NATURAL BITUMEN OF GEORGIAN

Manifestations of natural bitumen are recorded in almost all regions of Georgia. The bitumen of Kari Crossing, Natanebi, Chibrevi, Baida, Polpoy-Teibi, Mirzaani and Kila-Kupra were studied. The main aromatic structures contained in organic extracts obtained from bitumen under investigation are identified, and physical and chemical characteristics, elemental composition and distribution of microelements in these organic extracts are determined. The study of microelements distribution showed that bitumen of the Kari Crossing and the Baida 2, in which the ratio V/Ni is less than 1 stratigraphically belong to the third-generation bitumen, and the Chibrevi and Mirzaani bitumen with the ratio V/Ni >1 is of older origin and belongs to Paleozoic period. By content of oils, tars and asphaltes the bitumen under investigation belong to the asphalt type bitumen.Manifestations of natural bitumen are recorded in almost all regions of Georgia. The bitumen of Kari Crossing, Natanebi, Chibrevi, Baida, Polpoy-Teibi, Mirzaani and Kila-Kupra were studied. The main aromatic structures contained in organic extracts obtained from bitumen under investigation are identified, and physical and chemical characteristics, elemental composition and distribution of microelements in these organic extracts are determined. The study of microelements distribution showed that bitumen of the Kari Crossing and the Baida 2, in which the ratio V/Ni is less than 1 stratigraphically belong to the third-generation bitumen, and the Chibrevi and Mirzaani bitumen with the ratio V/Ni >1 is of older origin and belongs to Paleozoic period. By content of oils, tars and asphaltes the bitumen under investigation belong to the asphalt type bitumen

COMPREHENSIVE METHODOLOGY FOR INVESTIGATION OF MIDDLE FRACTIONS OF PETROLEUM

A methodology has been developed for separation and identification of hydrocarbons of middle 250-350°C fractions of Taribani and Mirzaani petroleum (Georgia) in order to determine their individual hydrocarbon composition. The middle fractions of petroleum are difficult to study objects due to the huge variety of hydrocarbon isomers present in them.The methodology includes the following complex of physical and chemical methods for processing of petroleum: distillation, dearomatization by adsorption chromatography, thorough separation of isoalkanes from cycloalkanes using three stages thermal diffusion, processing of the obtained concentrates with thiocarbamide. To determine the individual composition of the fractions, instrumental methods of gasliquid chromatography analysis on capillary columns, MS and GC/MS were used. The developed methodology has been successfully applied to the separation of paraffinic, isoparaffinic and cycloparaffinic hydrocarbons and to determine molecular composition of the middle fractions. Separation of isomers from the concentrates obtained by way of thermal diffusion fractions of Taribani and Mirzaani petroleum was achieved and a number of isoprenoids of C11-C23 composition were identified, in thiocarbamide concentrates there were polycyclic alkanes of C11-C16 composition, and in filtrates - relict, polymethyl-substituted decalins of C14-C16 compositionA methodology has been developed for separation and identification of hydrocarbons of middle 250-350°C fractions of Taribani and Mirzaani petroleum (Georgia) in order to determine their individual hydrocarbon composition. The middle fractions of petroleum are difficult to study objects due to the huge variety of hydrocarbon isomers present in them.The methodology includes the following complex of physical and chemical methods for processing of petroleum: distillation, dearomatization by adsorption chromatography, thorough separation of isoalkanes from cycloalkanes using three stages thermal diffusion, processing of the obtained concentrates with thiocarbamide. To determine the individual composition of the fractions, instrumental methods of gasliquid chromatography analysis on capillary columns, MS and GC/MS were used. The developed methodology has been successfully applied to the separation of paraffinic, isoparaffinic and cycloparaffinic hydrocarbons and to determine molecular composition of the middle fractions. Separation of isomers from the concentrates obtained by way of thermal diffusion fractions of Taribani and Mirzaani petroleum was achieved and a number of isoprenoids of C11-C23 composition were identified, in thiocarbamide concentrates there were polycyclic alkanes of C11-C16 composition, and in filtrates - relict, polymethyl-substituted decalins of C14-C16 compositio

Comprehensive Methodology for Investigation of Middle Fractions of Petroleum

A methodology has been developed for separation and identification of hydrocarbons of middle 250-350°C fractions of Taribani and Mirzaani petroleum (Georgia) in order to determine their individual hydrocarbon composition. The middle fractions of petroleum are difficult to study objects due to the huge variety of hydrocarbon isomers present in them.The methodology includes the following complex of physical and chemical methods for processing of petroleum: distillation, dearomatization by adsorption chromatography, thorough separation of isoalkanes from cycloalkanes using three stages thermal diffusion, processing of the obtained concentrates with thiocarbamide. To determine the individual composition of the fractions, instrumental methods of gasliquid chromatography analysis on capillary columns, MS and GC/MS were used. The developed methodology has been successfully applied to the separation of paraffinic, isoparaffinic and cycloparaffinic hydrocarbons and to determine molecular composition of the middle fractions. Separation of isomers from the concentrates obtained by way of thermal diffusion fractions of Taribani and Mirzaani petroleum was achieved and a number of isoprenoids of C11-C23 composition were identified, in thiocarbamide concentrates there were polycyclic alkanes of C11-C16 composition, and in filtrates - relict, polymethyl-substituted decalins of C14-C16 compositio