Algebraic Approach to Molecular thermodynamics

An algebraic model based on Lie-algebraic and discrete symmetry techniques is applied to the analysis of thermodynamic vibrational properties of molecules. The local anharmonic effects are described by a Morse-like potential and the corresponding anharmonic bosons are associated with the SU(2) algebra. A vibrational high-temperature partition function and the related thermodynamic functions are derived and studied in terms of the parameters of the model. The idea of a critical temperature is introduced in relation with the specific heat. A physical interpretation of a quantum deformation associated with the model is given.Comment: 18 pages, 6 figures, submitted to J Physics: Condensed Matte

Positive solutions for asymptotically linear problems in exterior domains

The existence of a positive solution for a class of asymptotically lin- ear problems in exterior domains is established via a linking argument on the Nehari manifold and by means of a barycenter function

Roughness correction to the Casimir force : Beyond the Proximity Force Approximation

We calculate the roughness correction to the Casimir effect in the parallel plates geometry for metallic plates described by the plasma model. The calculation is perturbative in the roughness amplitude with arbitrary values for the plasma wavelength, the plate separation and the roughness correlation length. The correction is found to be always larger than the result obtained in the Proximity Force Approximation.Comment: 7 pages, 3 figures, v2 with minor change

Particle Creation by a Moving Boundary with Robin Boundary Condition

We consider a massless scalar field in 1+1 dimensions satisfying a Robin boundary condition (BC) at a non-relativistic moving boundary. We derive a Bogoliubov transformation between input and output bosonic field operators, which allows us to calculate the spectral distribution of created particles. The cases of Dirichlet and Neumann BC may be obtained from our result as limiting cases. These two limits yield the same spectrum, which turns out to be an upper bound for the spectra derived for Robin BC. We show that the particle emission effect can be considerably reduced (with respect to the Dirichlet/Neumann case) by selecting a particular value for the oscillation frequency of the boundary position