Technical Feasibility of Recycling Waste Cooking Oils (WCO) Produced in Qom to Biodiesel

Background: The aim of this research was to study the technical feasibility of recycling waste cooking oils (WCO) produced in Qom to biodiesel. Methods: This cross-sectional study was performed in Qom in the first half of 2013. In this study, 147 domestic, commercial, and industrial sources producing WCO were identified, selected, and asked to collect and deliver the WCO produced by them within a week. The samples obtained from the sources were mixed separately at a ratio of one to one, and finally, a WCO sample was obtained from each source. Then, some characteristics of samples such as chemical profiles were analyzed and the esterification and transesterification process were used to convert WCO into biodiesel. Finally, some of the technical characteristics of produced biodiesel such as flash point, viscosity, density, moisture, and acidic number were determined and compared with the standard. Results: In terms of basic properties, domestic WCO had the best quality for conversion to biodiesel. Also, in terms of viscosity, density, acidic number and flash point, biodiesel produced from domestic WCO had more favorable conditions. In terms of the percentage of humidity, biodiesel produced from industrial WCO was the best one. Conclusion: WCO produced from domestic and commercial sources has the potential to be converted into biodiesel with standard features but WCO produced from industrial sources due to their very poor quality needs more pre-treatment processes

Assessment of a Continuous Electrocoagulation on Turbidity Removal from Spent Filter Backwash Water

Background & Aims of the Study: Spent filter backwash water (SFBW) consists of 1-5% of the total treated water typically and it has a high turbidity. Because of the scarcity of water resources and in order to prevent the environmental contamination, effluent treatment of rapid sand filter backwashing is unavoidable. One of the new technologies for removal of turbidity from the effluent is ElectroCoagulation (EC) processes. This study aimed to examine the efficiency of continuous electrocoagulation in turbidity removal from spent filter backwash water. Materials & Methods: This study was non-continuous experiment. A rectangular cube electrocoagulation tank in 24 cm×17 cm×18 cm dimensions from Plexiglas with the volume of 7.35 liter was made. In this tank there were 4 metal plates (electrode) (15× 22× 0.1cm); two electrodes as cathode and anode which were made of aluminum and iron, respectively. All of the tests were done in continuous flow. According to the study criteria (Time, Turbidity and pH), 126 sample got with the turbidity 320, 350, 400 NTU from rapid sand filter backwashing water, so they were tested in current density; 1, 1.4, 1.8, 2, 2.4, 2.8 and 3.2 ampere in 3 selected detention times (10, 20 and 30 min). Each experiment was repeated two times. In this research the space of electrode and pH is fixed at 1.5 cm and 8.2. Results: In this case the highest turbidity removal for Al electrode from rapid sand filter backwashing occurred in the current density 3.2 ampere, 30 min detention time and 320 NTU turbidity. The percent of removal for Al was 95.12. The highest removal for Fe electrode from rapid sand filter backwashing occur in the current density 3.2 ampere, 30 min detention time and 320 NTU turbidity. The percent of removal for Fe was 87.40. Conclusion: Regarding to the results of the tests, using electrocoagulation has an appropriate efficiency in turbidity removal

Evaluation of physical and chemical quality of groundwater in the villages of Qom province and zoning them by GIS

Background: The aim of this study was to evaluate the physical and chemical quality of groundwater in the villages of Qom province during summer 2014, and to compare the results with Iran’s Standard No. 1053. Methods: This research is a descriptive sectional study. During the investigation, one step sampling with the necessary repetitions (if necessary) was performed of each well for evaluation of physical and chemical quality of groundwater in the villages of Qom province. SPSS version 16 and ARCGIS software were employed for data analysis and data zoning respectively. Results: The average concentration of magnesium, sulfate and ammonia in wells water were higher than standard. The average concentration of fluoride was lower than the standard limit. pH and turbidity in all wells were within the standard limit but sulfate in 33.33%, ammonia in 13.33%, magnesium in 10.66%, sodium in 40%, calcium in 5.33%, nitrate in 17.33%, total dissolved solids (TDS) in 14.66% and electrical conductivity (EC) in 24% of wells were higher than the standard limit, and fluorine in 98.66% of wells was lower than the standard limit. The results of zoning in the villages of Qom province revealed that measured values at most wells were in the maximum amount in central and northeastern areas and minimum amount in southern and western areas. Conclusion: This study indicated that most of the physicochemical parameters such as fluoride in almost all villages, and sulfates, chloride, magnesium, sodium, calcium, nitrate, TDS and EC in some of the wells did not fall within the permissible limit

Assessment of nanopolyamidoamine-G7 dendrimer antibacterial effect in aqueous solution

Background: Poly(amidoamine) (PAMAM) dendrimer derivatives have been investigated for their biological applications, especially for delivery of drugs, including antimicrobial drugs to eukaryotic cells, but their effects on bacterial cells are largely unexplored. Nanotechnology and its application is one of the rapidly developing sciences. As demand of fresh drinking water is increasing, nanotechnology can contribute noticeable development and improvement to water treatment process. This study was aimed to examine synthesis and the antibacterial effect of Nanopolyamidoamine-G7 (NPAMAM-G7) dendrimer on Escherichia Coli (E. Coli), Klebsiella Oxytoca (K. Oxytoca), Pseudomonas Aeruginosa (P. Aeruginosa), Proteus Mirabilis (P. Mirabilis) and Staphylococcus Aureus (S. Aureus) from aqueous solution. Methods: In this experimental study that has been conducted in August to December 2015 in the laboratory of microbiology of Iran University of Medical Sciences, initially dilution of 103 CFU/ml were prepared from each strain of bacteria. Then different concentrations of dendrimer (0.025, 0.25, 2.5 and 25 µg/ml) in the laboratory temperature (23-25 °C) was added to water. In order to determine the efficiency of dendrimers in removal of bacteria, samples were taken at different times (0, 10, 20, 30, 40, 50 and 60 min) and were cultured on nutrient agar medium. Samples were incubated for 24 hours at 37 °C and then number of colonies were counted. Results: Antibacterial properties of dendrimers in aqueous solution by increasing the dendrimer concentration and contact time is directly related. At a concentration of 25 μg/ml at 60 minutes all bacteria except S. Aureus, and at 30 minutes, E. Coli and K. Oxytoca bacteria for 100% excluded. The concentration of 2.5 μg/ml at 60 minutes of bacteria, E. Coli, K. Oxytoca and P. Mirabilis are 100% excluded. All concentrations of dendrimers at different times were reduced bacteria in the PAMAM- G7 dendrimer effect on gram-negative bacteria, gram-positive bacteria was better. Conclusion: The NPAMAM-G7 dendrimer with end amine groups exhibited a positive impact on the removal of standard strains, gram-positive and gram-negative bacteria. Therefore, it is possible to use these nanodendrimers as antibacterial in the future

Efficiency of electrical coagulation process using aluminum electrodes for municipal wastewater treatment: a case study at Karaj wastewater treatment plant

Background: The reuse of treated municipal wastewater is an important source of water for different purposes. This study evaluated the efficiency of the electrocoagulation process in removing turbidity, total suspended solids (TSS), chemical oxygen demand (COD), nitrate, and phosphate from wastewater at the treatment facility in Karaj, Iran. Methods: This experimental study was performed at a pilot scale and in a batch system. A 4-liter tank made from safety glass with 4 plate electrodes made from aluminum was unipolarly connected to a direct current power supply with a parallel arrangement. Wastewater samples were taken from the influent at the Karaj wastewater treatment facility. Rates of turbidity, TSS, COD, nitrate, and phosphate removal under different conditions were determined. Results: The highest efficiency of COD, TSS, nitrate, turbidity, and phosphate elimination was achieved at a voltage of 30 volts and a reaction time of 30 minutes. The rates were 88.43%, 87.39%, 100%, 80.52%, and 82.69%, respectively. Conclusion: Based on the results of this study, electrocoagulation is an appropriate method for use in removing nitrate, phosphate, COD, turbidity, and TSS from wastewater

Fluoride Concentration of Drinking-Water of Qom, Iran

Background and Purpose: Fluoride is a natural element essential for human nutrition due to its benefits for dental enamel. It is well-documented that standard amounts of fluoride in drinkingwater can decrease the rate of dental caries. This study was conducted with the aim of measuring fluoride concentration of drinking-water supplies and urban distribution system in Qom, Iran. Materials and Methods: Results were subsequently compared against national and international standards. All sources of drinking-water of rural and urban areas were examined. To measure fluoride, the standard SPADNS method and a DR/4000s spectrophotometer were used. Results: Results showed that the mean of fluoride concentration in rural areas, mainly supplied with groundwater sources, was 0.41 mg/L, that of the urban distribution system 0.82 mg/L, that of Ali-Abad station 0.11 mg/L, and that of the private water desalination system 0.24 mg/L. Due to the hot climate of Qom, fluoride concentration means of all sources were lower than the permissible standards set by Iranian Standards and the WHO guidelines (except those of some of the groundwater sources and urban distribution systems). Conclusion: It seems that in most of the drinking-water sources the average fluoride concentration is not enough to prevent dental caries or strengthen dental enamel. It is concluded that Qom’s drinkingwater would require at least 0.4 mg/L to reach the minimum desirable standard

Investigation of Qom Rural Area Water Network Accident in 2010 and Minimization Approaches of Accident Frequencies

Background & Aims of the Study : Accidents in water networks can lead to increase the uncounted water, costs of repair, maintenance, restoration and enter water contaminants to water network. The aim of this study is to survey the accidents of Qom rural water network and choose the right approaches to reduce the number of accidents. Materials & Methods: In this cross-sectional study, four sector of Qom province (Markazi, Dastjerd, Kahak and Qahan), were assessed over a period of 8 months (July – January 2010). This study was conducted through questionnaire of Ministry of Energy. Results: The total number of accidents was 763. The highest number of accidents in the four sectors was related to Markazi sector with 228 accidents. According to the time of the accident, the highest and lowest number of accident was related to September (19.7%) and November (6.8%), respectively. According to the location of the accident on network, the highest and lowest number of accident was related to distribution network (64%) and connections (17.5%) and transmission pipe (18.34%), respectively. According to the type of the accident, the highest and lowest number of accident was related to breaking (47.8%) and gasket failure (1.2%), respectively. Considering with the pipes’ material, the highest and lowest number of accident was related to polyethylene pipes (93%) and steel and cast iron pipes (0.5%, 0.5%), respectively. Conclusions: Due to the high break rate of Polyethylene pipes, it is recommended to be placed in priority of leak detection and rehabilitation.  

Removal of Acid Red 18 dye from Aqueous Solutions Using Nanoscale Zero-Valent Iron

Background and Purpose:Organic dyes with a complex structure are often toxic, carcinogenic, mutagenic, non-biodegradation and stable in the environment and if released to the environment without treatment can endanger the environment and human health. The aim was to evaluate the performance nanoscalezero-valent iron (NZVI) in the removal of dye acid red 18 (AR18) from aqueous solutions. Materials and Methods:This study was conducted at the laboratory scale. In this study, the removal efficiency of AR18 from a synthetic solution by NZVI was investigated. As well as the effect of solution pH, dye concentration, the concentration of NZVI and contact time in decolorization efficiency was investigated. Results:The results show that in pH = 3, contact time of 80 minutes, dye concentration of 25 mg/l and concentration of NZVI of 2 g/l, the removal efficiency was about 94%. Conclusion:According to the results of experiments, NZVI has high efficiency in removal of AR18 from aqueous solution

The status of wastewater management in Shokuhieh industrial park (A case study of Qom province)

Background: Water resource management is a strategic issue in Qom city. Water scarcity is one of the most critical concerns of industrial estates. This study aimed to evaluate wastewater management in the Shokuhieh industrial park of Qom province in 2013. Methods: This is a descriptive cross-sectional study done by visiting the industrial units in person, completing questionnaires and analyzing the results. The questionnaire had 25 questions, including general information, the status of water supply, treatment and consumption, wastewater production, reuse or discharge of produced wastewater and the status of wastewater treatment and discharge of effluent. The industrial units evaluated were active with over 50 personnel and numbered 44 in total. Results: The water suppliers in the industries included network (70.5%), network and reverse osmosis (RO) (22.5%), network and tanker (2.4%) and tanker (4.6%). 63.63% of the industries had water treatment systems. 19.5% reused wastewater and 31.8% performed pretreatment before discharge of wastewater. The discharge sites of water treatment units’ effluent included the absorption well (17%), greenbelt (18%) and sewer (65%). Discharge sites of sanitary wastewater in 50% of the industries was sewer and in 50%, it was absorption well. The discharge sites of processed wastewater was reuse (2%), sewer (52%) and absorption well (46%). Discharge sites of exiting effluent from pretreatment units in the industrial park, included sewer (85.5%), transport by tanker (7.1%) and absorption well (7.1%). The type of pretreatment process in 35.7% of the industries was chemical and in 64.3%, it was septic tank. Conclusion: The results of this study showed that pre-treatment is not done in most industries and wastewater reuse is performed in few industries. The main method of wastewater disposal in industries was by discharge into the sewer and absorbent well

Efficiency of horizontal roughing filter in removing nitrate, phosphate and chemical oxygen demand from effluent of waste stabilization pond

Background: The effective size of the end grain of horizontal roughing filters (HRFs) is larger than 2 mm. This study aimed to examine the efficiency of HRFs in removing nitrate, phosphate, and chemical oxygen demand (COD) from effluent of a wastewater stabilization pond. Methods: This experimental study was conducted in 2013. The pilot project was transferred to the Karaj wastewater treatment plant (stabilization pond), and the installation, equipping, and start-up of the system began using an effluent treatment plant. Sampling was done from March to August in 3 rates, 0.5, 1 and 1.5 m/h, and included simultaneous sampling from inlet and outlet filtering to determine the concentrations of nitrate, phosphate, and COD. Results: At filtration rates of 0.5, 1, and 1.5 m/h, the average nitrate removal equaled 25%, 32%, and 34%, respectively, average phosphate removal equaled 29%, 26%, and 28%, respectively, and the average COD removal at filtration rates of 0.5, 1, and 1.5 m/h equaled 62%, 66%, and 68%, respectively. Outlet values of phosphate and nitrate were lower than the standards set by the Environmental Standards Organization (ESO) (P < 0.05). Conclusion: According to the results of this study, the HRF function was approximately adequate in COD removal, but its efficiency in nitrate and phosphate removal was lower