NO3, the fused pyrrolidine and piperidine rings of the octa­hydro­indolizine unit exhibit envelope and chair conformations, respectively. The dihedral angle between the naphthalene ring system and the benzene ring is 40.37 (5)°. The crystal packing is stabilized by weak inter­molecular C—H⋯O inter­actions

Residual effect of organics and direct effect of mineral nitrogen on rice (Oryza sativa L.) in two different textural soils

Nitrogen through organics and inorganics application is an alternate to maintain soil health and crop productivity in the rice cropping system. With this background, field experiments were conducted in farmer’s field at Kuttalam during 2012-2013, 2013-14 to evaluate residual organics and mineral nitrogen (100%N) on growth parameters and yield of rice (Oryza sativa) in sandy clay loam and clay loam soil. The treatments consisted of residual organics viz., composted coir pith (CCP), green manures (GM), sugarcane trash compost (STC), vermicompost (VC), poultry manure (PM) and FYM applied(100%N) and a combination of above residual organics with urea@50%N besides 100% recommended dose of nitrogen (RDN) and control. The results revealed that residual organics and urea recorded higher growth parameters like plant height, chlorophyll content, leaf area index(LAI), crop growth rate (CGR), relative growth rate(RGR), net assimilation rate(NAR), No. of tillers/hill compared to their individual addition. The growth parameters were more under residual PM in combination with mineral nitrogen in both the soils. Residual PM + fertilizer nitrogen (100% N) recorded highest grain (4485, 4693 kg ha-1) and straw yield (6984, 5897 kg ha-1) in clay loam and sandy clay loam soils, respectively. The lowest grain(3292, 2993 kg ha-1) and straw yield(4998, 4003 kg ha-1) were recorded in residual GM + fertilizer (100% N) in both soils. Among organics alone, residual PM(100% N) registered highest grain yield (4025, 4048 kg ha-1) in both soils. It can be concluded that the application of poultry manure alone or in combination with N fertilizers enhanced the growth and improved soil health.

19-Ferrocenyl-18-oxa-8,16-diaza­penta­cyclo­[8.6.3.01,10.02,7.012,16]nona­deca-2(7),3,5-triene-9,17-dione

In the title compound, [Fe(C5H5)(C21H19N2O3)], both pyrrol­idine rings of the pyrrolizine substructure show an envelope conformation. In the ferrocenyl moiety, the unsubstituted cyclo­penta­dienyl ring is disordered over two orientations with site occupancies of 0.64 (2) and 0.36 (2). In the pyrrolizine ring, one C atom is disordered over two positions, with site occupancies of 0.71 (1) and 0.29 (1). Intra­molecular C—H⋯O inter­actions occur. The crystal packing is established through weak inter­molecular C—H⋯O and N—H⋯O inter­actions